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Pumpellyite-(Fe2+)

A valid IMA mineral species
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About Pumpellyite-(Fe2+)Hide

00338530017271926117054.jpg
Raphael Pumpelly
Formula:
Ca2Fe2+Al2[Si2O6OH][SiO4](OH)2(OH)
Colour:
Greenish black
Lustre:
Vitreous
Hardness:
5
Specific Gravity:
3.31
Crystal System:
Monoclinic
Name:
Named for its relationship to the the members of the pumpellyite group. The suffix was added in 1973 during a redefinition of the species.

Raphael Pumpelly [September 8, 1837 Owego, New York, USA – August 10, 1923 Newport, Rhode Island, USA] was an active mining consultant and was professor of Mining Science at Harvard University. He was appointed director of the New England branch of the United States Geological Survey in 1884.

Unique IdentifiersHide

Mindat ID:
3307
Long-form identifier:
mindat:1:1:3307:3

Similar NamesHide

PampaloiteA valid IMA mineral speciesAuSbTe
PumpellyiteA synonym of Pumpellyite Subgroup
Pumpellyite-(Al)A valid IMA mineral speciesCa2AlAl2[Si2O6OH][SiO4](OH)2O
Pumpellyite-(Fe)
Pumpellyite-(Fe2+)-Pumpellyite-(Mg) SeriesA solid-solution series between two end-member minerals
Pumpellyite-(Fe3+)A valid IMA mineral speciesCa2Fe3+Al2[Si2O6OH][SiO4](OH)2O
Pumpellyite-(Mg)A valid IMA mineral species - grandfatheredCa2MgAl2[Si2O6OH][SiO4](OH)2(OH)
Pumpellyite-(Mn2+)A valid IMA mineral speciesCa2Mn2+Al2[Si2O6OH][SiO4](OH)2(OH)

IMA Classification of Pumpellyite-(Fe2+)Hide

Classification of Pumpellyite-(Fe2+)Hide

9.BG.20

9 : SILICATES (Germanates)
B : Sorosilicates
G : Sorosilicates with mixed SiO4 and Si2O7 groups; cations in octahedral [6] and greater coordination
58.2.2.5

58 : SOROSILICATES Insular, Mixed, Single, and Larger Tetrahedral Groups
2 : Insular, Mixed, Single, and Larger Tetrahedral Groups with cations in [6] and higher coordination; single and double groups (n = 1, 2)
16.21.8

16 : Silicates Containing Aluminum and other Metals
21 : Aluminosilicates of Fe and Ca

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.

SymbolSourceReference for Standard
Pmp-Fe2+IMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43
PmpKretz (1983)Kretz, R. (1983) Symbols of rock-forming minerals. American Mineralogist, 68, 277–279.
PmpSiivolam & Schmid (2007)Siivolam, J. and Schmid, R. (2007) Recommendations by the IUGS Subcommission on the Systematics of Metamorphic Rocks: List of mineral abbreviations. Web-version 01.02.07. IUGS Commission on the Systematics in Petrology. download
PmpWhitney & Evans (2010)Whitney, D.L. and Evans, B.W. (2010) Abbreviations for names of rock-forming minerals. American Mineralogist, 95, 185–187 doi:10.2138/am.2010.3371
PmpThe Canadian Mineralogist (2019)The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download

Physical Properties of Pumpellyite-(Fe2+)Hide

Vitreous
Transparency:
Translucent
Colour:
Greenish black
Hardness:
Density:
3.31 g/cm3 (Measured)    3.35 g/cm3 (Calculated)

Optical Data of Pumpellyite-(Fe2+)Hide

Type:
Biaxial (-)
RI values:
nα = 1.728 nβ = 1.748 nγ = 1.754
2V:
Measured: -60° to 30°
Max. Birefringence:
δ = 0.026
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.

No measured or calculated 2V is on file for this mineral, so the value used here (57°) is estimated from its recorded refractive indices and optic sign, not from a direct 2V measurement.
Pleochroism:
Strong
Comments:
X = pale yellow; Y = deep grass-green; Z = yellowish brown to reddish brown

Chemistry of Pumpellyite-(Fe2+)Hide

Mindat Formula:
Ca2Fe2+Al2[Si2O6OH][SiO4](OH)2(OH)
Element Weights:
Element% weight
O44.598 %
Si16.776 %
Ca15.960 %
Fe11.119 %
Al10.744 %
H0.803 %

Calculated from ideal end-member formula.
O
Si
Ca
Fe
Al
H

Crystallography of Pumpellyite-(Fe2+)Hide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Cell Parameters:
a = 8.89(2) Å, b = 6.03(3) Å, c = 19.19(4) Å
β = 97.83(20)°
Ratio:
a:b:c = 1.474 : 1 : 3.182
Unit Cell V:
1,019.12 ų (Calculated from Unit Cell)
Z:
4
Morphology:
Rosettes and spherulites in stringers.
Comment:
Non-standard space group A2/m.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0007761Pumpellyite-(Fe2+)Artioli G, Geiger C A (1994) The crystal chemistry of pumpellyite: An X-ray Rietveld refinement and 57Fe Mossbauer study Physics and Chemistry of Minerals 20 443-4531994Torrente Bulla, Italy0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
2.91 Å(100)
3.79 Å(64)
2.75 Å(60)
2.22 Å(36)
2.66 Å(34)
4.76 Å(30)
4.43 Å(27)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
High-? alteration and/or metamorphism
31 : Thermally altered carbonate, phosphate, and iron formations

Type Occurrence of Pumpellyite-(Fe2+)Hide

Synonyms of Pumpellyite-(Fe2+)Hide

Other Language Names for Pumpellyite-(Fe2+)Hide

Relationship of Pumpellyite-(Fe2+) to other SpeciesHide

Other Members of Pumpellyite Subgroup:
Pumpellyite-(Al)Ca2AlAl2[Si2O6OH][SiO4](OH)2OMon. 2/m
Pumpellyite-(Fe3+)Ca2Fe3+Al2[Si2O6OH][SiO4](OH)2OMon. 2/m
Pumpellyite-(Mg)Ca2MgAl2[Si2O6OH][SiO4](OH)2(OH)Mon. 2/m
Pumpellyite-(Mn2+)Ca2Mn2+Al2[Si2O6OH][SiO4](OH)2(OH)Mon. 2/m
Forms a series with:

Common AssociatesHide

Associations Based on Photo Data:
19 photos of Pumpellyite-(Fe2+) associated with QuartzSiO2
10 photos of Pumpellyite-(Fe2+) associated with CalciteCaCO3
9 photos of Pumpellyite-(Fe2+) associated with Actinolite◻Ca2(Mg4.5-2.5Fe0.5-2.5)Si8O22(OH)2
8 photos of Pumpellyite-(Fe2+) associated with AlbiteNa(AlSi3O8)
7 photos of Pumpellyite-(Fe2+) associated with Epidote(CaCa)(AlAlFe3+)O[Si2O7][SiO4](OH)
6 photos of Pumpellyite-(Fe2+) associated with 'Clinozoisite-Epidote Series'
5 photos of Pumpellyite-(Fe2+) associated with FluorapatiteCa5(PO4)3F
5 photos of Pumpellyite-(Fe2+) associated with 'Oligoclase'(Na,Ca)[Al(Si,Al)Si2O8]
5 photos of Pumpellyite-(Fe2+) associated with Clinozoisite(CaCa)(AlAlAl)O[Si2O7][SiO4](OH)
5 photos of Pumpellyite-(Fe2+) associated with BabingtoniteCa2Fe2+Fe3+Si5O14(OH)

Related Minerals - Strunz-mindat GroupingHide

9.BG.AlumovesuvianiteCa19AlAl4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(OH)9Tet. 4/m : P4/n
9.BG.Alnaperbøeite-(Ce)Ca(Ce2.5Na0.5)(AlAl2Al)[Si2O7][SiO4]3O(OH)2Mon. 2/m : P21/m
9.BG.Zilbermintsite-(La)(CaLa5)(Fe3+Al3Fe2+)[Si2O7][SiO4]5O(OH)3Mon. 2/m : P21/m
9.BG.Heflikite(CaCa)(AlAlSc)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.MagnesiovesuvianiteCa19MgAl4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10](OH)(OH)9Tet. 4/m : P4/n
9.BG.Zoisite-(Pb)(CaPb)(AlAlAl)O[Si2O7][SiO4](OH)Orth. mmm(2/m2/m2/m) : Pnma
9.BG.Shuiskite-(Cr)Ca2Cr3+Cr3+2[Si2O6OH][SiO4](OH)2OMon. 2/m : B2/m
9.BG.Radekškodaite Group
9.BG.05Dissakisite-(La)(CaLa)(AlAlMg)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05Manganiandrosite-(Ce)(Mn2+Ce)(Mn3+AlMn2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05bDissakisite-(Ce)(CaCe)(AlAlMg)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05bAllanite-(Sm)(CaSm)(AlAlFe2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05aHancockite(CaPb)(AlAlFe3+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05Dollaseite-(Ce)(CaCe)(MgAlMg)F[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05a v'Unnamed (Ga-analogue of Epidote)'(CaCa)(AlAlGa3+)O[Si2O7][SiO4](OH)
9.BG.05aClinozoisite(CaCa)(AlAlAl)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05aEpidote-(Sr)(CaSr)(AlAlFe3+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05Vanadoandrosite-(Ce)(Mn2+Ce)(V3+AlMn2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05bVanadoallanite-(La)(CaLa)(V3+AlFe2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05b'Unnamed (Mg-analogue of Ferriallanite-(Ce))'(CaCe)(Fe3+AlMg)O[Si2O7][SiO4](OH)
9.BG.05bFerriallanite-(La)(CaLa)(Fe3+AlFe2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05Uedaite-(Ce)(Mn2+Ce)(AlAlFe2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05aEpidote(CaCa)(AlAlFe3+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05Tweddillite(CaSr)(Mn3+AlMn3+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05bÅskagenite-(Nd)(Mn2+Nd)(AlAlFe3+)O[Si2O7][SiO4]OMon. 2/m : P21/m
9.BG.05Piemontite-(Pb)(CaPb)(AlAlMn3+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05bAllanite-(Ce)(CaCe)(AlAlFe2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05bAllanite-(La)(CaLa)(AlAlFe2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05bAllanite-(Y)(CaY)(AlAlFe2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05aPiemontite(CaCa)(AlAlMn3+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05bAkasakaite-(Ce)(CaCe)(AlAlMn2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05bManganiandrosite-(La)(Mn2+La)(Mn3+AlMn2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05bAkasakaite-(La)(CaLa)(AlAlMn2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05bVanadoakasakaite-(La)(CaLa)(V3+AlMn2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05Khristovite-(Ce)(CaCe)(MgAlMn2+)F[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05bFerriakasakaite-(La)(CaLa)(Fe3+AlMn2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05Ferriandrosite-(La)(Mn2+La)(Fe3+AlMn2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05'Androsite-(Ce)'(Mn2+Ce)(AlAlMn2+)O[Si2O7][SiO4](OH)
9.BG.05Vielleaureite-(Ce)Mn2+Ce(MgAlMn2+)(Si2O7)(SiO4)F(OH)Mon. 2/m : P21/m
9.BG.05Ferriandrosite-(Ce)(Mn2+Ce)(Fe3+AlMn2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05bFerriallanite-(Ce)(CaCe)(Fe3+AlFe2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05b'Unnamed (Mn3+-analogue of Ferriakasakaite-(Ce))'(CaCe)(Mn3+AlMn2+)O[Si2O7][SiO4](OH)
