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Aplowite

A valid IMA mineral species
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About AplowiteHide

02686730017271921121856.jpg
Albert P. Low
Formula:
CoSO4 · 4H2O
Originally given as (Co,Mn,Ni)SO4 · 4H2O.
Colour:
Bright pink
Lustre:
Vitreous
Hardness:
3
Specific Gravity:
2.33
Crystal System:
Monoclinic
Member of:
Name:
Named in honor of Albert Peter Low (24 May 1861, Montreal, Quebec, Canada - 9 October 1942, Ottawa, Ontario, Canada), geologist and former director of the Geological Survey of Canada. His explorations of 1893–1895 were important in declaring Canada's sovereignty over the Arctic.
Rozenite Group. The Co analogue of rozenite, ilesite, etc. Chemically also analogous to drobecite (same point group, different space group).

It is a higher hydrate when compared to cobaltkieserite, and lower hydrate when compared to bieberite and moorhouseite.


Unique IdentifiersHide

Mindat ID:
282
Long-form identifier:
mindat:1:1:282:8

IMA Classification of AplowiteHide

Classification of AplowiteHide

7.CB.15

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
C : Sulfates (selenates, etc.) without additional anions, with H2O
B : With only medium-sized cations
Dana 7th ed.:
29.6.6.4
29.6.6.4

29 : HYDRATED ACID AND NORMAL SULFATES
6 : AXO4·xH2O
25.12.3

25 : Sulphates
12 : Sulphates of Co and Ni

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
ApwIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of AplowiteHide

Vitreous
Transparency:
Translucent
Colour:
Bright pink
Streak:
White
Hardness:
Comment:
ca. 3
Density:
2.33 g/cm3 (Measured)    2.36 g/cm3 (Calculated)

Optical Data of AplowiteHide

Type:
Biaxial (-)
RI values:
nα = 1.528 nγ = 1.536
Max. Birefringence:
δ = 0.008
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
None to Very Low
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.

No measured or calculated 2V is on file for this mineral, so the value used here (90°) is estimated from its recorded refractive indices and optic sign, not from a direct 2V measurement.
Dispersion:
weak

Chemistry of AplowiteHide

Mindat Formula:
CoSO4 · 4H2O

Originally given as (Co,Mn,Ni)SO4 · 4H2O.
Element Weights:
Element% weight
O56.371 %
Co25.955 %
S14.122 %
H3.551 %

Calculated from ideal end-member formula.
O
Co
S
H
Common Impurities:
Mn,Ni

Crystallography of AplowiteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/c
Setting:
P21/n
Cell Parameters:
a = 5.93 Å, b = 13.54 Å, c = 7.88 Å
β = 90.55°
Ratio:
a:b:c = 0.438 : 1 : 0.582
Unit Cell V:
632.67 ų (Calculated from Unit Cell)
Z:
4

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0010272AplowiteKellersohn T (1992) Structure of cobalt sulfate tetrahydrate Acta Crystallographica C48 776-7791992synthetic0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
4.46 Å(100)
5.44 Å(90)
3.95 Å(80)
2.95 Å(70)
3.39 Å(60)
3.22 Å(50)
6.78 Å(40)
Comments:
Walton mine, Nova Scotia, Canada. Data from the type description.

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 7: Great Oxidation Event<2.4
47a : [Near-surface hydration of prior minerals]
47e : [Vanadates, chromates, manganates]
Stage 10b: Anthropogenic minerals<10 Ka
55 : Anthropogenic mine minerals

Type Occurrence of AplowiteHide

General Appearance of Type Material:
Efflorescences with sulfides
Place of Conservation of Type Material:
National School of Mines, Paris, France.
Canadian Geological Survey, Ottawa, Canada, 12145
Geological Setting of Type Material:
Efflorescences from a hydrothermal sulphide orebody associated with a large barite deposit.
Associated Minerals at Type Locality:

Synonyms of AplowiteHide

Other Language Names for AplowiteHide

Dutch:Aplowiet
French:Aplowite
German:Aplowit
Norwegian:Aplowitt
Spanish:Aplowita

