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Senarmontite

A valid IMA mineral species - grandfathered

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Senarmontite

Djebel Hammimat Mine, Aïn Babouche, Ain Babouche District, Oum el Bouaghi Province, Algeria

Senarmontite

Pereta Mine, Scansano, Grosseto Province, Tuscany, Italy

Senarmontite

Tafone mine, Manciano, Grosseto Province, Tuscany, Italy

Senarmontite

Djebel Hammimat Mine, Aïn Babouche, Ain Babouche District, Oum el Bouaghi Province, Algeria

Senarmontite

Pereta Mine, Scansano, Grosseto Province, Tuscany, Italy

Senarmontite

Tafone mine, Manciano, Grosseto Province, Tuscany, Italy

Senarmontite

Djebel Hammimat Mine, Aïn Babouche, Ain Babouche District, Oum el Bouaghi Province, Algeria

Senarmontite

Pereta Mine, Scansano, Grosseto Province, Tuscany, Italy

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About SenarmontiteHide

Henri H. de Sénarmont

Formula:

Sb₂O₃

Colour:

Colourless to gray

Lustre:

Sub-Adamantine, Resinous

Hardness:

2 - 2½

Specific Gravity:

5.5

Crystal System:

Isometric

Name:

Named by J.D. Dana in 1851 in honor of Henri Hureau de Sénarmont (6 September 1808, Broué, France – 30 June 1862, Paris, France), Professor of Mineralogy, School of Mines, Paris, who first described the species. De Sénarmont also made significant contributions to the study of polarization and demonstrating the anisotropy of heat diffusion in a crystal.

Type Locality:

ⓘ Djebel Hammimat Mine, Aïn Babouche, Ain Babouche District, Oum el Bouaghi Province, Algeria

Dimorph of:

Valentinite

Isostructural with:

Arsenolite

This page provides mineralogical data about Senarmontite.

Unique IdentifiersHide

Mindat ID:

3618

Long-form identifier:

mindat:1:1:3618:0

IMA Classification of SenarmontiteHide

IMA status:

Approved, 'Grandfathered' (first described prior to 1959)

IMA Formula:

Sb³⁺₂O₃

First published:

1851

Classification of SenarmontiteHide

Strunz-mindat (2026):

4.CB.50

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
C : Metal: Oxygen = 2: 3,3: 5, and similar
B : With medium-sized cations

Dana 8th ed.:

4.3.9.2

4 : SIMPLE OXIDES
3 : A₂X₃

Hey's CIM Ref.:

7.13.3

7 : Oxides and Hydroxides
13 : Oxides of As, Sb and Bi

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.

Symbol	Source	Reference for Standard
Sen	IMA–CNMNC	Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43
Sen	The Canadian Mineralogist (2019)	The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download

Physical Properties of SenarmontiteHide

Lustre:

Sub-Adamantine, Resinous

Transparency:

Transparent, Translucent

Colour:

Colourless to gray

Streak:

White

Hardness:

2 - 2½ on Mohs scale

Tenacity:

Brittle

Cleavage:

Poor/Indistinct
{111} in traces.

Fracture:

Irregular/Uneven

Density:

5.5 g/cm³ (Measured) 5.584 g/cm³ (Calculated)

Optical Data of SenarmontiteHide

Type:

Isotropic

RI values:

n = 2.087

Surface Relief:

Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.

Focus:

In focus

Anisotropism:

Strong anomalous anisotropism, sectored or zoned.

Chemistry of SenarmontiteHide

Mindat Formula:

Sb₂O₃

Element Weights:

Element	% weight
Sb	83.535 %
O	16.465 %

Calculated from ideal end-member formula.

Elements listed:

O, Sb - search for minerals with similar chemistry

Crystallography of SenarmontiteHide

Crystal System:

Isometric

Class (H-M):

m3m(4/m32/m) - Hexoctahedral

Space Group:

Fd3m

Cell Parameters:

a = 11.1519(2) Å

Unit Cell V:

1,386.90 Å³ (Calculated from Unit Cell)

Morphology:

Octahedral crystals, modified by cube and dodecahedron.

Comment:

On synthetic material

Crystal StructureHide

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Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4

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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure

ID	Species	Reference	Year	Locality	Temp (K)
0015530	Senarmontite	Zav'yalova A A, Imamov R M (1975) About the structure of the cubic modification of Sb2O3 Soviet Journal of Coordination Chemistry 1 1186-1188	1975	synthetic	293
0009536	Senarmontite	Svensson C (1975) Refinement of the crystal structure of cubic antiomony trioxide, Sb2O3 Acta Crystallographica B31 2016-2018	1975	synthetic	293
0014075	Senarmontite	Bozorth R M (1923) The crystal structures of the cubic forms of arsenious and antimonous oxides Journal of the American Chemical Society 45 1621-1627	1923	Mt. Hamimat, Algeria	293
0012430	Senarmontite	Whitten A E, Dittrich B, Spackman M A, Turner P, Brown T C (2004) Charge density analysis of two polymorphs of antimony(III) oxide Dalton Transactions 2004 23-29	2004		293
0010494	Senarmontite	Dehlinger U (1927) Uber die kristallstruktur der antimonoxyde Zeitschrift fur Kristallographie 66 108-119	1927		293

CIF Raw Data - click here to close

data_global
_chemical_name_mineral 'Senarmontite'
loop_
_publ_author_name
'Zav'yalova A A'
'Imamov R M'
_journal_name_full 'Soviet Journal of Coordination Chemistry'
_journal_volume 1 
_journal_year 1975
_journal_page_first 1186
_journal_page_last 1188
_publ_section_title
;
 About the structure of the cubic modification of Sb2O3
 Note: y(O) and z(O) corrected
;
_database_code_amcsd 0015530
_chemical_compound_source 'Synthetic'
_chemical_formula_sum 'Sb2 O3'
_cell_length_a 11.10
_cell_length_b 11.10
_cell_length_c 11.10
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 90
_cell_volume 1367.631
_exptl_crystal_density_diffrn      5.663
_symmetry_space_group_name_H-M 'F d 3 m'
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loop_
_atom_site_label
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_atom_site_fract_y
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_atom_site_U_iso_or_equiv
Sb  -0.11500  -0.11500  -0.11500   0.01520
O   0.19500   0.00000   0.00000   0.02026

X-Ray Powder DiffractionHide

Loading XRD data...

2θ (degrees) d-spacing (Å)

Data courtesy of RRUFF project at University of Arizona, used with permission.

Powder Diffraction Data:

d-spacing	Intensity
6.44 Å	(12)
3.218 Å	(100)
2.788 Å	(40)
2.559 Å	(11)
1.972 Å	(42)
1.681 Å	(35)
1.279 Å	(12)

Comments:

Synthetic.

Geological EnvironmentHide

Paragenetic Mode(s):

Paragenetic Mode	Earliest Age (Ga)
Stage 7: Great Oxidation Event	<2.4
47d : [Arsenates, antimonates, selenates, bismuthinates]
47h : [Near-surface oxidized, dehydrated minerals]

Type Occurrence of SenarmontiteHide

Type Locality:

ⓘ Djebel Hammimat Mine, Aïn Babouche, Ain Babouche District, Oum el Bouaghi Province, Algeria

General Appearance of Type Material:

Cavernous masses composed of capillary filaments, parallel or slightly divergent. Also in saccharoid masses, granular or compact, with cavities of octahedral crystals to 1 cm.

Place of Conservation of Type Material:

No designated type material.

Geological Setting of Type Material:

Oxidation zone of an antimony deposit.

Synonyms of SenarmontiteHide

Sénarmontite

Other Language Names for SenarmontiteHide

Dutch:Senarmontiet

German:Senarmontit

Russian:Сенармонтит

Simplified Chinese:方锑矿

Spanish:Senarmontita

Traditional Chinese:方銻礦

Common AssociatesHide

Associations Based on Photo Data:

