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Baumhauerite

A valid IMA mineral species - grandfathered
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About BaumhaueriteHide

09122660017271921476036.jpg
Heinrich A. Baumhauer
Formula:
Pb12As16S36
Simplified Pb3As4S9. May contain minor Sb substituting for As.
Colour:
Lead-grey, steel-grey; iridescent at times
Lustre:
Metallic
Hardness:
3
Specific Gravity:
5.33 - 5.44
Crystal System:
Triclinic
Member of:
Name:
Named in 1902 by Richard Harrison Solly in honor of Heinrich Adolf Baumhauer [October 26, 1848 Bonn, Germany - August 1, 1926 Fribourg, Switzerland], Professor of Mineralogy, University of Fribourg, Switzerland.
Compare argentobaumhauerite (formerly 'baumhauerite-2a') and bernarlottiite (Sb-rich); also 'UM1966-04-S:AsPb'.

The structure contains isolated and interconnected AsS3 pyramids, as, e.g., in case of dufrénoysite, gratonite, sartorite, and seligmannite.


Unique IdentifiersHide

Mindat ID:
572
Long-form identifier:
mindat:1:1:572:8

Similar NamesHide

Baumhauerit-2aA synonym of Argentobaumhauerite
Baumhauerite IIA valid IMA mineral species - grandfathered - questionable

IMA Classification of BaumhaueriteHide

Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
Pb2+12As3+16S2-36
Approval year:
1988
First published:
1902

Classification of BaumhaueriteHide

2.HC.05b

2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
H : Sulfosalts of SnS archetype
C : With only Pb
3.6.13.1

3 : SULFOSALTS
6 : 2 < ø < 2.49
5.6.4

5 : Sulphosalts - Sulpharsenites and Sulphobismuthites (those containing Sn, Ge,or V are in Section 6)
6 : Sulpharsenites etc. of Pb alone

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
BhaIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of BaumhaueriteHide

Metallic
Transparency:
Opaque
Colour:
Lead-grey, steel-grey; iridescent at times
Streak:
Chocolate-brown
Hardness:
Hardness:
VHN100=179 - Vickers
Tenacity:
Brittle
Cleavage:
Perfect
On {100} perfect.
Fracture:
Conchoidal
Density:
5.33 - 5.44 g/cm3 (Measured)    5.42 g/cm3 (Calculated)

Optical Data of BaumhaueriteHide

Anisotropism:
Strong, in dark brown, pale brown, pale brownish grey, green, violet, blue-green or yellow
Reflectivity:
WavelengthR1 (%)R2 (%)
400nm38.0% 42.1%
420nm37.6% 41.9%
440nm37.2% 41.6%
460nm36.8% 41.2%
480nm36.4% 40.7%
500nm36.0% 40.4%
520nm35.5% 39.8%
540nm35.1% 39.2%
560nm34.6% 38.6%
580nm34.2% 37.9%
600nm33.7% 37.2%
620nm33.2% 36.5%
640nm32.5% 35.7%
660nm31.8% 34.9%
680nm31.1% 34.2%
700nm30.5% 33.5%


Graph shows reflectance levels at different wavelengths (in nm). Peak reflectance is 42.1%.
R1 shown in black, R2 shown in red
Colour in reflected light:
White
Internal Reflections:
Deep red

Chemistry of BaumhaueriteHide

Mindat Formula:
Pb12As16S36

Simplified Pb3As4S9. May contain minor Sb substituting for As.
Element Weights:
Element% weight
Pb51.377 %
As24.770 %
S23.853 %

Calculated from ideal end-member formula.
Pb
As
S
Common Impurities:
Sb

Crystallography of BaumhaueriteHide

Crystal System:
Triclinic
Class (H-M):
1 - Pinacoidal
Space Group:
P1
Cell Parameters:
a = 22.74 Å, b = 8.33 Å, c = 7.89 Å
α = 90.35°, β = 97°, γ = 90.42°
Ratio:
a:b:c = 2.73 : 1 : 0.947
Unit Cell V:
1,483.34 ų (Calculated from Unit Cell)
Z:
4
Morphology:
Short prismatic [010]; tabular {100}; striated on {100} parallel to [010] and on {010} parallel to [001]. Some crystals considerably rounded, as by etching.
Twinning:
On {100}, polysynthetic, with visible twin lamellae.
Comment:
Pseudomonoclinic. Also a = 22.905, b = 8.329, c = 7.957 (ICDD 12-281)

