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Edwindavisite

A valid IMA mineral species
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About EdwindavisiteHide

Formula:
Cu(C2O4)(NH3)
Colour:
green
Lustre:
Vitreous
Hardness:
2
Specific Gravity:
2.55
Crystal System:
Orthorhombic
Name:
The new mineral name honors Mr. F. Edwin (Ed) Davis, Jr., an Arizona-based mineral collector and the current contractor operator of the Rowley mine, who has gladly accepted the proposed mineral name. Ed Davis graduated from Miami University in Oxford, Ohio, USA, with degrees in chemical engineering, mathematics and chemistry. He is credited for the discovery of the Purple Passion deposit near Wickenburg, Arizona, USA, which is world-renowned among fluorescent mineral collectors.
The first mineral species to combine oxalate anions and ammine ligands.

Yet another copper-ammine -complex-bearing mineral after ammineite and shilovite, chanabayaite, triazolite, and joanneumite.

Known synthetic analogue. Natural counterpart of synthetic catena-μ-oxalato-ammine-copper(II), Cu(C2O4)(NH3).


Unique IdentifiersHide

Mindat ID:
470888
Long-form identifier:
mindat:1:1:470888:5

IMA Classification of EdwindavisiteHide

Classification of EdwindavisiteHide

10.AB.

10 : ORGANIC COMPOUNDS
A : Salts of organic acids
B : Oxalates

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
EwdIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of EdwindavisiteHide

Vitreous
Transparency:
Transparent
Colour:
Green
Streak:
Pale green
Hardness:
Tenacity:
Brittle
Cleavage:
Perfect
{100}
Parting:
none
Density:
2.55(2) g/cm3 (Measured)    2.53 g/cm3 (Calculated)

Optical Data of EdwindavisiteHide

Type:
Biaxial (+)
RI values:
nα = 1.550(2) nβ = 1.559(2) nγ = 1.755(5)
2V:
Measured: 26° (2), Calculated: 2.64°
Max. Birefringence:
δ = 0.205
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
dispersion is distinct with r > v.
Pleochroism:
Visible
Comments:
pleochroism is X = light green, Y = pale green, Z = deep green, with Y < X << Z.

Chemistry of EdwindavisiteHide

Mindat Formula:
Cu(C2O4)(NH3)
Element Weights:
Element% weight
O37.959 %
Cu37.691 %
C14.248 %
N8.308 %
H1.794 %

Calculated from ideal end-member formula.
O
Cu
C
N
H

Crystallography of EdwindavisiteHide

Crystal System:
Orthorhombic
Class (H-M):
mmm(2/m2/m2/m) - Dipyramidal
Space Group:
Pbca
Setting:
Pbca
Cell Parameters:
a = 11.1998(10) Å, b = 9.4307(9) Å, c = 8.3977(7) Å
Ratio:
a:b:c = 1.188 : 1 : 0.89
Unit Cell V:
886.98 ų (Calculated from Unit Cell)
Z:
8
Twinning:
none

X-Ray Powder DiffractionHide

Type Occurrence of EdwindavisiteHide

General Appearance of Type Material:
occurs as fans or sprays of bladed or prismatic crystals (up to 0.50 x 0.08 x 0.06 mm),
Place of Conservation of Type Material:
collections of (1) the University of Arizona Alfie Norville Gem & Mineral Museum, 115 N Church Ave Ste 121, Tucson, AZ 85701, USA, catalogue no. 22732, the RRUFF Project, deposition no. R230005, and (2) the Natural History Museum of Los Angeles County, 900 Exposition Boulevard, Los Angeles, CA 90007, USA, catalogue numbers 76287 and 76288 (cotypes)
Geological Setting of Type Material:
The area where the edwindavisite specimens were collected has an unusual bat guano-related, secondary mineral assemblage, from which a number of new mineral species have been discovered. This mine is a former Cu-Pb-Au-Ag-Mo-V-baryte-fluorspar mine that exploited veins presumed to be related to the intrusion of an andesite porphyry dike into Tertiary volcanic rocks.
Associated Minerals at Type Locality:

