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Volkonskoite

A valid IMA mineral species - grandfathered
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About VolkonskoiteHide

04951040017271927712773.jpg
Pyotr Mikhailovich Volkonsky
Formula:
Ca0.3(Cr,Mg,Fe)2((Si,Al)4O10)(OH)2 · 4H2O
Colour:
Blue-green, dark green, grass-green
Lustre:
Waxy, Dull
Hardness:
1 - 2
Specific Gravity:
2.11 - 2.36
Crystal System:
Monoclinic
Member of:
Name:
Named in 1831 by August Alexander KĂ€mmerer in honour of Prince Pyotr Mikhailovich Volkonsky (25 April (6 May) 1776, Saint-Petersburg, Russian Empire - 27 August (8 September) 1852, Petergof, Petrodvortsovy District, Saint Petersburg, Russian Empire), Minister of the Russian Court, Russia.

Unique IdentifiersHide

Mindat ID:
4201
Long-form identifier:
mindat:1:1:4201:3

IMA Classification of VolkonskoiteHide

Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
Ca0.3(Cr3+,Mg)2(Si,Al)4O10(OH)2·4H2O
First published:
1831

Classification of VolkonskoiteHide

9.EC.40

9 : SILICATES (Germanates)
E : Phyllosilicates
C : Phyllosilicates with mica sheets, composed of tetrahedral and octahedral nets
71.3.1a.4

71 : PHYLLOSILICATES Sheets of Six-Membered Rings
3 : Sheets of 6-membered rings with 2:1 clays
16.15.6

16 : Silicates Containing Aluminum and other Metals
15 : Aluminosilicates of V and Cr

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.

SymbolSourceReference for Standard
VknIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43
VknWarr (2020)Warr, L.N. (2020) Recommended abbreviations for the names of clay minerals and associated phases. Clay Minerals, 55, 261–264 doi:10.1180/clm.2020.30

Physical Properties of VolkonskoiteHide

Waxy, Dull
Transparency:
Translucent
Colour:
Blue-green, dark green, grass-green
Hardness:
1 - 2 on Mohs scale
Tenacity:
Brittle
Fracture:
Conchoidal
Density:
2.11 - 2.36 g/cm3 (Measured)    

Optical Data of VolkonskoiteHide

Type:
Biaxial (-)
RI values:
nα = 1.551 - 1.560 nβ = 1.569 nγ = 1.564
2V:
Calculated: 62° to 84°
Max. Birefringence:
δ = 0.004 - 0.013
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 ”m thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Low (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
r > v strong

Chemistry of VolkonskoiteHide

Mindat Formula:
Ca0.3(Cr,Mg,Fe)2((Si,Al)4O10)(OH)2 · 4H2O
Element Weights:
Element% weight
O51.775 %
Si22.722 %
Cr21.033 %
Ca2.432 %
H2.039 %

Calculated from ideal end-member formula.
O
Si
Cr
Ca
H
Common Impurities:
Ti,Mn,Na,K,C,P

Crystallography of VolkonskoiteHide

Crystal System:
Monoclinic
Morphology:
Fine scaly to fibrous, massive.
Comment:
Point Group: n.d.; Space Group: n.d. Z = n.d

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
- Å()
Comments:
No published powder X-ray diffraction data.

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 3b: Earth’s earliest hydrosphere>4.45
13 : Hadean serpentinization
Stage 7: Great Oxidation Event<2.4
47a : [Near-surface hydration of prior minerals]
47e : [Vanadates, chromates, manganates]
Stage 10a: Neoproterozoic oxygenation/terrestrial biosphere<0.6
53 : Other minerals with taphonomic origins<0.4
Geological Setting:
Weathering product of serpentine, epigenetic mineral in clastic sedimentary rocks.

Type Occurrence of VolkonskoiteHide

Synonyms of VolkonskoiteHide

Other Language Names for VolkonskoiteHide

Relationship of Volkonskoite to other SpeciesHide

Member of:
Other Members of Smectite Group:
Beidellite(Na,Ca0.5)0.3Al2((Si,Al)4O10)(OH)2 · nH2OMon. 2/m : B2/m
FerrosaponiteCa0.3(Fe2+,Mg,Fe3+)3((Si,Al)4O10)(OH)2 · 4H2OMon.
HectoriteNa0.3(Mg,Li)3(Si4O10)(F,OH)2Mon. 2/m : B2/m
Montmorillonite(Na,Ca)0.33(Al,Mg)2(Si4O10)(OH)2 · nH2OMon. 2/m : B2/m
NontroniteNa0.3Fe2((Si,Al)4O10)(OH)2 · nH2OMon. 2/m : B2/m
'Pimelite'Ni3Si4O10(OH)2 · 4H2OHex.
Saliotite(Li,Na)Al3(AlSi3O10)(OH)5Mon. 2/m : B2/m
SaponiteCa0.25(Mg,Fe)3((Si,Al)4O10)(OH)2 · nH2OMon.
SauconiteNa0.3Zn3((Si,Al)4O10)(OH)2 · 4H2OMon.
Stevensite(Ca,Na)xMg3-x(Si4O10)(OH)2Mon.
SwineforditeLi(Al,Li,Mg)3((Si,Al)4O10)2(OH,F)4 · nH2OMon. 2/m : B2/m
Yakhontovite(Ca,Na)0.5(Cu,Fe,Mg)2(Si4O10)(OH)2 · 3H2OMon.
ZincsiliteZn3Si4O10(OH)2 · 4H2O (?)Mon.

