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Molinelloite

A valid IMA mineral species - pending publication
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09418400017271952903366.jpg
Molinelloite

Molinello Mine, Ne, Genoa, Liguria, Italy
04511380017271952912373.jpg
Molinelloite

Molinello Mine, Ne, Genoa, Liguria, Italy
09677820017271952915462.jpg
Molinelloite

Molinello Mine, Ne, Genoa, Liguria, Italy
09418400017271952903366.jpg
Molinelloite

Molinello Mine, Ne, Genoa, Liguria, Italy
04511380017271952912373.jpg
Molinelloite

Molinello Mine, Ne, Genoa, Liguria, Italy
09677820017271952915462.jpg
Molinelloite

Molinello Mine, Ne, Genoa, Liguria, Italy
09418400017271952903366.jpg
Molinelloite

Molinello Mine, Ne, Genoa, Liguria, Italy
02555570017271952928214.jpg
Molinelloite

Molinello Mine, Ne, Genoa, Liguria, Italy
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About MolinelloiteHide

06684380017271952926477.jpg
Entrance

Molinello Mine, Ne, Genoa, Liguria, Italy
Formula:
Cu(H2O)(OH)V4+O(V5+O4)
Crystal System:
Triclinic
Name:
Named for the type locality, the Molinello mine, Italy.
Known synthetic analogue. The first vanadate mineral containing both copper and vanadyl group.

The occurrence at the Livorno province is not molinelloite but volborthite with small quantity of associated duttonite (Cristian Biagioni, PXRD, 23/07/2026).


Unique IdentifiersHide

Mindat ID:
50352
Long-form identifier:
mindat:1:1:50352:1

IMA Classification of MolinelloiteHide

IMA status:
Approved, Pending publication
IMA Formula:
Cu2+(H2O)(OH)V4+O(V5+O4)
Approval year:
2016

Classification of MolinelloiteHide

Strunz-mindat (2026):
8.DC.67

8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
C : With only medium-sized cations, (OH, etc.):RO4 = 1:1 and < 2:1

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
MnlIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Chemistry of MolinelloiteHide

Mindat Formula:
Cu(H2O)(OH)V4+O(V5+O4)
Element Weights:
Element% weight
O39.935 %
V36.329 %
Cu22.659 %
H1.078 %

Calculated from ideal end-member formula.
O
V
Cu
H
Elements listed:
Cu, H, O, V - search for minerals with similar chemistry

Crystallography of MolinelloiteHide

Crystal System:
Triclinic
Class (H-M):
1 - Pinacoidal
Space Group:
P1
Cell Parameters:
a = 5.122(1) Å, b = 5.296(1) Å, c = 10.356(2) Å
α = 100.01(3)°, β = 101.15(3)°, γ = 101.43(3)°
Ratio:
a:b:c = 0.967 : 1 : 1.955
Unit Cell V:
263.49 ų (Calculated from Unit Cell)

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
9.90 Å(80)
5.06 Å(20)
4.85 Å(60)
4.019 Å(100)
3.301 Å(35)
3.095 Å(80)
2.781 Å(45)
2.706 Å(25)
Locality:
Molinello Mine, Ne, Genoa, Liguria, Italy

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 7: Great Oxidation Event<2.4
47a : [Near-surface hydration of prior minerals]
47e : [Vanadates, chromates, manganates]

Type Occurrence of MolinelloiteHide

Type Locality:
ⓘ Molinello Mine, Ne, Genoa, Liguria, Italy
Place of Conservation of Type Material:
Mineralogical collections of the Natural History Museum, Vienna, Austria, catalogue no. N 9735

Synonyms of MolinelloiteHide

Other Language Names for MolinelloiteHide

Common AssociatesHide

Associations Based on Photo Data:
1 photo of Molinelloite associated with QuartzSiO2

Related Minerals - Strunz-mindat GroupingHide

8.DC.FerroberauniteFe2+Fe3+5(PO4)4(OH)5 · 6H2OMon. 2/m : B2/b
8.DC.CésarferreiraiteFe2+ Fe3+2(AsO4)2(OH)2 · 8H2OTric. 1 : P1
8.DC.FerrivauxiteFe3+Al2(PO4)2(OH)3 · 5H2OTric. 1 : P1
8.DC.IanbruceiteZn2(AsO4)(OH) · 3H2OMon. 2/m : P21/c
8.DC.05NissoniteCu2Mg2(PO4)2(OH)2 · 5H2OMon. 2/m : B2/b
8.DC.07EuchroiteCu2(AsO4)(OH) · 3H2OOrth. 222 : P212121
8.DC.10LegranditeZn2(AsO4)(OH) · H2OMon. 2/m : P21/c
8.DC.12StrashimiriteCu8(AsO4)4(OH)4 · 5H2OMon.
8.DC.15EarlshannoniteMn2+Fe3+2(PO4)2(OH)2 · 4H2OMon. 2/m : P21/c
8.DC.15KunatiteCuFe3+2(PO4)2(OH)2 · 4H2OMon. 2/m : P21/c
8.DC.15'UM2006-27-PO:FeHZn'ZnFe3+2(PO4)2(OH)2 · 4H2OMon.
8.DC.15'UKI-2006-(PO:AlCuFeH)'Fe2+Al3+2(PO4)2(OH)2 · 4H2O
8.DC.15CobaltarthuriteCoFe3+2(AsO4)2(OH)2 · 4H2OMon. 2/m : P21/c
8.DC.15ArthuriteCuFe3+2(AsO4)2(OH)2 · 4H2OMon. 2/m : P21/c
8.DC.15OjuelaiteZnFe3+2(AsO4)2(OH)2 · 4H2OMon. 2/m : P21/c
8.DC.15WhitmoreiteFe2+Fe3+2(PO4)2(OH)2 · 4H2OMon. 2/m : P21/c
8.DC.15BendadaiteFe2+Fe3+2(AsO4)2(OH)2 · 4H2OMon. 2/m : P21/c
8.DC.17KleemaniteZnAl2(PO4)2(OH)2 · 3H2OMon.
8.DC.20MagnesiobermaniteMgMn3+2(PO4)2(OH)2 · 4H2OMon. 2 : P21
8.DC.20BermaniteMn2+Mn3+2(PO4)2(OH)2 · 4H2OMon. 2/m : P2/b
8.DC.20CoralloiteMn2+Mn3+2(AsO4)2(OH)2 · 4H2OTric. 1 : P1
8.DC.22KovdorskiteMg2(PO4)(OH) · 3H2OMon. 2/m : P21/c
8.DC.25ZincostrunziteZnFe3+2(PO4)2(OH)2 · 6.5H2OTric. 1 : P1
8.DC.25MetavauxiteFe2+Al2(PO4)2(OH)2 · 8H2OMon. 2/m : P21/c
8.DC.25MetavivianiteFe2+Fe3+2(PO4)2(OH)2 · 6H2OTric. 1 : P1
8.DC.25FerristrunziteFe3+Fe3+2(PO4)2(OH)3 · 5H2OTric.
8.DC.25StrunziteMn2+Fe3+2(PO4)2(OH)2 · 6H2OTric. 1 : P1
8.DC.25FerrostrunziteFe2+Fe3+2(PO4)2(OH)2 · 6H2OTric.
8.DC.27BerauniteFe3+6(PO4)4O(OH)4 · 6H2OMon. m : Bb
8.DC.27TvrdýiteFe2+Fe3+2Al3(PO4)4(OH)5(H2O)4 · 2H2OMon. 2/m : B2/b
8.DC.27ZincoberauniteZnFe3+5(PO4)4(OH)5 · 6H2OMon. 2/m : B2/b
8.DC.30MaghrebiteMgAl2(AsO4)2(OH)2 · 8H2OTric. 1 : P1
8.DC.30FerrolaueiteFe2+Fe3+2(PO4)2(OH)2 · 8H2OTric. 1 : P1
8.DC.30UshkoviteMgFe3+2(PO4)2(OH)2 · 8H2OTric. 1 : P1
8.DC.30LaueiteMn2+Fe3+2(PO4)2(OH)2 · 8H2OTric. 1 : P1
8.DC.30ParavauxiteFe2+Al2(PO4)2(OH)2 · 8H2OTric. 1 : P1