Relationship of Aplowite to other SpeciesHide

Member of:
Other Members of Rozenite Group:
BoyleiteZnSO4 · 4H2OMon. 2/m : P21/c
DrobeciteCdSO4 · 4H2OMon. 2/m : P21/m
IlesiteMn2+(SO4) · 4H2OMon. 2/m
RozeniteFeSO4 · 4H2OMon. 2/m : P21/c
StarkeyiteMgSO4 · 4H2OMon. 2/m : P21/c

Common AssociatesHide

Associations Based on Photo Data:
2 photos of Aplowite associated with MoorhouseiteCo2+(H2O)6(SO4)
1 photo of Aplowite associated with GypsumCaSO4 · 2H2O

Related Minerals - Strunz-mindat GroupingHide

7.CB.SarvodaiteAl2(SO4)3 · 5H2OMon. 2/m : P21/c
7.CB.02VoudourisiteCdSO4 · H2OMon. 2/m : P21/m
7.CB.05SzmikiteMnSO4 · H2OMon. 2/m : B2/b
7.CB.05SzomolnokiteFeSO4 · H2OMon. 2/m : B2/b
7.CB.05CobaltkieseriteCoSO4 · H2OMon. 2/m : B2/b
7.CB.05DwornikiteNi(SO4) · H2OMon. 2/m : B2/b
7.CB.05KieseriteMgSO4 · H2OMon. 2/m : B2/b
7.CB.05Poitevinite(Cu,Fe)SO4 · H2OTric. 1 : P1
7.CB.05GunningiteZnSO4 · H2OMon. 2/m : B2/b
7.CB.07SanderiteMgSO4 · 2H2OOrth. 222 : P212121
7.CB.10BonattiteCuSO4 · 3H2OMon. m : Bb
7.CB.12BelogubiteCuZn(SO4)2 · 10H2OTric. 1 : P1
7.CB.15DrobeciteCdSO4 · 4H2OMon. 2/m : P21/m
7.CB.15CranswickiteMgSO4 · 4H2OMon. m : Bb
7.CB.15RozeniteFeSO4 · 4H2OMon. 2/m : P21/c
7.CB.15StarkeyiteMgSO4 · 4H2OMon. 2/m : P21/c
7.CB.15IlesiteMn2+(SO4) · 4H2OMon. 2/m
7.CB.15BoyleiteZnSO4 · 4H2OMon. 2/m : P21/c
7.CB.20SiderotilFeSO4 · 5H2OTric.
7.CB.20JôkokuiteMnSO4 · 5H2OTric. 1 : P1
7.CB.20PentahydriteMgSO4 · 5H2OTric. 1 : P1
7.CB.20ChalcanthiteCuSO4 · 5H2OTric. 1 : P1
7.CB.25ChvaleticeiteMn2+(H2O)6(SO4)Mon. 2/m : B2/b
7.CB.25NickelhexahydriteNi2+(H2O)6(SO4)Mon. 2/m : B2/b
7.CB.25HexahydriteMg(H2O)6(SO4)Mon. 2/m : P2/c
7.CB.25BianchiteZn(H2O)6(SO4)Mon. 2/m : P2/c
7.CB.25MoorhouseiteCo2+(H2O)6(SO4)Mon. 2/m : B2/b
7.CB.25FerrohexahydriteFe2+(H2O)6(SO4)Mon. 2/m : B2/b
7.CB.30RetgersiteNiSO4 · 6H2OTet. 422 : P41212
7.CB.35ZincmelanteriteZn(H2O)6(SO4) · H2OMon. 2/m : P21/c
7.CB.35MelanteriteFe2+(H2O)6(SO4) · H2OMon. 2/m : P21/c
7.CB.35Alpersite(Mg,Cu2+)(H2O)6(SO4) · H2OMon. 2/m : P21/c
7.CB.35BieberiteCo2+(H2O)6(SO4) · H2OMon. 2/m : P2/c
7.CB.35BoothiteCu2+(H2O)6(SO4) · H2OMon. 2/m : P21/c
7.CB.35MallarditeMn2+(H2O)6(SO4) · H2OMon. 2/m : P2/c
7.CB.40EpsomiteMgSO4 · 7H2OOrth. 222 : P212121
7.CB.40GoslariteZnSO4 · 7H2OOrth. 222 : P212121
7.CB.40MorenositeNiSO4 · 7H2OOrth. 222 : P212121
7.CB.45Meta-alunogenAl2(SO4)3 · 12H2OOrth.
7.CB.45AlunogenAl2(SO4)3 · 17H2OTric. 1 : P1
7.CB.50AluminocoquimbiteAl2Fe2(SO4)6(H2O)12 · 6H2OTrig. 3m(32/m) : P31c
7.CB.50LazaridisiteCd3(SO4)3 · 8H2OMon. 2/m : B2/b
7.CB.52PararaisaiteCuMg[Te6+O4(OH)2] · 6H2OMon. 2/m : P21/c
7.CB.55ParacoquimbiteFe4(SO4)6(H2O)12 · 6H2OTrig. 3 : R3
7.CB.55Rhomboclase(H5O2)Fe3+(SO4)2 · 2H2OOrth. mmm(2/m2/m2/m) : Pnma
7.CB.55RaisaiteCuMg[Te6+O4(OH)2] · 6H2OMon. 2/m : B2/b
7.CB.55CoquimbiteAlFe3(SO4)6(H2O)12 · 6H2OTrig. 3m(32/m) : P31c
7.CB.57'Caichengyunite'Fe2+3Al2(SO4)6 · 30H2OMon.
7.CB.60KorneliteFe2(SO4)3 · 7H2OMon. 2/m : P21/m
7.CB.65QuenstedtiteFe2(SO4)3 · 11H2OTric. 1 : P1
7.CB.70LauseniteFe2(SO4)3 · 5H2OMon. 2/m : P21/m
7.CB.75RömeriteFe2+Fe3+2(SO4)4 · 14H2OTric. 1 : P1
7.CB.75LishizheniteZnFe2(SO4)4 · 14H2OTric. 1 : P1
7.CB.80RansomiteCuFe2(SO4)4 · 6H2OMon. 2/m : P21/c
7.CB.85DietrichiteZnAl2(SO4)4 · 22H2OMon. 2/m : P21/c
7.CB.85HalotrichiteFe2+Al2(SO4)4 · 22H2OMon. 2 : P2
7.CB.85ApjohniteMn2+Al2(SO4)4 · 22H2OMon. 2/m : P21/c
7.CB.85RedingtoniteFe2+Cr3+2(SO4)4 · 22H2OMon. 2
7.CB.85PickeringiteMgAl2(SO4)4 · 22H2OMon. 2/m : P21/c
7.CB.85BíliniteFe2+Fe3+2(SO4)4 · 22H2OMon. 2/m : P21/c
7.CB.85WupatkiiteCo2+Al2(SO4)4 · 22H2OMon. 2/m : P21/c
7.CB.90MeridianiiteMgSO4 · 11H2OTric. 1 : P1

