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Arsenatrotitanite
A valid IMA mineral species
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About Arsenatrotitanite
Formula:
NaTi(AsO4)O
Colour:
brownish red, pale pinkish-reddish, almost colourless
Lustre:
Vitreous
Hardness:
5½
Specific Gravity:
3.950 (Calculated)
Crystal System:
Monoclinic
Member of:
Name:
For being the Na and As analogue of titanite
Unique Identifiers
Mindat ID:
47915
Long-form identifier:
mindat:1:1:47915:4
IMA Classification of Arsenatrotitanite
Approved
IMA Formula:
NaTi4+(As5+O4)O
Approval year:
2016
First published:
2019
Type description reference:
Pekov, Igor V., Zubkova, Natalia V., Agakhanov, Atali A., Belakovskiy, Dmitry I., Vigasina, Marina F., Yapaskurt, Vasiliy O., Sidorov, Evgeny G., Britvin, Sergey N., Pushcharovsky, Dmitry Y. (2019) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. IX. Arsenatrotitanite, NaTiO(AsO4) Mineralogical Magazine, 83 (3) 453-458 doi:10.1180/mgm.2018.134
Classification of Arsenatrotitanite
8.BH.10
8 : PHOSPHATES, ARSENATES, VANADATES
B : Phosphates, etc., with additional anions, without H2O
H : With medium-sized and large cations, (OH,etc.):RO4 = 1:1
8 : PHOSPHATES, ARSENATES, VANADATES
B : Phosphates, etc., with additional anions, without H2O
H : With medium-sized and large cations, (OH,etc.):RO4 = 1:1
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Anttn | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Arsenatrotitanite
Vitreous
Transparency:
Transparent
Colour:
Brownish red, pale pinkish-reddish, almost colourless
Streak:
White
Hardness:
5½ on Mohs scale
Hardness Data:
Measured
Tenacity:
Brittle
Cleavage:
Perfect
On {110}
On {110}
Fracture:
Step-Like
Density:
3.950 g/cm3 (Calculated)
Optical Data of Arsenatrotitanite
Type:
Biaxial (+)
RI values:
nα = 1.825(5) nβ = 1.847(6) nγ = 1.896(6)
2V:
Measured: 70° (5), Calculated: 69°
Max. Birefringence:
δ = 0.071
Based on recorded range of RI values above.
Based on recorded range of RI values above.
Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.
Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.
Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.
Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).
Relative to Canada balsam mounting medium (n ≈ 1.537).
This shows the grain boundary and Becke line effect under plane-polarised
light, based on the contrast between this mineral's average refractive
index and the mounting medium. It does not take into account mineral
colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure
- the conoscopic view for a grain cut perpendicular to the acute bisectrix, using
this mineral's 2V. The two small white dots mark the melatopes - the points
where the two optic axes emerge - and are shown only when they fall within the
field of view. The coloured bands are isochromatics, and the dark bands are
isogyres.
Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
strong, r> v
Pleochroism:
Strong
Comments:
Z (bright pink to, in thicker grains, carmin red) > Y(very pale pinkish to almost colourless) ≥ X(colourless)
Comments:
Y = b
Chemistry of Arsenatrotitanite
Mindat Formula:
NaTi(AsO4)O
Element Weights:
Elements listed:
Crystallography of Arsenatrotitanite
Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/b
Setting:
C2/c
Cell Parameters:
a = 6.6979(3) Å, b = 8.7630(3) Å, c = 7.1976(3) Å
β = 114.805(5)°
β = 114.805(5)°
Ratio:
a:b:c = 0.764 : 1 : 0.821
Unit Cell V:
383.48 ų
Z:
4
Morphology:
Prismatic, tabular or lamellar, wedge-shaped
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 4.845 Å | (89) |
| 3.631 Å | (36) |
| 3.431 Å | (48) |
| 3.300 Å | (100) |
| 3.036 Å | (100) |
| 2.655 Å | (25) |
| 2.627 Å | (91) |
| 2.615 Å | (57) |
Reference:
Pekov, Igor V., Zubkova, Natalia V., Agakhanov, Atali A., Belakovskiy, Dmitry I., Vigasina, Marina F., Yapaskurt, Vasiliy O., Sidorov, Evgeny G., Britvin, Sergey N., Pushcharovsky, Dmitry Y. (2019) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. IX. Arsenatrotitanite, NaTiO(AsO4) Mineralogical Magazine, 83 (3) 453-458 doi:10.1180/mgm.2018.134
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 7: Great Oxidation Event | <2.4 |
| 45a : [Sulfates, arsenates, selenates, antimonates] | |
| 45b : [Other oxidized fumarolic minerals] |
Type Occurrence of Arsenatrotitanite
General Appearance of Type Material:
Prismatic, tabular, lamellar or acicular crystals up to 0.3×0.8×2 mm. They are separated or combined in open-work aggregates up to 2 mm across or interrupted crusts up to 2x5 mm2 in area and up to 0.3 mm thick.