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0010683BaumhaueriteEngel P, Nowacki W (1969) Die kristallstruktur von baumhauerit Zeitschrift fur Kristallographie 129 178-2021969Lengenbach quarry, Binnatal, Canton Wallis, Switzerland0293
0009265BaumhaueriteLe Bihan M T (1961) Contribution a l'etude structurale des sulfures d'arsenic et de plomb. Structure de la baumhauerite Acta Crystallographica 14 1210-12111961Binnenthal, Switzerland0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
11.5 Å(20)
7.69 Å(10)
7.22 Å(10)
6.78 Å(10)
6.15 Å(10)
5.82 Å(10)
5.64 Å(10)
5.17 Å(10)
4.924 Å(10)
4.716 Å(10)
4.548 Å(10)
4.360 Å(10)
4.149 Å(100)
3.983 Å(10)
3.872 Å(20)
3.806 Å(20)
3.743 Å(10)
3.682 Å(10)
3.594 Å(80)
3.470 Å(80)
3.398 Å(20)
3.258 Å(60)
3.184 Å(30)
3.061 Å(10)
3.020 Å(60)
2.957 Å(90)
2.873 Å(40)
2.799 Å(20)
2.773 Å(80)
2.724 Å(60)
2.661 Å(20)
2.619 Å(5)
2.579 Å(10)
2.569 Å(10)
2.354 Å(50)
2.257 Å(5)
2.223 Å(30)
2.095 Å(40)
2.056 Å(10)
Comments:
ICDD 12-281. Binntal, Switzerland (close to baumhauerite-2a).

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
High-? alteration and/or metamorphism
33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12])

Type Occurrence of BaumhaueriteHide

General Appearance of Type Material:
Isolated crystals, closely resembling dufrenoysite and jordanite.
Place of Conservation of Type Material:
British Museum of Natural History, London, England, 1926,1654.
Geological Setting of Type Material:
Dolomite
Associated Minerals at Type Locality:

Synonyms of BaumhaueriteHide

Other Language Names for BaumhaueriteHide

Simplified Chinese:褐硫砷铅矿
Spanish:Baumhauerita
Traditional Chinese:褐硫砷鉛礦

Relationship of Baumhauerite to other SpeciesHide

Member of:
Other Members of Sartorite Group:
ArgentobaumhaueriteAg1.5Pb22As33.5S72Tric. 1 : P1
ArgentodufrénoysiteAg3Pb26As35S80Tric. 1 : P1
ArgentoliveingiteAg3+xPb36-2xAs51+xS112Tric. 1 : P1
BarikaiteAg3Pb10(Sb8As11)S40Mon. 2/m : P21/c
BernarlottiitePb6(As5Sb3)S18Tric. 1 : P1
BoscardiniteTlPb4(Sb7As2)S18Tric. 1 : P1
Carducciite(Ag2Sb2)Pb12(As,Sb)16S40Mon. 2/m : P21/c
DekatriasartoriteTlPb58As97S204Mon. 2/m : P21/c
DufrénoysitePb2As2S5Mon. 2 : P21
ÉcrinsiteAgTl3Pb4As11Sb9S36Tric. 1 : P1
EnneasartoriteTl6Pb32As70S140Mon. 2/m : P21/c
GeueriteAg2Tl4Pb4As22S40Mon. 2/m : P21/c
GiuşcăiteAg2Tl4Pb4As20Sb2S40Mon. m
GuettarditePb8(Sb0.56As0.44)16S32Mon. 2/m : P21/c
HendekasartoriteTl2Pb48As82S172Mon. 2/m : P21/c
HeptasartoriteTl7Pb22As55S108Mon. 2/m : P21/c
HyršlitePb8As10Sb6S32Mon. 2 : P21
IncomsartoriteTl6Pb144As246S516Mon. 2/m : P21/c
InterliveingiteAgPb18As25S56Mon. 2 : P21
LiveingitePb20As24S56Mon. 2 : P21
ParapierrotiteTlSb5S8Mon. m
PhilrothiteTlAs3S5Mon. 2/m : P21/c
PierrotiteTl2(Sb,As)10S16Orth. mm2 : Pna21
PolloneiteAgPb46As26Sb23S120Mon. 2 : P21
RathiteAg2Pb12-xTlx/2As18+x/2S40Mon. 2/m : P21/c
SartoritePbAs2S4Mon. 2/m : P21/m
Twinnite Pb0.8Tl0.1Sb1.3As0.8S4Mon. 2/m
VeenitePb16Sb9-xAs7+xS40, x ~ 0-0.5Mon. 2 : P21

