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Kamiokite

A valid IMA mineral species
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About KamiokiteHide

00628710017271924274556.jpg
Distant view of Nijyuugoyama and Kamioka adit

Nijuugoyama, Kamioka Mine, Hida City, Gifu Prefecture, Japan
Formula:
Fe2Mo3O8
Colour:
Black, grey with olive tint in reflected light
Lustre:
Metallic, Sub-Metallic
Hardness:
4½
Specific Gravity:
5.96
Crystal System:
Hexagonal
Name:
Named by D. Picot and Z. Johan in 1977 for the type locality, Kamioka mine, Japan.
Isostructural with:
The iron analogue of iseite and majindeite.


Unique IdentifiersHide

Mindat ID:
2147
Long-form identifier:
mindat:1:1:2147:6

IMA Classification of KamiokiteHide

Classification of KamiokiteHide

4.CB.40

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
C : Metal: Oxygen = 2: 3,3: 5, and similar
B : With medium-sized cations
7.6.3.1

7 : MULTIPLE OXIDES
6 : (AB)5X8
27.3.13

27 : Sulphites, Chromates, Molybdates and Tungstates
3 : Molybdates

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
KmkIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of KamiokiteHide

Metallic, Sub-Metallic
Transparency:
Opaque
Colour:
Black, grey with olive tint in reflected light
Streak:
Black
Hardness:
4½ on Mohs scale
Hardness:
VHN50=600 kg/mm2 (15 s test time) - Vickers
Cleavage:
Perfect
on [0001]
Density:
5.96 g/cm3 (Measured)    6.02 g/cm3 (Calculated)

Optical Data of KamiokiteHide

Type:
Uniaxial (-)
Anisotropism:
Strong - light brownish gray to dark greenish gray
Colour in reflected light:
grey, olive tint
Internal Reflections:
None

Chemistry of KamiokiteHide

Mindat Formula:
Fe2Mo3O8
Element Weights:
Element% weight
Mo54.568 %
O24.262 %
Fe21.171 %

Calculated from ideal end-member formula.
Mo
O
Fe

Crystallography of KamiokiteHide

Crystal System:
Hexagonal
Class (H-M):
6mm - Dihexagonal Pyramidal
Space Group:
P63mc
Cell Parameters:
a = 5.781(1) Å, c = 10.060(1) Å
Ratio:
a:c = 1 : 1.74
Unit Cell V:
291.16 ų (Calculated from Unit Cell)
Z:
2

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0010022KamiokiteKanazawa Y, Sasaki A (1986) Structure of kamiokite Acta Crystallographica C42 9-111986Kamioka mine, Gifu Prefecture, Japan0293
0016631Kamiokitele Page Y, Strobel P (1982) Structure of Iron(II) Molybdenum(IV) Oxide Fe2 Mo3 O8 _cod_database_code 1008752 Acta Crystallographica B38 1265-126719820293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
5.03 Å(100)
3.55 Å(90)
2.509 Å(75b)
2.430 Å(55)
2.006 Å(40)
2.785 Å(35)
1.5678 Å(35)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Near-surface Processes
23 : Subaerial aqueous alteration by non-redox-sensitive fluids (see also #47)
Stage 5: Initiation of plate tectonics<3.5-2.5
40 : Regional metamorphism (greenschist, amphibolite, granulite facies)

Type Occurrence of KamiokiteHide

General Appearance of Type Material:
thick tabular hexagonal crystals to 3 mm
Place of Conservation of Type Material:
Geology Museum (Geological Survey of Japan)
Geological Setting of Type Material:
Vein in a skarn
Associated Minerals at Type Locality:

Synonyms of KamiokiteHide

Other Language Names for KamiokiteHide

Dutch:Kamiokiet
German:Kamiokit
Spanish:Kamiokita

Relationship of Kamiokite to other SpeciesHide

Other Members of Kamiokite Group:
IseiteMn2Mo3O8Hex. 6mm : P63mc
MajindeiteMg2Mo3O8Hex. 6mm : P63mc

Common AssociatesHide

Associations Based on Photo Data:
5 photos of Kamiokite associated with MolybdeniteMoS2
2 photos of Kamiokite associated with JordisiteMoS2
2 photos of Kamiokite associated with IlsemanniteMo3O8 · nH2O
2 photos of Kamiokite associated with FerrimolybditeFe2(MoO4)3 · nH2O
2 photos of Kamiokite associated with FluoriteCaF2
1 photo of Kamiokite associated with MonipiteMoNiP
1 photo of Kamiokite associated with TugarinoviteMoO2
1 photo of Kamiokite associated with 'Apatite'Ca5(PO4)3A
1 photo of Kamiokite associated with MagnetiteFe2+Fe3+2O4
1 photo of Kamiokite associated with SpinelMgAl2O4

Related Minerals - Strunz-mindat GroupingHide

4.CB.Magnesiohögbomite-6N12SMg5Al11TiO23(OH)Trig. 3m(32/m) : R3m
4.CB.KidoditeBaMg2Fe16O27Hex. 6/mmm(6/m2/m2/m) : P63/mmc
4.CB.Ferrohögbomite-2N2S[(Fe2+,Mg,Zn,Al)3(Al,Ti,Fe3+)8O15(OH)]2Hex. 6mm : P63mc
4.CB.Zhenruite(MoO3)2 · H2OMon. 2/m : P21/m
4.CB.FuyuaniteMg7Nb6O18(OH)8Trig. 3 : P3
4.CB.VirgilluethiteMoO3 · H2OMon. 2/m : P21/c
4.CB.Pengite(Pb8Sb3+3)Σ11Sb5+9O35Trig. 3m(32/m) : R3m
4.CB.05BrizziiteNaSb5+O3Trig. 3 : R3
4.CB.05TistariteTi3+2O3Trig. 3m(32/m) : R3c
4.CB.05HematiteFe2O3Trig. 3m(32/m) : R3c
4.CB.05EcandrewsiteZnTiO3Trig. 3 : R3
4.CB.05MelanostibiteMn2+2Fe3+Sb5+O6Trig. 3 : R3
4.CB.05'UM1998-11-O-AuHSb'Au+2Sb3+O2(OH)
4.CB.05KarelianiteV3+2O3Trig. 3m(32/m) : R3c
4.CB.05CorundumAl2O3Trig. 3m(32/m) : R3c
4.CB.05EskolaiteCr2O3Trig. 3m(32/m) : R3c
4.CB.05GeikieliteMgTiO3Trig. 3 : R3
4.CB.05AkimotoiteMgSiO3Trig. 3 : R3
4.CB.05'Unnamed (Fe-Cr Oxide)'FeCrO3Trig. 3 : R3
4.CB.05'Auroantimonate'AuSbO3
4.CB.05HemleyiteFe2+SiO3Trig. 3 : R3
4.CB.05IlmeniteFe2+TiO3Trig. 3 : R3
4.CB.05PyrophaniteMn2+TiO3Trig. 3 : R3
4.CB.10Bixbyite-(Fe)(Fe,Mn)2O3Iso.
4.CB.10Bixbyite-(Mn)Mn3+2O3Iso. m3(2/m3) : Ia3
4.CB.10AvicenniteTl3+2O3Iso. m3(2/m3) : Ia3
4.CB.15ArmalcoliteMgTi4+2O5Orth. mmm(2/m2/m2/m)
4.CB.15FerropseudobrookiteFe2+Ti4+2O5Orth. mmm(2/m2/m2/m) : Cmcm
4.CB.15GriffiniteAl2Ti4+O5Orth. mmm(2/m2/m2/m) : Cmcm
4.CB.15Pseudobrookite Group
4.CB.15SassiteTi3+2Ti4+O5Orth. mmm(2/m2/m2/m) : Cmcm
4.CB.15PseudobrookiteFe3+2Ti4+O5Orth. mmm(2/m2/m2/m) : Cmcm
4.CB.20Zincovelesite-6N6SZn3(Fe3+,Mn3+,Al,Ti)8O15(OH)Trig. 3m(32/m) : P3m1
4.CB.20Magnesiohögbomite-2N4S(Mg8.43Fe2+1.57)Σ=10Al22Ti4+2O46(OH)2Hex. 6mm : P63mc
4.CB.20Magnesiobeltrandoite-2N3S(Mg6Al2)(Al18Fe3+2)O38(OH)2 Trig. 3m : P3m1
4.CB.20Zincohögbomite-2N6S[(Zn,Mg)7(Al,Fe3+,Ti)16O31(OH)]2Hex. 6mm : P63mc
4.CB.20Magnesiohögbomite-6N6S[(Mg,Fe2+)3(Al,Ti,Fe3+)8O15(OH)]6Trig. 3m(32/m) : R3m
4.CB.20Magnesiohögbomite-2N3S[(Mg,Fe2+,Zn)4(Al,Ti,Fe3+)10O19(OH)]2Trig. 3m(32/m) : P31m
4.CB.20Magnesiohögbomite-2N2S[(Mg,Fe2+)3[Al7(Ti,Fe3+)]O15(OH)]2Hex. 6mm : P63mc
4.CB.20'Ferrohögbomite-6N12S'[(Fe2+,Mg,Zn)5(Al,Ti,Fe3+)12O23(OH)]6Trig. 3m(32/m) : R3m
4.CB.20Zincohögbomite-2N2S[(Zn,Al,Fe2+)3(Al,Fe3+,Ti)8O15(OH)]2Hex. 6mm : P63mc
4.CB.25KleberiteFeTi6O11(OH)5Mon. 2/m : P21/c
4.CB.25PseudorutileFe3+2Ti4+3O9Hex. 622 : P6322
4.CB.30