72 photos of Senarmontite associated with Stibnite	Sb₂S₃
57 photos of Senarmontite associated with Valentinite	Sb₂O₃
37 photos of Senarmontite associated with Kermesite	Sb₂S₂O
18 photos of Senarmontite associated with Stibiconite	Sb³⁺Sb⁵⁺₂O₆(OH)
15 photos of Senarmontite associated with Native Antimony	Sb
12 photos of Senarmontite associated with Native Sulphur	S₈
10 photos of Senarmontite associated with Quartz	SiO₂
10 photos of Senarmontite associated with Baryte	BaSO₄
7 photos of Senarmontite associated with Metastibnite	Sb₂S₃
6 photos of Senarmontite associated with Celestine	SrSO₄

Related Minerals - Strunz-mindat Grouping Hide

4.CB.	Magnesiohögbomite-6N12S	Mg₅Al₁₁TiO₂₃(OH)	Trig. 3m(32/m) : R3m
4.CB.	Kidodite	BaMg₂Fe₁₆O₂₇	Hex. 6/mmm(6/m2/m2/m) : P6₃/mmc
4.CB.	Ferrohögbomite-2N2S	[(Fe²⁺,Mg,Zn,Al)₃(Al,Ti,Fe³⁺)₈O₁₅(OH)]₂	Hex. 6mm : P6₃mc
4.CB.	Zhenruite	(MoO₃)₂ · H₂O	Mon. 2/m : P2₁/m
4.CB.	Fuyuanite	Mg₇Nb₆O₁₈(OH)₈	Trig. 3 : P3
4.CB.	Virgilluethite	MoO₃ · H₂O	Mon. 2/m : P2₁/c
4.CB.	Pengite	(Pb₈Sb³⁺₃)_Σ11Sb⁵⁺₉O₃₅	Trig. 3m(32/m) : R3m
4.CB.05	Brizziite	NaSb⁵⁺O₃	Trig. 3 : R3
4.CB.05	Tistarite	Ti³⁺₂O₃	Trig. 3m(32/m) : R3c
4.CB.05	Hematite	Fe₂O₃	Trig. 3m(32/m) : R3c
4.CB.05	Ecandrewsite	ZnTiO₃	Trig. 3 : R3
4.CB.05	Melanostibite	Mn²⁺₂Fe³⁺Sb⁵⁺O₆	Trig. 3 : R3
4.CB.05	'UM1998-11-O-AuHSb'	Au⁺₂Sb³⁺O₂(OH)
4.CB.05	Karelianite	V³⁺₂O₃	Trig. 3m(32/m) : R3c
4.CB.05	Corundum	Al₂O₃	Trig. 3m(32/m) : R3c
4.CB.05	Eskolaite	Cr₂O₃	Trig. 3m(32/m) : R3c
4.CB.05	Geikielite	MgTiO₃	Trig. 3 : R3
4.CB.05	Akimotoite	MgSiO₃	Trig. 3 : R3
4.CB.05	'Unnamed (Fe-Cr Oxide)'	FeCrO₃	Trig. 3 : R3
4.CB.05	'Auroantimonate'	AuSbO₃
4.CB.05	Hemleyite	Fe²⁺SiO₃	Trig. 3 : R3
4.CB.05	Ilmenite	Fe²⁺TiO₃	Trig. 3 : R3
4.CB.05	Pyrophanite	Mn²⁺TiO₃	Trig. 3 : R3
4.CB.10	Bixbyite-(Fe)	(Fe,Mn)₂O₃	Iso.
4.CB.10	Bixbyite-(Mn)	Mn³⁺₂O₃	Iso. m3(2/m3) : Ia3
4.CB.10	Avicennite	Tl³⁺₂O₃	Iso. m3(2/m3) : Ia3
4.CB.15	Armalcolite	MgTi⁴⁺₂O₅	Orth. mmm(2/m2/m2/m)
