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Achalaite
A valid IMA mineral species
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About Achalaite
Formula:
(Fe2+,Mn)(Ti,Fe3+,Ta)(Nb,Ta)2O8
Colour:
Black
Lustre:
Metallic
Hardness:
5½
Specific Gravity:
6.285 (Calculated)
Crystal System:
Monoclinic
Member of:
Name:
After the type locality, the Achala granite batholith, located in Córdoba, Argentina.
Achalaite is the first member of the wodginite group with Nb dominant over Ta; it is genetically considered a post-magmatic phase.
In hand specimens achalaite shows the same properties as columbite-group minerals. (via Miguel Galliski)
In hand specimens achalaite shows the same properties as columbite-group minerals. (via Miguel Galliski)
Unique Identifiers
Mindat ID:
46039
Long-form identifier:
mindat:1:1:46039:6
IMA Classification of Achalaite
Approved
IMA Formula:
Fe2+Ti4+Nb5+2O8
Approval year:
2013
First published:
2016
Type description reference:
Galliski, Miguel Ángel, Márquez-Zavalía, María Florencia, Černý, Petr, Lira, Raúl, Colombo, Fernando, Roberts, Andrew C., Bernhardt, Heinz-Jürgen (2016) Achalaite, Fe2+TiNb2O8, a new member of the wodginite group from the La Calandria Granitic pegmatite, Córdoba, Argentina. The Canadian Mineralogist, 54 (4) 1043-1052 doi:10.3749/canmin.1500094
Classification of Achalaite
4.D0.
4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
D : Metal: Oxygen = 1:2 and similar
0 :
4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
D : Metal: Oxygen = 1:2 and similar
0 :
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Ahl | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Achalaite
Metallic
Colour:
Black
Streak:
Black
Hardness:
5½ on Mohs scale
Tenacity:
Brittle
Cleavage:
None Observed
Appears to lack cleavage
Appears to lack cleavage
Fracture:
Irregular/Uneven
Density:
6.285 g/cm3 (Calculated)
Comment:
Calculated based on empirical formula
Optical Data of Achalaite
Anisotropism:
Weak in air, particularly noticeable along grain boundaries; in oil, it is medium with light to intermediate olive grey tint
Bireflectance:
Weak but noticeable
Reflectivity:
| Wavelength | R1 (%) | R2 (%) | imR1 (%) | imR2 (%) |
|---|---|---|---|---|
| 400nm | 17.57% | 18.80% | 5.82% | 6.17% |
| 440nm | 17.25% | 18.15% | 5.50% | 6.03% |
| 470nm | 16.89% | 17.72% | 5.26% | 5.76% |
| 500nm | 16.66% | 17.50% | 5.12% | 5.53% |
| 546nm | 16.49% | 17.26% | 4.98% | 5.32% |
| 560nm | 16.45% | 17.16% | 4.96% | 5.29% |
| 589nm | 16.34% | 17.04% | 4.97% | 5.26% |
| 620nm | 16.37% | 17.07% | 4.94% | 5.25% |
| 650nm | 16.23% | 16.94% | 4.86% | 5.19% |
| 680nm | 16.16% | 16.85% | 4.85% | 5.17% |
| 700nm | 16.13% | 16.70% | 4.79% | 5.09% |
Graph shows reflectance levels at different wavelengths (in nm). Peak reflectance is 18.80%.
R1 shown in black, R2 shown in red, imR1 shown in green, imR2 shown in blue
Colour in reflected light:
Light grey with a slightly violet tint in air, and light grey with an olive tint in oil
Internal Reflections:
None observed
Pleochroism:
Non-pleochroic
Comments:
None
Chemistry of Achalaite
Mindat Formula:
(Fe2+,Mn)(Ti,Fe3+,Ta)(Nb,Ta)2O8
Element Weights:
Crystallography of Achalaite
Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/b
Setting:
C2/c
Cell Parameters:
a = 9.422(4) Å, b = 11.427(3) Å, c = 5.120(1) Å
β = 90.12(4)°
β = 90.12(4)°
Ratio:
a:b:c = 0.825 : 1 : 0.448
Unit Cell V:
551.2 ų
Z:
4
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 3.630 Å | (40) |
| 2.964 Å | (100) |
| 2.564 Å | (35) |
| 2.493 Å | (40) |
| 1.766 Å | (35) |
| 1.735 Å | (40) |
| 1.711 Å | (50) |
| 1.453 Å | (40) |
Reference:
Galliski, Miguel Ángel, Márquez-Zavalía, María Florencia, Černý, Petr, Lira, Raúl, Colombo, Fernando, Roberts, Andrew C., Bernhardt, Heinz-Jürgen (2016) Achalaite, Fe2+TiNb2O8, a new member of the wodginite group from the La Calandria Granitic pegmatite, Córdoba, Argentina. The Canadian Mineralogist, 54 (4) 1043-1052 doi:10.3749/canmin.1500094
Comments:
From Type Description.
