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Shirozulite

A valid IMA mineral species
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About ShirozuliteHide

01843370017271929836965.jpg
Dr. Haruo Shirozu
Formula:
KMn2+3(Si3Al)O10(OH)2
Mn(II) may be replaced by minor Mg.
Colour:
Dark reddish brown
Lustre:
Pearly
Hardness:
3
Specific Gravity:
3.2
Crystal System:
Monoclinic
Name:
Named by K. Ishida, F.C. Hawthorne and F. Hirowatari in honor of Haruo Shirozu (白水晴雄) (1925-2007), Professor at Kyushu University, for his outstanding contributions to the crystal-chemistry of sheet-silicate minerals, especially the chlorite group.

Unique IdentifiersHide

Mindat ID:
11466
Long-form identifier:
mindat:1:1:11466:4

IMA Classification of ShirozuliteHide

Classification of ShirozuliteHide

9.EC.20

9 : SILICATES (Germanates)
E : Phyllosilicates
C : Phyllosilicates with mica sheets, composed of tetrahedral and octahedral nets

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
SzuIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of ShirozuliteHide

Pearly
Transparency:
Transparent
Colour:
Dark reddish brown
Hardness:
Tenacity:
Elastic
Cleavage:
Perfect
on (001)
Fracture:
Micaceous
Density:
3.2 g/cm3 (Measured)    

Chemistry of ShirozuliteHide

Mindat Formula:
KMn2+3(Si3Al)O10(OH)2

Mn(II) may be replaced by minor Mg.
Element Weights:
Element% weight
O37.708 %
Mn32.370 %
Si16.548 %
K7.679 %
Al5.299 %
H0.396 %

Calculated from ideal end-member formula.
O
Mn
Si
K
Al
H

Crystallography of ShirozuliteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/m
Setting:
C2/m
Cell Parameters:
a = 5.3791 Å, b = 9.319 Å, c = 10.2918 Å
β = 100.18°
Ratio:
a:b:c = 0.577 : 1 : 1.104
Unit Cell V:
507.78 ų (Calculated from Unit Cell)

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0003404ShirozuliteIshida K, Hawthorne F C, Hirowatari F (2004) Shirozulite, KMn3(Si3Al)O10(OH)2, a new manganese-dominant trioctahedral mica: Description and crystal structure American Mineralogist 89 232-23820040293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
High-𝑇 alteration and/or metamorphism
32 : Ba/Mn/Pb/Zn deposits, including metamorphic deposits

Type Occurrence of ShirozuliteHide

General Appearance of Type Material:
Grains to 0.5 mm across.
Place of Conservation of Type Material:
Graduate School of Social and Cultural Studies, Kyushu University, Fukuoka, Japan.
Geological Setting of Type Material:
Contact of barium-rich K feldspars to metamorphosed manganese ores.
Associated Minerals at Type Locality:

Synonyms of ShirozuliteHide

Other Language Names for ShirozuliteHide

Relationship of Shirozulite to other SpeciesHide

Other Members of Trioctahedral mica:
AspidoliteNaMg3(AlSi3O10)(OH)2Mon. 2/m : B2/m
BalestraiteKLi2V5+Si4O12Mon. 2 : B2
BiotiteK(Fe2+/Mg)2(Al/Fe3+/Mg/Ti)([Si/Al/Fe]2Si2O10)(OH/F)2
EphesiteNaLiAl2(Al2Si2O10)(OH)2Tric. 1 : P1
GarmiteCsLiMg2(Si4O10)F2Mon.
HendricksiteKZn3(Si3Al)O10(OH)2Mon. 2/m : B2/m
KreiteriteCsLi2Fe3+(Si4O10)F2Mon.
LepidoliteA field name for the group of Li-rich micas in, or close to, the so-called Polylithionite-Trilithionite ...
MasutomiliteK(LiAlMn2+)[AlSi3O10]F2Mon. 2 : B2
NorrishiteKLiMn3+2(Si4O10)O2Mon. 2/m : B2/m
OrloviteKLi2Ti(Si4O10)OFMon. 2 : B2
PreiswerkiteNaMg2Al(Al2Si2O10)(OH)2Mon. 2/m : B2/b
ShirokshiniteK(NaMg2)(Si4O10)F2Mon. 2/m : B2/m
SokolovaiteCsLi2Al(Si4O10)F2Mon.
Suhailite(NH4)Fe2+3(AlSi3O10)(OH)2Mon. 2/m : B2/m
TainioliteKLiMg2(Si4O10)F2Mon. 2/m : B2/m
Wonesite(Na,K,◻)(Mg,Fe,Al)6(Si,Al)8O20(OH,F)4Mon. 2/m : B2/m
'Zinnwaldite'Mica Group.