4.CB.15	Ferropseudobrookite	Fe²⁺Ti⁴⁺₂O₅	Orth. mmm(2/m2/m2/m) : Cmcm
4.CB.15	Griffinite	Al₂Ti⁴⁺O₅	Orth. mmm(2/m2/m2/m) : Cmcm
4.CB.15	Pseudobrookite Group
4.CB.15	Sassite	Ti³⁺₂Ti⁴⁺O₅	Orth. mmm(2/m2/m2/m) : Cmcm
4.CB.15	Pseudobrookite	Fe³⁺₂Ti⁴⁺O₅	Orth. mmm(2/m2/m2/m) : Cmcm
4.CB.20	Zincovelesite-6N6S	Zn₃(Fe³⁺,Mn³⁺,Al,Ti)₈O₁₅(OH)	Trig. 3m(32/m) : P3m1
4.CB.20	Magnesiohögbomite-2N4S	(Mg_8.43Fe²⁺_1.57)_Σ=10Al₂₂Ti⁴⁺₂O₄₆(OH)₂	Hex. 6mm : P6₃mc
4.CB.20	Magnesiobeltrandoite-2N3S	(Mg₆Al₂)(Al₁₈Fe³⁺₂)O₃₈(OH)₂	Trig. 3m : P3m1
4.CB.20	Zincohögbomite-2N6S	[(Zn,Mg)₇(Al,Fe³⁺,Ti)₁₆O₃₁(OH)]₂	Hex. 6mm : P6₃mc
4.CB.20	Magnesiohögbomite-6N6S	[(Mg,Fe²⁺)₃(Al,Ti,Fe³⁺)₈O₁₅(OH)]₆	Trig. 3m(32/m) : R3m
4.CB.20	Magnesiohögbomite-2N3S	[(Mg,Fe²⁺,Zn)₄(Al,Ti,Fe³⁺)₁₀O₁₉(OH)]₂	Trig. 3m(32/m) : P31m
4.CB.20	Magnesiohögbomite-2N2S	[(Mg,Fe²⁺)₃[Al₇(Ti,Fe³⁺)]O₁₅(OH)]₂	Hex. 6mm : P6₃mc
4.CB.20	'Ferrohögbomite-6N12S'	[(Fe²⁺,Mg,Zn)₅(Al,Ti,Fe³⁺)₁₂O₂₃(OH)]₆	Trig. 3m(32/m) : R3m
4.CB.20	Zincohögbomite-2N2S	[(Zn,Al,Fe²⁺)₃(Al,Fe³⁺,Ti)₈O₁₅(OH)]₂	Hex. 6mm : P6₃mc
4.CB.25	Kleberite	FeTi₆O₁₁(OH)₅	Mon. 2/m : P2₁/c
4.CB.25	Pseudorutile	Fe³⁺₂Ti⁴⁺₃O₉	Hex. 622 : P6₃22
4.CB.30	Oxyvanite	V³⁺₂V⁴⁺O₅	Mon. 2/m : B2/b
4.CB.30	Berdesinskiite	V³⁺₂TiO₅	Mon.
4.CB.30	Kaitianite	Ti³⁺₂Ti⁴⁺O₅	Mon. 2/m : B2/b
4.CB.35	Machiite	Al₂Ti₃O₉	Mon. 2/m : B2/b
4.CB.35	Vestaite	(Ti⁴⁺Fe²⁺)Ti⁴⁺₃O₉	Mon. 2/m : B2/b
4.CB.35	Olkhonskite	(Cr,V)₂Ti₃O₉	Mon.
4.CB.35	Schreyerite	V³⁺₂Ti⁴⁺₃O₉	Mon. 2/m : B2/b
4.CB.40	Zincorinmanite-(Zn)	Zn₂Sb₂(Fe³⁺₄Zn₂)O₁₄(OH)₂	Hex. 6mm : P6₃mc
4.CB.40	Majindeite	Mg₂Mo₃O₈	Hex. 6mm : P6₃mc
4.CB.40	Almagreraite	CuZnMn⁴⁺₃O₈	Orth. mm2 : Pmn2₁
4.CB.40	Kamiokite	Fe₂Mo₃O₈	Hex. 6mm : P6₃mc
4.CB.40	Nolanite	V³⁺₈Fe³⁺₂O₁₄(OH)₂	Hex. 6mm : P6₃mc
4.CB.40	Iseite	Mn₂Mo₃O₈	Hex. 6mm : P6₃mc
4.CB.40	Rinmanite	Zn₂Sb₂Mg₂Fe₄O₁₄(OH)₂	Hex. 6 : P6₃
4.CB.45	Stibioclaudetite	AsSbO₃	Mon. 2/m : P2₁/m
4.CB.45

Senarmontite

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