Other InformationHide

Notes:
Water soluble.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for AplowiteHide

References for AplowiteHide

Localities for AplowiteHide

Showing 12 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Canada (TL)
 
  • Nova Scotia
    • Hants Co.
      • Walton
Transactions of the Canadian Institute ... +1 other reference
China
 
  • Qinghai
    • Haixi Mongol and Tibetan Autonomous Prefecture
      • Golmud City (Ge'ermu Co.)
Niu et al. (2023)
Niu et al. (2023)
Costa Rica
 
  • Cartago Province
    • Oreamuno Canton
      • Irazú Volcano
Ulloa et al. (2018)
Greece
 
  • Attica
    • East Attica
      • Lavreotiki
        • Plaka
          • Plaka Mines
Hanke et al. (1994)
Rieck (n.d.)
  • Eastern Macedonia and Thrace
    • Evros
      • Alexandroupoli
Skarpelis et al. (2004)
Norway
 
  • Nordland
    • Hamarøy
      • Drag
        • Lapplægeret
Husdal (2019)
Russia
 
  • Murmansk Oblast
  • Orenburg Oblast
Shcherbakova (2004)
  • Zabaykalsky Krai
    • Nerchinsky District
      • Adun-Cholon Range
Kasatkin et al. (2014)
USA
 
  • Alaska
    • Valdez-Cordova Census Area
      • Chisana Mining District
U. S. Geological Survey Open-File ...
 
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