8.DC.30SigloiteFe3+Al2(PO4)2(OH)3 · 7H2OTric. 1 : P1
8.DC.30NordgauiteMnAl2(PO4)2(F,OH)2 · 5H2OTric. 1 : P1
8.DC.30Kayrobertsonite[MnAl2(PO4)2(OH)2(H2O)4] · 2H2OTric. 1 : P1
8.DC.30KummeriteMn2+Fe3+Al(PO4)2(OH)2 · 8H2OTric. 1 : P1
8.DC.30MangangordoniteMn2+Al2(PO4)2(OH)2 · 8H2OTric. 1 : P1
8.DC.30StewartiteMn2+Fe3+2(PO4)2(OH)2 · 8H2OTric. 1 : P1
8.DC.30GordoniteMgAl2(PO4)2(OH)2 · 8H2OTric. 1 : P1
8.DC.30Kastningite(Mn2+,Fe2+,Mg)Al2(PO4)2(OH)2 · 8H2OTric. 1 : P1
8.DC.30PseudolaueiteMn2+Fe3+2(PO4)2(OH)2 · 8H2OMon. 2/m : P21/c
8.DC.32KamarizaiteFe3+3(AsO4)2(OH)3 · 3H2OTric. 1 : P1
8.DC.32TinticiteFe3+3(PO4)2(OH)3 · 3H2OTric. 1 : P1
8.DC.35VauxiteFe2+Al2(PO4)2(OH)2 · 6H2OTric. 1 : P1
8.DC.37VantasseliteAl4(PO4)3(OH)3 · 9H2OOrth.
8.DC.40CacoxeniteFe3+24AlO6(PO4)17(OH)12 · 75H2OHex. 6/m : P63/m
8.DC.45SouzaliteMg3Al4(PO4)4(OH)6 · 2H2OTric. 1
8.DC.45Gormanite(Fe2+,Mg)3(Al,Fe3+)4(PO4)4(OH)6 · 2H2OTric.
8.DC.47KingiteAl3(PO4)2F2(OH) · 7H2OTric.
8.DC.50AllanpringiteFe3+3(PO4)2(OH)3 · 5H2OMon. 2/m : P21/m
8.DC.50FluorwavelliteAl3(PO4)2(OH)2F · 5H2OOrth. mmm(2/m2/m2/m)
8.DC.50WavelliteAl3(PO4)2(OH)3 · 5H2OOrth. mmm(2/m2/m2/m)
8.DC.52KribergiteAl5(PO4)3(SO4)(OH)4 · 4H2OTric. 1 : P1
8.DC.55MapimiteZn2Fe3+3(AsO4)3(OH)4 · 10H2OMon. m : Bm
8.DC.57OgdensburgiteCa2Fe3+4(Zn,Mn2+)(AsO4)4(OH)6 · 6H2OOrth. mmm(2/m2/m2/m) : Cmmm
8.DC.60CloncurryiteCu0.5(VO)0.5Al2(PO4)2F2 · 5H2OMon. 2/m : P21/c
8.DC.60Nevadaite(Cu2+,Al,V3+)6Al8(PO4)8F8(OH)2 · 22H2OOrth. mmm(2/m2/m2/m)
8.DC.62KenngottiteMn2+3Fe3+4(PO4)4(OH)6(H2O)2 Mon. 2/m : P2/b
8.DC.70WhitecapsiteH16Fe2+5Fe3+14Sb3+6(AsO4)18O16 · 120H2OHex. 6/m : P63/m
8.DC.75HeimitePbCu2(AsO4)(OH)3 · 2H2OMon. 2/m : P21/c
8.DC.80LedneviteCu[PO3(OH)] · H2OMon. 2/m : P21/c

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for MolinelloiteHide

References for MolinelloiteHide

Localities for MolinelloiteHide

Showing 2 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Italy (TL)
 
  • Liguria
    • Genoa
      • Ne
Hålenius et al. (2016)
  • Tuscany
    • Livorno Province
      • Livorno
        • Valle Benedetta
Bonifazi (2021)
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