Common AssociatesHide

Associations Based on Photo Data:
4 photos of Shirozulite associated with TephroiteMn2+2(SiO4)
1 photo of Shirozulite associated with CalciteCaCO3
1 photo of Shirozulite associated with Epidote(CaCa)(AlAlFe3+)O[Si2O7][SiO4](OH)
1 photo of Shirozulite associated with QuartzSiO2

Related Minerals - Strunz-mindat GroupingHide

9.EC.MeifuiteKFe6(Si7Al)O19(OH)4Cl2Tric. 1 : P1
9.EC.BalestraiteKLi2V5+Si4O12Mon. 2 : B2
9.EC.VoloshiniteRb(LiAl1.5◻0.5)(Al0.5Si3.5)O10F2Mon. 2/m : B2/b
9.EC.05TalcMg3Si4O10(OH)2Tric. 1 : P1
9.EC.05MinnesotaiteFe2+3Si4O10(OH)2Tric. 1 : P1
9.EC.05WillemseiteNi3Si4O10(OH)2Mon.
9.EC.10FluorluanshiweiiteKLiAl1.5(Si3.5Al0.5)O10F2Mon. 2/m : B2/m
9.EC.10GarmiteCsLiMg2(Si4O10)F2Mon.
9.EC.10GorbunoviteCsLi2(Ti,Fe)Si4O10(F,OH,O)2Mon.
9.EC.10FerripyrophylliteFe3+Si2O5(OH)Mon. 2/m
9.EC.10ManganiceladoniteK(MgMn3+◻)(Si4O10)(OH)2Mon.
9.EC.10LuanshiweiiteKLiAl1.5(Si3.5Al0.5)O10(OH)2Mon. 2/m : B2/b
9.EC.10PyrophylliteAl2Si4O10(OH)2Tric. 1
9.EC.15ParagoniteNaAl2(AlSi3O10)(OH)2Mon.
9.EC.15FerroaluminoceladoniteK(Fe2+Al◻)(Si4O10)(OH)2Mon. 2/m : B2/m
9.EC.15NanpingiteCsAl2(AlSi3O10)(OH,F)2Mon. 2/m : B2/b
9.EC.15FerroceladoniteK(Fe2+Fe3+◻)(Si4O10)(OH)2Mon. 2/m : B2/m
9.EC.15GanteriteBa0.5(Na,K)0.5Al2(Si2.5Al1.5)O10(OH)2Mon. 2/m : B2/b
9.EC.15KreiteriteCsLi2Fe3+(Si4O10)F2Mon.
9.EC.15RoscoeliteKV3+2(AlSi3O10)(OH)2Mon. 2/m : B2/b
9.EC.15AluminoceladoniteK(MgAl◻)(Si4O10)(OH)2Mon. 2/m : B2/m
9.EC.15Tobelite(NH4)Al2(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.15TainioliteKLiMg2(Si4O10)F2Mon. 2/m : B2/m
9.EC.15CeladoniteK(MgFe3+◻)(Si4O10)(OH)2Mon. 2/m : B2/m
9.EC.15ChromceladoniteK(MgCr◻)(Si4O10)(OH)2Mon. 2 : B2
9.EC.15MontdoriteKFe2+1.5Mn2+0.5Mg0.5Si4O10(F,OH)2Mon. 2/m : B2/m
9.EC.15ChromphylliteKCr2(AlSi3O10)(OH)2Mon. 2/m : B2/b
9.EC.15BoromuscoviteKAl2(BSi3O10)(OH)2Mon. 2/m
9.EC.15'UM1988-22-SiO:AlCaFFeHKLiMg'KLiMgAl2Si3O10F2Mon.
9.EC.15Chernykhite(Ba,Na)(V3+,Al,Mg)2((Si,Al)4O10)(OH)2Mon.
9.EC.15MuscoviteKAl2(AlSi3O10)(OH)2Mon. 2/m : B2/b
9.EC.20MasutomiliteK(LiAlMn2+)[AlSi3O10]F2Mon. 2 : B2
9.EC.20OxyphlogopiteK(Mg,Ti,Fe)3[(Si,Al)4O10](O,F)2Mon. 2/m : B2/m
9.EC.20'Chloroferrokinoshitalite'(Ba,K)(Fe2+,Mg)3(Al2Si2O10)(Cl,OH,F)2
9.EC.20SiderophylliteKFe2+2Al(Al2Si2O10)(OH)2Mon.
9.EC.20SokolovaiteCsLi2Al(Si4O10)F2Mon.