Other Language Names for EdwindavisiteHide

Related Minerals - Strunz-mindat GroupingHide

10.AB.Deveroite-(Ce)Ce2(C2O4)3 · 10H2OMon. 2/m : P21/c
10.AB.XFalottaiteMnC2O4 · 3H2OOrth. mmm(2/m2/m2/m)
10.AB.Uroxite [(UO2)2(C2O4)(OH)2(H2O)2] · H2OMon. 2/m : P21/c
10.AB.05KatsarositeZn(C2O4) · 2H2OMon. 2/m : B2/b
10.AB.05AndreybulakhiteNi(C2O4) · 2H2OMon. 2/m : B2/b
10.AB.05HumboldtineFe2+(C2O4) · 2H2OMon. 2/m : B2/b
10.AB.05LindbergiteMn2+(C2O4) · 2H2OMon. 2/m : B2/b
10.AB.10GlushinskiteMg(C2O4) · 2H2OMon. 2/m : B2/b
10.AB.15MoolooiteCu(C2O4) · nH2OOrth.
10.AB.20StepanoviteNaMgFe3+(C2O4)3 · 8-9H2OTrig. 3m : P3c1
10.AB.25MinguzziteK3Fe3+(C2O4)3 · 3H2OMon. 2/m : P21/c
10.AB.30WheatleyiteNa2Cu(C2O4)2 · 2H2OTric. 1 : P1
10.AB.35ZhemchuzhnikoviteNaMgAl(C2O4)3 · 8H2OTrig. 3m : P3c1
10.AB.40WeddelliteCa(C2O4) · (2.5-x)H2OTet. 4/m : I4/m
10.AB.45WhewelliteCa(C2O4) · H2OMon. 2/m : P21/c
10.AB.47FiemmeiteCu2(C2O4)(OH)2 · 2H2OMon. 2/m : P21/c
10.AB.50CaoxiteCa(C2O4) · 3H2OTric. 1 : P1
10.AB.50MiddlebackiteCu2C2O4(OH)2Mon. 2/m : P21/c
10.AB.52Metauroxite(UO2)2(C2O4)(OH)2(H2O)2Tric. 1 : P1
10.AB.55Oxammite(NH4)2(C2O4) · H2OOrth. 222 : P21212
10.AB.60NatroxalateNa2(C2O4)Mon. 2/m : P21/c
10.AB.60Phoxite(NH4)2Mg2(C2O4)(PO3OH)2(H2O)4Mon. 2/m : P21/c
10.AB.60Carboferriphoxite[(NH4)K(H2CO3)][Fe3+(HPO4)(H2PO4)(C2O4)]Tric. 1 : P1
10.AB.60Ferriphoxite[(NH4)2K(H2O)][Fe3+(HPO4)2(C2O4)]Mon. 2/m : P21/c
10.AB.65Coskrenite-(Ce)Ce2(SO4)2(C2O4) · 8H2OTric.
10.AB.70Levinsonite-(Y)(Y,Nd,La)Al(C2O4)(SO4)2 · 12H2OMon. 2/m
10.AB.75Zugshunstite-(Ce)(Ce,Nd,La)Al(C2O4)(SO4)2 · 12H2OMon. 2/m : B2/b
10.AB.80NovgorodovaiteCa2(C2O4)Cl2 · 2H2OMon. 2/m : B2/m

Other InformationHide

Notes:
At room temperature, edwindavisite is insoluble in H2O, but easily soluble in dilute HCl.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for EdwindavisiteHide

References for EdwindavisiteHide

Localities for EdwindavisiteHide

Showing 1 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
USA (TL)
 
  • Arizona
    • Maricopa County
      • Painted Rock Mountains
        • Painted Rock Mining District
          • Theba
            • Rowley Mine
Bosi et al. (2023) +1 other reference
 
and/or  
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