Place of Conservation of Type Material:
Collections of the Fersman Mineralogical Museum of the Russian Academy of Sciences, Moscow, Russia (registration number 4852/1)
Geological Setting of Type Material:
Fumarole
Associated Minerals at Type Locality:
Reference:
Pekov, Igor V., Zubkova, Natalia V., Agakhanov, Atali A., Belakovskiy, Dmitry I., Vigasina, Marina F., Yapaskurt, Vasiliy O., Sidorov, Evgeny G., Britvin, Sergey N., Pushcharovsky, Dmitry Y. (2019) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. IX. Arsenatrotitanite, NaTiO(AsO4) Mineralogical Magazine, 83 (3) 453-458 doi:10.1180/mgm.2018.134
Synonyms of Arsenatrotitanite
Other Language Names for Arsenatrotitanite
Relationship of Arsenatrotitanite to other Species
Member of:
Other Members of Tilasite Group:
| Durangite | NaAl(AsO4)F | Mon. 2/m : B2/b |
| Isokite | CaMg(PO4)F | Mon. 2/m : B2/b |
| Kononovite | NaMg(SO4)F | Mon. 2/m : B2/b |
| Lacroixite | NaAl(PO4)F | Mon. 2/m : B2/b |
| Maxwellite | NaFe3+(AsO4)F | Mon. 2/m : P2/c |
| Panasqueiraite | CaMg(PO4)(OH) | Mon. |
| Reznitskyite | CaMg(VO4)F | Mon. 2/m : B2/b |
| Tilasite | CaMg(AsO4)F | Mon. |
Related Minerals - Strunz-mindat Grouping
| 8.BH. | Peterchinite | Zn3Zn2(OH)6As[O3(OH)3] |
| 8.BH. | Reznitskyite | CaMg(VO4)F |
| 8.BH. | Plumbogottlobite | PbMg(VO4)(OH) |
| 8.BH. | Cuprozheshengite | Pb4CuZn2(AsO4)2(PO4)2(OH)2 |
| 8.BH. | Zheshengite | Pb4ZnZn2(AsO4)2(PO4)2(OH)2 |
| 8.BH. | Crimsonite | PbFe3+2(PO4)2(OH)2 |
| 8.BH.05 | Thadeuite | Ca(Mg,Fe2+)3(PO4)2(OH,F)2 |
| 8.BH.10 | Panasqueiraite | CaMg(PO4)(OH) |
| 8.BH.10 | Isokite | CaMg(PO4)F |
| 8.BH.10 | Lacroixite | NaAl(PO4)F |
| 8.BH.10 | Maxwellite | NaFe3+(AsO4)F |
| 8.BH.10 | Durangite | NaAl(AsO4)F |
| 8.BH.10 | Kononovite | NaMg(SO4)F |
| 8.BH.15 | Drugmanite | Pb2Fe3+(PO4)(PO3OH)(OH)2 |
| 8.BH.20 | Nigelcookite | PbFe2+2V3+2(PO4)3(OH)3 |
| 8.BH.20 | Plumbojohntomaite | PbFe2+2Fe3+2(PO4)3(OH)3 |
| 8.BH.20 | Cirrolite | Ca3Al2(PO4)3(OH)3 (?) |
| 8.BH.20 | Penikisite | Ba(Mg,Fe2+,Ca)2Al2(PO4)3(OH)3 |
| 8.BH.20 | Perloffite | Ba(Mn2+,Fe2+)2Fe3+2(PO4)3(OH)3 |
| 8.BH.20 | Bjarebyite Group | |
| 8.BH.20 | Strontioperloffite | SrMn2+2Fe3+2(PO4)3(OH)3 |
| 8.BH.20 | Plumboperloffite | PbMn2+2Fe3+2(PO4)3(OH)3 |
| 8.BH.20 | Johntomaite | BaFe2+2Fe3+2(PO4)3(OH)3 |
| 8.BH.20 | Bjarebyite | (Ba,Sr)(Mn2+,Fe2+,Mg)2Al2(PO4)3(OH)3 |
| 8.BH.20 | Kulanite | Ba(Fe2+,Mn2+,Mg)2(Al,Fe3+)2(PO4)3(OH)3 |
| 8.BH.25 | Bertossaite | Li2CaAl4(PO4)4(OH)4 |
| 8.BH.25 | Natropalermoite | Na2SrAl4(PO4)4(OH)4 |
| 8.BH.25 | Palermoite | Li2SrAl4(PO4)4(OH)4 |
| 8.BH.30 | Sewardite | CaFe3+2(AsO4)2(OH)2 |
| 8.BH.30 | Carminite | PbFe3+2(AsO4)2(OH)2 |