9.EC.20HendricksiteKZn3(Si3Al)O10(OH)2Mon. 2/m : B2/m
9.EC.20TetraferriphlogopiteKMg3(Si3Fe3+)O10(OH)2Mon. 2/m : B2/m
9.EC.20FluoranniteKFe2+3(Si3Al)O10F2Mon. 2/m : B2/m
9.EC.20AspidoliteNaMg3(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.20Suhailite(NH4)Fe2+3(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.20EphesiteNaLiAl2(Al2Si2O10)(OH)2Tric. 1 : P1
9.EC.20NorrishiteKLiMn3+2(Si4O10)O2Mon. 2/m : B2/m
9.EC.20PhlogopiteKMg3(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.20YangzhumingiteKMg2.5(Si4O10)F2Mon. 2/m : B2/m
9.EC.20OrloviteKLi2Ti(Si4O10)OFMon. 2 : B2
9.EC.20TetraferrianniteKFe2+3(Si3Fe3+)O10(OH)2Mon. 2/m : B2/m
9.EC.20ShirokshiniteK(NaMg2)(Si4O10)F2Mon. 2/m : B2/m
9.EC.20TrilithioniteK(Li1.5Al1.5)(AlSi3O10)(F,OH)2Mon. 2/m : B2/b
9.EC.20PolylithioniteKLi2Al(Si4O10)(F,OH)2Mon. 2/m : B2/b
9.EC.20PreiswerkiteNaMg2Al(Al2Si2O10)(OH)2Mon. 2/m : B2/b
9.EC.20FluorophlogopiteKMg3(Si3Al)O10F2Mon. 2/m : B2/m
9.EC.20Wonesite(Na,K,◻)(Mg,Fe,Al)6(Si,Al)8O20(OH,F)4Mon. 2/m : B2/m
9.EC.20'UM2004-49-SiO:AlCsFHKLi'(Cs,K)(Al,Li)2.6((Si,Al)4O10)(F,OH)2
9.EC.20FluorotetraferriphlogopiteKMg3(Fe3+Si3O10)F2Mon. 2/m : B2/m
9.EC.20AnniteKFe2+3(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.20EastoniteKMg2Al(Al2Si2O10)(OH)2Mon.
9.EC.22'Pimelite'Ni3Si4O10(OH)2 · 4H2OHex.
9.EC.30MargariteCaAl2(Al2Si2O10)(OH)2Mon. 2/m : B2/b
9.EC.35Kinoshitalite(Ba,K)(Mg,Mn2+,Al)3(Al2Si2O10)(OH)2Mon. 2/m : B2/m
9.EC.35Ferrokinoshitalite(Ba,K)(Fe2+,Mg)3(Al2Si2O10)(OH,F)2Mon. 2/m : B2/m
9.EC.35ClintoniteCaAlMg2(SiAl3O10)(OH)2Mon. 2/m : B2/m
9.EC.35Oxykinoshitalite(Ba,K)(Mg,Ti,Fe3+,Fe2+)3((Si,Al)4O10)(O,OH,F)2Mon. 2/m : B2/m
9.EC.35FluorokinoshitaliteBaMg3(Al2Si2O10)F2Mon. 2/m : B2/m
9.EC.35BityiteCaLiAl2(AlBeSi2O10)(OH)2Mon. 2/m : B2/b
9.EC.35Anandite(Ba,K)(Fe2+,Mg)3((Si,Al,Fe)4O10)(S,OH)2Mon. 2/m : B2/b
9.EC.40Montmorillonite(Na,Ca)0.33(Al,Mg)2(Si4O10)(OH)2 · nH2OMon. 2/m : B2/m
9.EC.40Beidellite(Na,Ca0.5)0.3Al2((Si,Al)4O10)(OH)2 · nH2OMon. 2/m : B2/m
9.EC.40VolkonskoiteCa0.3(Cr,Mg,Fe)2((Si,Al)4O10)(OH)2 · 4H2OMon.
9.EC.40NontroniteNa0.3Fe2((Si,Al)4O10)(OH)2 · nH2OMon. 2/m : B2/m
9.EC.40Kurumsakite(Zn,Ni,Cu)8Al8V5+2Si5O35 · 27H2O (?)Orth.
9.EC.40Yakhontovite(Ca,Na)0.5(Cu,Fe,Mg)2(Si4O10)(OH)2 · 3H2OMon.
9.EC.45SwineforditeLi(Al,Li,Mg)3((Si,Al)4O10)2(OH,F)4 · nH2OMon. 2/m : B2/m