Common AssociatesHide

Associations Based on Photo Data:
12 photos of Baumhauerite associated with RealgarAs4S4
11 photos of Baumhauerite associated with SphaleriteZnS
10 photos of Baumhauerite associated with PyriteFeS2
10 photos of Baumhauerite associated with DolomiteCaMg(CO3)2
8 photos of Baumhauerite associated with Tennantite SubgroupCu6(Cu4C2+2)As4S12S
4 photos of Baumhauerite associated with ArgentobaumhaueriteAg1.5Pb22As33.5S72
3 photos of Baumhauerite associated with PararealgarAs4S4
3 photos of Baumhauerite associated with ArgentoliveingiteAg3+xPb36-2xAs51+xS112
3 photos of Baumhauerite associated with LiveingitePb20As24S56
3 photos of Baumhauerite associated with CalciteCaCO3

Related Minerals - Strunz-mindat GroupingHide

2.HC.BernarlottiitePb6(As5Sb3)S18Tric. 1 : P1
2.HC.HuntingdonitePb19Sb16As6S51Cl2Tric. 1 : P1
2.HC.MoiraitePb12Sb8As8S36Tric. 1 : P1
2.HC.05fParapierrotiteTlSb5S8Mon. m
2.HC.05gMarumoitePb32As40S92Mon. 2 : P21
2.HC.05bBaumhauerite II
2.HC.05dRathiteAg2Pb12-xTlx/2As18+x/2S40Mon. 2/m : P21/c
2.HC.05eHeptasartoriteTl7Pb22As55S108Mon. 2/m : P21/c
2.HC.05dDufrénoysitePb2As2S5Mon. 2 : P21
2.HC.05eHendekasartoriteTl2Pb48As82S172Mon. 2/m : P21/c
2.HC.05bArgentobaumhaueriteAg1.5Pb22As33.5S72Tric. 1 : P1
2.HC.05cArgentoliveingiteAg3+xPb36-2xAs51+xS112Tric. 1 : P1
2.HC.05dVeenitePb16Sb9-xAs7+xS40, x ~ 0-0.5Mon. 2 : P21
2.HC.05eDekatriasartoriteTlPb58As97S204Mon. 2/m : P21/c
2.HC.05aHyršlitePb8As10Sb6S32Mon. 2 : P21
2.HC.05eIncomsartoriteTl6Pb144As246S516Mon. 2/m : P21/c
2.HC.05cLiveingitePb20As24S56Mon. 2 : P21
2.HC.05cJohnjamboritePb14Sb8.5As7.5S38Tric. 1 : P1
2.HC.05fPierrotiteTl2(Sb,As)10S16Orth. mm2 : Pna21
2.HC.05dRathite-IVPbAs2S4
2.HC.05dArgentodufrénoysiteAg3Pb26As35S80Tric. 1 : P1
2.HC.05eÉcrinsiteAgTl3Pb4As11Sb9S36Tric. 1 : P1
2.HC.05aSartoritePbAs2S4Mon. 2/m : P21/m
2.HC.05aTwinnite Pb0.8Tl0.1Sb1.3As0.8S4Mon. 2/m
2.HC.05fPhilrothiteTlAs3S5Mon. 2/m : P21/c
2.HC.05hPolloneiteAgPb46As26Sb23S120Mon. 2 : P21
2.HC.05aGuettarditePb8(Sb0.56As0.44)16S32Mon. 2/m : P21/c
2.HC.10aFülöppitePb3Sb8S15Mon. 2/m : B2/b
2.HC.10dSemseyitePb9Sb8S21Mon. 2/m : B2/b
2.HC.10dRayitePb8(Ag,Tl)2Sb8S21Mon.
2.HC.10cHeteromorphitePb7Sb8S19Mon. 2/m : B2/b
2.HC.10bPlagionitePb5Sb8S17Mon. 2/m : B2/b
2.HC.15FalkmanitePb3Sb2S6Mon.
2.HC.15BoulangeritePb5Sb4S11Mon. 2/m : P21/c
2.HC.20RobinsonitePb4Sb6S13Mon. 2/m : P21/m
2.HC.25MoëloitePb6Sb6S14(S3)Orth. 222 : P21212
2.HC.30DadsonitePb23Sb25S60ClTric. 1 : P1
2.HC.35ZoubekiteAgPb4Sb4S10Orth.
2.HC.35Proto-owyheeiteAg9Pb40Sb45S112Mon. 2/m : P21/c
2.HC.35OwyheeiteAg3Pb10Sb11S28Mon. 2/m : P21/c
2.HC.40ParasterryiteAg4Pb20Sb14As10S58Mon. 2/m : P21/c
2.HC.50LopatkaitePb5Sb3AsS11Mon. 2/m : P21/c

Fluorescence of BaumhaueriteHide

Not fluorescent in UV

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for BaumhaueriteHide

References for BaumhaueriteHide

Reference List: