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Oyonite

A valid IMA mineral species
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Formula:
Ag3Mn2Pb4Sb7As4S24
Colour:
Black
Lustre:
Metallic
Hardness:
3 - 3½
Specific Gravity:
5.237 (Calculated)
Crystal System:
Monoclinic
Name:
Named after the Oyon district in which the type locality is located.
Oyonite belongs to the Sb-rich members of the andorite homeotypic sub-series. Chemically similar to menchettiite, lasmanisite, and uchucchacuaite. Also compare ramdohrite and 'dürfeldtite'.

Also compare luboržákite.

A phase chemically similar to oyonite, but with the (Pb-poorer) "approximate composition MnPbAg2Sb4As2S12" is reported by Kasatkin et al. (2022).


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Unique IdentifiersHide

Mindat ID:
52807
Long-form identifier:
mindat:1:1:52807:0

Similar NamesHide

AeoniteA synonym of 'Elaterite'
LyoniteA synonym of 'Chillagite'

IMA Classification of OyoniteHide

Classification of OyoniteHide

2.JB.40a

2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
J : Sulfosalts of PbS archetype
B : Galena derivatives, with Pb

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
OyoIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of OyoniteHide

Metallic
Transparency:
Opaque
Colour:
Black
Streak:
Black
Hardness:
3 - 3½ on Mohs scale
Hardness:
VHN100=137 kg/mm2 - Vickers
Tenacity:
Brittle
Density:
5.237 g/cm3 (Calculated)

Optical Data of OyoniteHide

Bireflectance:
Weakly to moderately
Reflectivity:
WavelengthR1 (%)R2 (%)
471nm33.9%40.2%
548nm32.5%38.9%
586nm31.6%38.0%
652nm29.8%36.5%


Graph shows reflectance levels at different wavelengths (in nm). Peak reflectance is 40.2%.
R1 shown in black, R2 shown in red
Internal Reflections:
None
Pleochroism:
Weak
Comments:
Dark grey to a dark green

Chemistry of OyoniteHide

Mindat Formula:
Ag3Mn2Pb4Sb7As4S24
Element Weights:
Element% weight
Sb26.770 %
Pb26.031 %
S24.171 %
Ag10.164 %
As9.413 %
Mn3.451 %

Calculated from ideal end-member formula.
Sb
Pb
S
Ag
As
Mn

Crystallography of OyoniteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/c
Setting:
P21/n
Cell Parameters:
a = 19.1806(18) Å, b = 12.7755(14) Å, c = 8.1789(10) Å
β = 90.471(1)°
Ratio:
a:b:c = 1.501 : 1 : 0.64
Unit Cell V:
2004.1 ų
Z:
2
Morphology:
Subhedral to anhedral crystals, up to 100 μm in length.
Comment:
Pseudo-orthorhombic.

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.34 Å(40)
3.29 Å(100)
2.920 Å(40)
2.821 Å(70)
2.045 Å(50)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
High-? alteration and/or metamorphism
33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12])

Type Occurrence of OyoniteHide

General Appearance of Type Material:
Black metallic subhedral to anhedral crystals, up to 100 μm in length.
Place of Conservation of Type Material:
Mineralogical collections of the Museo di Storia Naturale,Sezione di Mineralogia e Litologia, Università di Firenze, Via La Pira 4, I-50121, Firenze, Italy, catalogue number 3283/I
Chemical Analysis of Type Material:
Cu0.76 %
Ag8.39 %
Mn3.02 %
Pb24.70 %
As9.54 %
Sb28.87 %
S24.30 %
Total:99.58 %
Geological Setting of Type Material:
Hydrothermal epigenetic deposit.
Associated Minerals at Type Locality:

Synonyms of OyoniteHide

Other Language Names for OyoniteHide

Dutch:Oyoniet
German:Oyonit

Relationship of Oyonite to other SpeciesHide

Other Members of Lillianite Homologous Series:
AndreadiniiteCuHgAg7Pb7Sb24S48Mon. 2/m : P21/c
ArsenquatrandoriteAg17.6Pb12.8Sb38.1As11.5S96Mon. 2/m : P21/c
AschamalmitePb6-3xBi2+xS9Mon. 2/m : B2/m
BaiamareiteAg4Pb12Fe4Sb20S48Mon. 2/m
BrusnitsyniteMn3CuPbAs3Sb2S12Mon. 2/m : P21/c
Clino-oscarkempffiteAg15Pb6Sb21Bi18S72Mon. 2/m : P21/c
ErzwiesiteAg8Pb12Bi16S40Orth. mmm(2/m2/m2/m) : Cmcm
EskimoiteAg7Pb10Bi15S36Mon.
FizélyiteAg5Pb14Sb21S48Mon. 2/m : P21/c
GustaviteAgPbBi3S6Orth. mmm(2/m2/m2/m)
HeyrovskýitePb6Bi2S9Orth. mmm(2/m2/m2/m) : Cccm
HolubiteAg3Pb6(Sb8Bi3)S24Mon. 2/m : P21/c
JasrouxiteAg16Pb4(Sb25As15)S72Tric. 1 : P1
LasmanisiteAg12Pb13Mn11Sb44S96Orth. 222 : P212121
LazerckeriteAg3.75Pb4.50(Sb7.75Bi4)S24Mon. 2/m : P21/c
LillianitePb3-2xAgxBi2+xS6Orth. mmm(2/m2/m2/m)
MenchettiiteAgPb2.40Mn1.60Sb3As2S12Mon. 2/m : P21/c
OscarkempffiteAg10Pb4(Sb17Bi9)S48Orth. mm2
OurayiteAg3Pb4Bi5S13Orth.
QuatrandoriteAgPbSb3S6Mon. 2/m : P21/c
RamdohritePb5.9Fe0.1Mn0.1In0.1Cd0.2Ag2.8Sb10.8S24Mon. 2/m
RoshchiniteAg19Pb10Sb51S96Orth. mmm(2/m2/m2/m) : Pnma
'Schirmerite'PbAgBi3S6 - Pb3Ag1.5Bi3.5S9Orth.
SenandoriteAgPbSb3S6Orth. mm2 : Pmn21
StaročeskéiteAg0.70Pb1.60(Bi1.35Sb1.35)Σ2.70S6Orth. mmm(2/m2/m2/m) : Cmcm
TarutinoiteAg3Pb7Bi7S19Mon. 2/m : B2/m
TerrywallaceiteAgPb(Sb,Bi)3S6Mon. 2/m : P21/c
TreasuriteAg7Pb6Bi15S32Mon.
UchucchacuaiteAgMnPb3Sb5S12Orth. mmm(2/m2/m2/m) : Pmmm
UstarasitePb(Bi,Sb)6S10 (?)
VikingiteAg5Pb8Bi13S30Mon. 2/m : B2/m
XilingolitePb3Bi2S6Mon.

Related Minerals - Strunz-mindat GroupingHide

2.JB.Clino-oscarkempffiteAg15Pb6Sb21Bi18S72Mon. 2/m : P21/c
2.JB.ArsenquatrandoriteAg17.6Pb12.8Sb38.1As11.5S96Mon. 2/m : P21/c
2.JB.GinelfiteAg2(Ag0.5Fe)TlPb23.5(Sb,As)33.5S76Tric. 1 : P1
2.JB.AndreadiniiteCuHgAg7Pb7Sb24S48Mon. 2/m : P21/c
2.JB.ChukotkaiteAgPb7Sb5S15Mon. 2/m : P21/c
2.JB.SelenojunoiteCu2Pb3Bi8Se16Mon. 2/m : B2/m
2.JB.LechneriteAg10Cu4HgPb33Sb58S128Tric. 1 : P1
2.JB.Cuprosenandorite Ag16Cu8Pb24Sb72S144Orth. mm2 : Pna21
2.JB.MorleyiteAg2CuPb25Sb24As4S68.5Tric. 1 : P1
2.JB.LazerckeriteAg3.75Pb4.50(Sb7.75Bi4)S24Mon. 2/m : P21/c
2.JB.LasmanisiteAg12Pb13Mn11Sb44S96Orth. 222 : P212121
2.JB.MontpelvouxiteAgPb16Sb27As18S84Tric. 1 : P1
2.JB.SenandoriteAgPbSb3S6Orth. mm2 : Pmn21
2.JB.OscarkempffiteAg10Pb4(Sb17Bi9)S48Orth. mm2
2.JB.05DiaphoriteAg3Pb2Sb3S8Mon. 2/m : P21/c
2.JB.10CosalitePb2Bi2S5Orth. mmm(2/m2/m2/m)
2.JB.15MarriteAgPbAsS3Mon. 2/m : P21/c
2.JB.15FreieslebeniteAgPbSbS3Mon. 2/m : P21/c
2.JB.20CannizzaritePb48Bi56S132Mon. 2/m : P21/m
2.JB.20WittitePb9Bi12(S,Se)27Mon.
2.JB.25jRouxeliteCu2HgPb23Sb27S65.5Tric. 1 : P1
2.JB.25iNeyiteAg2Cu6Pb25Bi26S68Mon. 2/m : B2/m
2.JB.25aJunoiteCu2Pb3Bi8(S,Se)16Mon. 2/m : B2/m
2.JB.25fÁngelaiteCu2AgPbBiS4Orth. mmm(2/m2/m2/m) : Pnma
2.JB.25eGalenobismutitePbBi2S4Orth. mmm(2/m2/m2/m)
2.JB.25cNordströmiteCuPb3Bi7(Se4S10)Mon. 2/m : P21/m
2.JB.25iCuproneyiteCu7Pb27Bi25S68Mon. 2/m : B2/m
2.JB.25gNuffielditeCu1.4Pb2.4Bi2.4Sb0.2S7Orth. mmm(2/m2/m2/m)
2.JB.25hWeibullitePb5Bi8Se7S11Orth. mmm(2/m2/m2/m) : Pnma
2.JB.25dProuditeCuPb7.5Bi9.33(S,Se)22Mon. 2/m : B2/m
2.JB.25bFelbertaliteCu2Pb6Bi8S19Mon. 2/m : B2/m
2.JB.30aJordanitePb14As6S23Mon. 2/m : P21/m
2.JB.30aGeocronitePb14Sb6S23Mon. 2/m : P21/m
2.JB.30aArsenmarcobaldiitePb12(As3.2Sb2.8)Σ6S21Tric. 1 : P1
2.JB.30bKirkiitePb10Bi3As3S19Mon. 2/m : P21/m
2.JB.30cTsugaruitePb28As15S50ClOrth. mm2 : Pnn2
2.JB.30aMarcobaldiitePb12(Sb3As2Bi)Σ6S21Tric. 1 : P1
2.JB.35dPellouxite(Cu,Ag)Pb10Sb12S27O(Cl,S)0.6Mon. 2/m : B2/m
2.JB.35eChovanitePb15-2xSb14+2xS36Ox (x ~ 0.2)Mon. 2/m : B2/m
2.JB.35aZinkenitePb9Sb22S42Hex. 6 : P63
2.JB.35cPillaitePb9Sb10S23ClO0.5Mon. 2/m : B2/m
2.JB.35bScainiitePb14Sb30S54O5Mon. 2/m : B2/m
2.JB.35fTubuliteAg2Pb22Sb20S53 Mon. m : Pb
2.JB.40aFizélyiteAg5Pb14Sb21S48Mon. 2/m : P21/c
2.JB.40aRamdohritePb5.9Fe0.1Mn0.1In0.1Cd0.2Ag2.8Sb10.8S24Mon. 2/m
2.JB.40eUstarasitePb(Bi,Sb)6S10 (?)
2.JB.40a'Bursaite'Pb5Bi4S11 (?)Orth.
2.JB.40'UM1988-05-S:AgBiCuHgPb'(Hg,Ag,Cu,Pb)5Pb5Bi11S27
2.JB.40'UM1988-06-S:AgBiCuHgPb'(Pb,Hg)12(Cu,Ag)3(Bi,Sb)10(S,Te)27
2.JB.40aTerrywallaceiteAgPb(Sb,Bi)3S6Mon. 2/m : P21/c
2.JB.40aJasrouxiteAg16Pb4(Sb25As15)S72Tric. 1 : P1
2.JB.40aTarutinoiteAg3Pb7Bi7S19Mon. 2/m : B2/m
2.JB.40bHeyrovskýitePb6Bi2S9Orth. mmm(2/m2/m2/m) : Cccm
2.JB.40aQuatrandoriteAgPbSb3S6Mon. 2/m : P21/c
2.JB.40aErzwiesiteAg8Pb12Bi16S40Orth. mmm(2/m2/m2/m) : Cmcm
2.JB.40aVikingiteAg5Pb8Bi13S30Mon. 2/m : B2/m
2.JB.40a