9.BG.05bVanadoakasakaite-(Ce)(CaCe)(V3+AlMn2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05Piemontite-(Sr)(CaSr)(AlAlMn3+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05Niigataite(CaSr)(AlAlAl)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05bFerriakasakaite-(Ce)(CaCe)(Fe3+AlMn2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05bVanadoandrosite-(La)Mn2+La(V3+AlMn2+)(Si2O7)(SiO4)O(OH)Mon. 2/m : P21/m
9.BG.05bAllanite-(Nd)(CaNd)(AlAlFe2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05b'UM1989-32-SiO:AlCaFeHREE'(Ca0.5◻0.5REE)(AlAlFe3+)O[Si2O7][SiO4](OH)
9.BG.05aMukhinite(CaCa)(AlAlV3+)O[Si2O7][SiO4](OH)Mon.
9.BG.05bManganiakasakaite-(La)(CaLa)(Mn3+AlMn2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.10Zoisite(CaCa)(AlAlAl)O[Si2O7][SiO4](OH)Orth. mmm(2/m2/m2/m) : Pnma
9.BG.15MacfalliteCa2Mn3+3(SiO4)(Si2O7)(OH)3Mon. 2/m : P21/m
9.BG.15SursassiteMn2+2Al3(SiO4)(Si2O7)(OH)3Mon. 2/m : P21/m
9.BG.20Pumpellyite-(Al)Ca2AlAl2[Si2O6OH][SiO4](OH)2OMon. 2/m
9.BG.20Shuiskite-(Mg)Ca2MgCr3+2[Si2O6OH][SiO4](OH)2(OH)Mon. 2/m
9.BG.20Julgoldite-(Fe2+)Ca2Fe2+Fe3+2[Si2O6OH][SiO4](OH)2(OH)Mon. 2/m
9.BG.20OkhotskiteCa2Mn2+Mn3+2[Si2O6OH][SiO4](OH)2(OH)Mon. 2/m
9.BG.20Julgoldite-(Mg)Ca2MgFe3+2[Si2O6OH][SiO4](OH)2(OH)Mon.
9.BG.20PoppiiteCa2V3+V3+2[Si2O6OH][SiO4](OH)2OMon. 2/m : B2/m
9.BG.20Julgoldite-(Fe3+)Ca2Fe3+Fe3+2[Si2O6OH][SiO4](OH)2OMon.
9.BG.20Pumpellyite-(Fe3+)Ca2Fe3+Al2[Si2O6OH][SiO4](OH)2OMon. 2/m
9.BG.20Pumpellyite-(Mg)Ca2MgAl2[Si2O6OH][SiO4](OH)2(OH)Mon. 2/m
9.BG.20Pumpellyite-(Mn2+)Ca2Mn2+Al2[Si2O6OH][SiO4](OH)2(OH)Mon. 2/m
9.BG.25GanomalitePb9Ca5Mn(Si2O7)4(SiO4)OHex. 6 : P6
9.BG.25WayneburnhamitePb9Ca6(Si2O7)3(SiO4)3Hex. 6 : P6
9.BG.30RustumiteCa10(Si2O7)2(SiO4)(OH)2Cl2Mon. 2/m : B2/b
9.BG.35ModraiteCa19Fe2+Al4(Al6Fe2+2)(◻4)◻[Si2O7]4[(SiO4)10](OH)(OH)9Tet. 4/mmm(4/m2/m2/m) : P4/nnc
9.BG.35FluorvesuvianiteCa19Fe3+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(F,OH)9Tet. 4/mmm(4/m2/m2/m) : P4/nnc
9.BG.35VesuvianiteCa19Fe3+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(OH)9Tet. 4/mmm(4/m2/m2/m) : P4/nnc
9.BG.35Milanriederite(Ca18[REE])Fe3+Al4(Mg4Al4)(◻4)◻[Si2O7]4[(SiO4)10](OH)(OH)9Tet. 4/mmm(4/m2/m2/m) : P4/nnc
9.BG.35Manaevite-(Ce)(Ca13Ce4[H2O]2)Mg(Al3Mg)(Mg3Ti3Fe3+2)(◻4)◻[Si2O7]4[(SiO4)8(H4O4)2]O(OH)9Tet. 4/mmm(4/m2/m2/m) : P4/nnc
9.BG.35HongheiteCa19Fe2+Al4(Fe3+,Mg)8(◻4)B[Si2O7]4[(SiO4)10]O(OH,O)9Tet. 4/mmm(4/m2/m2/m) : P4/nnc
9.BG.35WiluiteCa19MgAl4(Al,Mg)8(B,◻)4◻[Si2O7]4[(SiO4)10]O(O,OH)9Tet. 4/mmm(4/m2/m2/m) : P4/nnc
9.BG.35CyprineCa19Cu2+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10](OH)(OH)9Tet. 4/m : P4/n
9.BG.35ManganvesuvianiteCa19Mn3+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(OH)9Tet. 4/m : P4/n
9.BG.40Vyuntspakhkite-(Y)(Y,Yb)4Al2.5-1.5(Si,Al)1.5-2.5(SiO4)4O(OH)7Mon. 2/m : P21/c
9.BG.45DellaiteCa6Si3O11(OH)2Tric.
9.BG.50Ferriperbøeite-(Ce)CaCe3(Fe3+Al2Fe2+)[Si2O7][SiO4]3O(OH)2Mon. 2/m : P21/m
9.BG.50Perbøeite-(La)CaLa3(AlAl2Fe2+)[Si2O7][SiO4]3O(OH)2 Mon. 2/m : P21/m
9.BG.50Perbøeite-(Ce)CaCe3(AlAl2Fe2+)[Si2O7][SiO4]3O(OH)2 Mon. 2/m : P21/m
9.BG.50Gatelite-(Ce)CaCe3(AlAl2Mg)[Si2O7][SiO4]3O(OH)2Mon. 2/m : P21/c
9.BG.50Ferriperbøeite-(La) CaLa3(Fe3+Al2Fe2+)[Si2O7][SiO4]3O(OH)2Mon. 2/m : P21/m
9.BG.55Västmanlandite-(Ce)CaCe3(MgAl2Mg)[Si2O7][SiO4]3F(OH)2Mon. 2/m : P21/m
9.BG.60Radekškodaite-(La) (CaLa5)(Al4Fe2+)[Si2O7][SiO4]5O(OH)3Mon. 2/m : P21/m
9.BG.60Radekškodaite-(Ce)(CaCe5)(Al4Fe2+)[Si2O7][SiO4]5O(OH)3Mon. 2/m : P21/m

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for Pumpellyite-(Fe2+)Hide

References for Pumpellyite-(Fe2+)Hide

Localities for Pumpellyite-(Fe2+)Hide

Showing 39 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Austria
 
  • Carinthia
    • Sankt Veit an der Glan District
      • Hüttenberg
        • Lölling