| 8.BH.35 | Adelite | CaMg(AsO4)(OH) |
| 8.BH.35 | Duftite | PbCu(AsO4)(OH) |
| 8.BH.35 | Cobaltaustinite | CaCo(AsO4)(OH) |
| 8.BH.35 | Nickelaustinite | CaNi(AsO4)(OH) |
| 8.BH.35 | Gabrielsonite | PbFe3+(As3+O3)O |
| 8.BH.35 | Conichalcite | CaCu(AsO4)(OH) |
| 8.BH.35 | Arsendescloizite | PbZn(AsO4)(OH) |
| 8.BH.35 | 'Duftite-alpha' | PbCu(AsO4)(OH) |
| 8.BH.35 | Gottlobite | CaMg(VO4)(OH) |
| 8.BH.35 | Austinite | CaZn(AsO4)(OH) |
| 8.BH.35 | Hermannroseite | CaCu(PO4)(OH) |
| 8.BH.35 | Tangeite | CaCu(VO4)(OH) |
| 8.BH.40 | Čechite | PbFe2+(VO4)(OH) |
| 8.BH.40 | Khorixasite | (Bi0.67◻0.33)Cu(VO4)(OH) |
| 8.BH.40 | Mottramite | PbCu(VO4)(OH) |
| 8.BH.40 | Descloizite | PbZn(VO4)(OH) |
| 8.BH.40 | Pyrobelonite | PbMn2+(VO4)(OH) |
| 8.BH.45 | Bayldonite | PbCu3(AsO4)2(OH)2 |
| 8.BH.45 | Vésigniéite | BaCu3(VO4)2(OH)2 |
| 8.BH.50 | Paganoite | NiBi(AsO4)O |
| 8.BH.55 | Jagowerite | BaAl2(PO4)2(OH)2 |
| 8.BH.55 | Harrisonite | Ca(Fe2+,Mg)6(PO4)2(SiO4)2 |
| 8.BH.60 | Attakolite | CaMn2+Al4(SiO3OH)(PO4)3(OH)4 |
| 8.BH.65 | Leningradite | PbCu3(VO4)2Cl |
| 8.BH.70 | Katiarsite | KTiO(AsO4) |
| 8.BH.70 | Yurgensonite | K2SnTiO2(AsO4)2 |
| 8.BH.75 | Melanarsite | K3Cu7Fe3+O4(AsO4)4 |
| 8.BH.80 | Evseevite | Na2Mg(AsO4)F |
| 8.BH.80 | Moraskoite | Na2Mg(PO4)F |
| 8.BH.85 | Piccoliite | NaCaMn3+2(AsO4)2O(OH) |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Arsenatrotitanite
mindat.org URL:
https://www.mindat.org/min-47915.html
Please feel free to link to this page.
Please feel free to link to this page.
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External Links:
Mineral Dealers:
References for Arsenatrotitanite
Reference List:
Hålenius, U., Hatert, F., Pasero, M., Mills, S. J. (2016) New minerals and nomenclature modifications approved in 2016, CNMNC Newsletter No. 33. Mineralogical Magazine, 80 (6) 1135-1144 doi:10.1180/minmag.2016.080.085
Pekov, Igor V., Zubkova, Natalia V., Agakhanov, Atali A., Belakovskiy, Dmitry I., Vigasina, Marina F., Yapaskurt, Vasiliy O., Sidorov, Evgeny G., Britvin, Sergey N., Pushcharovsky, Dmitry Y. (2019) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. IX. Arsenatrotitanite, NaTiO(AsO4) Mineralogical Magazine, 83 (3) 453-458 doi:10.1180/mgm.2018.134
Localities for Arsenatrotitanite
Showing 1 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Russia (TL) | |
| Pekov et al. (2019) +1 other reference |
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The
Arsenatnaya fumarole, Second scoria cone, Northern Breakthrough, Great Fissure eruption, Tolbachik Volcanic field, Milkovsky District, Kamchatka Krai, Russia