9.EC.45HectoriteNa0.3(Mg,Li)3(Si4O10)(F,OH)2Mon. 2/m : B2/m
9.EC.45ZincsiliteZn3Si4O10(OH)2 · 4H2O (?)Mon.
9.EC.45HanjiangiteBa2CaV3+Al(H2AlSi3O12)(CO3)2FMon. 2 : B2
9.EC.45SpadaiteMgSiO2(OH)2 · H2O (?)
9.EC.45FerrosaponiteCa0.3(Fe2+,Mg,Fe3+)3((Si,Al)4O10)(OH)2 · 4H2OMon.
9.EC.45Stevensite(Ca,Na)xMg3-x(Si4O10)(OH)2Mon.
9.EC.45SaponiteCa0.25(Mg,Fe)3((Si,Al)4O10)(OH)2 · nH2OMon.
9.EC.45SauconiteNa0.3Zn3((Si,Al)4O10)(OH)2 · 4H2OMon.
9.EC.50VermiculiteMg0.7(Mg,Fe,Al)6(Si,Al)8O20(OH)4 · 8H2OMon. 2/m
9.EC.52'Tarasovite'near NaKAl11Si13O40(OH)9 · 3H2O
9.EC.55ClinochloreMg5Al(AlSi3O10)(OH)8Mon. 2/m : B2/m
9.EC.55Borocookeite(LiAl4◻)[BSi3O10](OH)8Mon. m : Bb
9.EC.55FranklinfurnaceiteCa2Fe3+Mn2+3Mn3+(Zn2Si2O10)(OH)8Mon. 2 : B2
9.EC.55PennantiteMn2+5Al(AlSi3O10)(OH)8Tric.
9.EC.55VakhrushevaiteMg5Cr(AlSi3O10)(OH)8Tric. 1
9.EC.55NimiteNi5Al(AlSi3O10)(OH)8Mon. 2/m : B2/m
9.EC.55Cookeite(LiAl4◻)[AlSi3O10](OH)8Mon. 2/m
9.EC.55GonyeriteMn2+5Fe3+(Fe3+Si3O10)(OH)8Orth.
9.EC.55ChamositeFe2+5Al(AlSi3O10)(OH)8Mon. 2/m : B2/m
9.EC.55'Orthochamosite'(Fe2+,Mg,Fe3+)5Al(AlSi3O10)(OH,O)8
9.EC.55BaileychloreZn5Al(AlSi3O10)(OH)8Tric. 1
9.EC.55SudoiteMg2Al3(AlSi3O10)(OH)8Mon. 2/m : B2/m
9.EC.55GlagoleviteNa(Mg,Al)6(AlSi3O10)(OH,O)8Tric. 1 : P1
9.EC.55DonbassiteAl4.33(AlSi3O10)(OH)8Mon. 2 : B2
9.EC.60DozyiteMg7Al2(Al2Si4O15)(OH)12Mon.
9.EC.60Rectorite(Na,Ca)Al4((Si,Al)8O20)(OH)4 · 2H2OMon.
9.EC.60Corrensite(Mg,Fe)9((Si,Al)8O20)(OH)10 · nH2OOrth.
9.EC.60AliettiteCa0.2Mg6((Si,Al)8O20)(OH)4 · 4H2OMon.
9.EC.60Karpinskite(Ni,Mg)2Si2O5(OH)2 (?)Mon.
9.EC.60LunijianlaiteLi0.7Al6.2(AlSi7O20)(OH,O)10Mon.
9.EC.60TosuditeNa0.5(Al,Mg)6((Si,Al)8O18)(OH)12 · 5H2OMon. 2 : B2
9.EC.60HydrobiotiteK(Mg,Fe2+)6((Si,Al)8O20)(OH)4 · nH2OMon. 2/m : B2/m
9.EC.60Saliotite(Li,Na)Al3(AlSi3O10)(OH)5Mon. 2/m : B2/m
9.EC.60KulkeiteMg8Al(AlSi7O20)(OH)10Mon.
9.EC.60BrinrobertsiteNa0.3Al4(Si4O10)2(OH)4 · 3.5 H2OMon.
9.EC.65Macaulayite(Fe,Al)24Si4O43(OH)2Mon.
9.EC.70BurckhardtitePb2(Fe3+Te6+)[AlSi3O8]O6Trig. 3m(32/m) : P31m
9.EC.75Niksergievite(Ba,Ca)2Al3(AlSi3O10)(CO3)(OH)6 · nH2OMon.
9.EC.75Ferrisurite(Pb,Ca)2.4Fe3+2(Si4O10)(CO3)1.7(OH)3 · nH2OMon.
9.EC.75Surite(Pb,Ca)3(Al,Fe2+,Mg)2((Si,Al)4O10)(CO3)2(OH)2Mon. 2 : P21
9.EC.80KegelitePb8Al4(Si8O20)(SO4)2(CO3)4(OH)8Mon.