Common AssociatesHide

Associations Based on Photo Data:
8 photos of Volkonskoite associated with DescloizitePbZn(VO4)(OH)
5 photos of Volkonskoite associated with Melanophlogite46SiO2 · 6(N2,CO2) · 2(CH4,N2)
4 photos of Volkonskoite associated with QuartzSiO2
4 photos of Volkonskoite associated with VanadinitePb5(VO4)3Cl
3 photos of Volkonskoite associated with BaryteBaSO4
3 photos of Volkonskoite associated with FerrihollanditeBa(Mn4+6Fe3+2)O16
2 photos of Volkonskoite associated with CinnabarHgS
2 photos of Volkonskoite associated with Cerianite-(Ce)Ce4+O2
1 photo of Volkonskoite associated with BentoriteCa6Cr2(SO4)3(OH)12 · 26H2O

Related Minerals - Strunz-mindat GroupingHide

9.EC.MeifuiteKFe6(Si7Al)O19(OH)4Cl2Tric. 1 : P1
9.EC.BalestraiteKLi2V5+Si4O12Mon. 2 : B2
9.EC.VoloshiniteRb(LiAl1.5◻0.5)(Al0.5Si3.5)O10F2Mon. 2/m : B2/b
9.EC.05TalcMg3Si4O10(OH)2Tric. 1 : P1
9.EC.05MinnesotaiteFe2+3Si4O10(OH)2Tric. 1 : P1
9.EC.05WillemseiteNi3Si4O10(OH)2Mon.
9.EC.10FluorluanshiweiiteKLiAl1.5(Si3.5Al0.5)O10F2Mon. 2/m : B2/m
9.EC.10GarmiteCsLiMg2(Si4O10)F2Mon.
9.EC.10GorbunoviteCsLi2(Ti,Fe)Si4O10(F,OH,O)2Mon.
9.EC.10FerripyrophylliteFe3+Si2O5(OH)Mon. 2/m
9.EC.10ManganiceladoniteK(MgMn3+◻)(Si4O10)(OH)2Mon.
9.EC.10LuanshiweiiteKLiAl1.5(Si3.5Al0.5)O10(OH)2Mon. 2/m : B2/b
9.EC.10PyrophylliteAl2Si4O10(OH)2Tric. 1
9.EC.15ParagoniteNaAl2(AlSi3O10)(OH)2Mon.
9.EC.15FerroaluminoceladoniteK(Fe2+Al◻)(Si4O10)(OH)2Mon. 2/m : B2/m
9.EC.15NanpingiteCsAl2(AlSi3O10)(OH,F)2Mon. 2/m : B2/b
9.EC.15FerroceladoniteK(Fe2+Fe3+◻)(Si4O10)(OH)2Mon. 2/m : B2/m
9.EC.15GanteriteBa0.5(Na,K)0.5Al2(Si2.5Al1.5)O10(OH)2Mon. 2/m : B2/b
9.EC.15KreiteriteCsLi2Fe3+(Si4O10)F2Mon.
9.EC.15RoscoeliteKV3+2(AlSi3O10)(OH)2Mon. 2/m : B2/b
9.EC.15AluminoceladoniteK(MgAl◻)(Si4O10)(OH)2Mon. 2/m : B2/m
9.EC.15Tobelite(NH4)Al2(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.15TainioliteKLiMg2(Si4O10)F2Mon. 2/m : B2/m
9.EC.15CeladoniteK(MgFe3+◻)(Si4O10)(OH)2Mon. 2/m : B2/m
9.EC.15ChromceladoniteK(MgCr◻)(Si4O10)(OH)2Mon. 2 : B2
9.EC.15MontdoriteKFe2+1.5Mn2+0.5Mg0.5Si4O10(F,OH)2Mon. 2/m : B2/m
9.EC.15ChromphylliteKCr2(AlSi3O10)(OH)2Mon. 2/m : B2/b
9.EC.15BoromuscoviteKAl2(BSi3O10)(OH)2Mon. 2/m
9.EC.15'UM1988-22-SiO:AlCaFFeHKLiMg'KLiMgAl2Si3O10F2Mon.
9.EC.15Chernykhite(Ba,Na)(V3+,Al,Mg)2((Si,Al)4O10)(OH)2Mon.
9.EC.15MuscoviteKAl2(AlSi3O10)(OH)2Mon. 2/m : B2/b
9.EC.20MasutomiliteK(LiAlMn2+)[AlSi3O10]F2Mon. 2 : B2
9.EC.20OxyphlogopiteK(Mg,Ti,Fe)3[(Si,Al)4O10](O,F)2Mon. 2/m : B2/m
9.EC.20'Chloroferrokinoshitalite'(Ba,K)(Fe2+,Mg)3(Al2Si2O10)(Cl,OH,F)2
9.EC.20SiderophylliteKFe2+2Al(Al2Si2O10)(OH)2Mon.
9.EC.20SokolovaiteCsLi2Al(Si4O10)F2Mon.
9.EC.20HendricksiteKZn3(Si3Al)O10(OH)2Mon. 2/m : B2/m
9.EC.20TetraferriphlogopiteKMg3(Si3Fe3+)O10(OH)2Mon. 2/m : B2/m
9.EC.20FluoranniteKFe2+3(Si3Al)O10F2Mon. 2/m : B2/m
9.EC.20AspidoliteNaMg3(AlSi3O10)(OH)2Mon. 2/m : B2/m
9.EC.20