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 4b: Highly evolved igneous rocks | >3.0 |
| 34 : Complex granite pegmatites |
Type Occurrence of Achalaite
General Appearance of Type Material:
As polygranular aggregates up to 1.5 cm across, included in albite
Place of Conservation of Type Material:
Type material is deposited in the collections of the Museo de Mineralogiá y Geologiá ‘‘Dr. Alfred Stelzner’’, Universidad Nacional de Córdoba, Córdoba, Argentina, catalogue number 3279
Empirical Formula of Type Material:
(Fe2+2.211Mn1.524Fe3+0.226U0.030Ca0.009)Σ4.000(Ti1.819Fe3+0.920Ta0.579Sn0.533Zr0.150)Σ4.000(Nb4.781Ta3.000W0.219)Σ8.000O32
Chemical Analysis of Type Material:
| WO3 | 2.41 % |
|---|---|
| Nb2O5 | 30.18 % |
| Ta2O5 | 37.56 % |
| TiO2 | 6.90 % |
| ZrO2 | 0.88 % |
| SnO2 | 3.82 % |
| Fe2O3 | 4.35 % |
| FeO | 7.54 % |
| MnO | 5.14 % |
| CaO | 0.02 % |
| UO2 | 0.38 % |
| Total: | 99.18 % |
Geological Setting of Type Material:
Granitic pegmatite
Associated Minerals at Type Locality:
Reference:
Galliski, Miguel Ángel, Márquez-Zavalía, María Florencia, Černý, Petr, Lira, Raúl, Colombo, Fernando, Roberts, Andrew C., Bernhardt, Heinz-Jürgen (2016) Achalaite, Fe2+TiNb2O8, a new member of the wodginite group from the La Calandria Granitic pegmatite, Córdoba, Argentina. The Canadian Mineralogist, 54 (4) 1043-1052 doi:10.3749/canmin.1500094
Synonyms of Achalaite
Other Language Names for Achalaite
Relationship of Achalaite to other Species
Member of:
Other Members of Wodginite Group:
| Ferrotitanowodginite | Fe2+TiTa2O8 | Mon. 2/m : B2/b |
| Ferrowodginite | Fe2+Sn4+Ta2O8 | Mon. 2/m : B2/b |
| Lithiotantite | LiTa3O8 | Mon. 2/m : P21/c |
| Lithiowodginite | LiTa3O8 | Mon. 2/m : B2/b |
| Sakhanaiskite | (Fe2+Ti)Nb2O8 | Mon. 2/m : P2/b |
| Tantalowodginite | (Mn2+0.5◻0.5)TaTa2O8 | Mon. 2/m : B2/b |
| Titanowodginite | Mn2+TiTa2O8 | Mon. 2/m : B2/b |
| Wodginite | Mn2+Sn4+Ta2O8 | Mon. 2/m : B2/b |
Common Associates
Associations Based on Photo Data:
Related Minerals - Strunz-mindat Grouping
| 4.D0. | Akaogiite | TiO2 |
| 4.D0. | Dmitryvarlamovite | Ti2(Fe3+Nb)O8 |
Fluorescence of Achalaite
None
Other Information
Notes:
Insoluble in HCl
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Achalaite
mindat.org URL:
https://www.mindat.org/min-46039.html
Please feel free to link to this page.
Please feel free to link to this page.
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References for Achalaite
Reference List:
Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2014) New minerals and nomenclature modifications approved in 2014, CNMNC Newsletter No 19. Mineralogical Magazine, 78 (1) 165-170 doi:10.1180/minmag.2014.078.1.12
Galliski, Miguel Ángel, Márquez-Zavalía, María Florencia, Černý, Petr, Lira, Raúl, Colombo, Fernando, Roberts, Andrew C., Bernhardt, Heinz-Jürgen (2016) Achalaite, Fe2+TiNb2O8, a new member of the wodginite group from the La Calandria Granitic pegmatite, Córdoba, Argentina. The Canadian Mineralogist, 54 (4) 1043-1052 doi:10.3749/canmin.1500094
Localities for Achalaite
Showing 2 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Argentina (TL) | |
| Galliski et al. (2016) |
Madagascar | |
| Färber (n.d.) |
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The
La Calandria mine, Cañada del Puerto, Ambul District, San Alberto Department, Córdoba Province, Argentina