RadioactivityHide

Radioactivity:
Element % Content Activity (Bq/kg) Radiation Type
Uranium (U) 0.0000% 0 α, β, γ
Thorium (Th) 0.0000% 0 α, β, γ
Potassium (K) 7.6790% 2,380 β, γ

For comparison:

  • Banana: ~15 Bq per fruit
  • Granite: 1,000–3,000 Bq/kg
  • EU exemption limit: 10,000 Bq/kg

Note: Risk is shown relative to daily recommended maximum exposure to non-background radiation of 1000 µSv/year. Note that natural background radiation averages around 2400 µSv/year so in reality these risks are probably extremely overstated! With infrequent handling and safe storage natural radioactive minerals do not usually pose much risk.

Interactive Simulator:

Note: The mass selector refers to the mass of radioactive mineral present, not the full specimen, also be aware that the matrix may also be radioactive, possibly more radioactive than this mineral!

Activity: –

DistanceDose rateRisk
1 cm
10 cm
1 m

The external dose rate (D) from a radioactive mineral is estimated by summing the gamma radiation contributions from its Uranium, Thorium, and Potassium content, disregarding daughter-product which may have a significant effect in some cases (eg 'pitchblende'). This involves multiplying the activity (A, in Bq) of each element by its specific gamma ray constant (Γ), which accounts for its unique gamma emissions. The total unshielded dose at 1 cm is then scaled by the square of the distance (r, in cm) and multiplied by a shielding factor (μshield). This calculation provides a 'worst-case' or 'maximum risk' estimate because it assumes the sample is a point source and entirely neglects any self-shielding where radiation is absorbed within the mineral itself, meaning actual doses will typically be lower. The resulting dose rate (D) is expressed in microsieverts per hour (μSv/h).

D = ((AU × ΓU) + (ATh × ΓTh) + (AK × ΓK)) / r2 × μshield

Fluorescence of ShirozuliteHide

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for ShirozuliteHide

References for ShirozuliteHide

Localities for ShirozuliteHide

Showing 2 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
Hide all sections | Show all sections

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Japan (TL)
 
  • Aichi Prefecture
    • Kitashitara County
      • Shitara
Ishida et al. (2004)
Russia
 
  • Bashkortostan
Brusnitsyn et al. (2009)
 
and/or  
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