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Hezuolinite

A valid IMA mineral species
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01051850017272472008061.jpg
He Zuolin
Formula:
(Sr,REE)4Zr(Ti,Fe3+)4(Si2O7)2O8
Colour:
Black
Lustre:
Resinous
Hardness:
5½ - 6
Specific Gravity:
4.28
Crystal System:
Monoclinic
Name:
Named in honor of He Zuolin (何作霖) (5 May 1900, Ji County, Hebei Province, China - 17 November 1967), professor of geology in Shandong University, Beijing Normal University, and the Chinese Academy of Sciences. He was a pioneer in the research of rare earth element (REE) deposits and discovered the first REE minerals at the Bayan Obo deposit in 1935. The type material is the same as an earlier described, but not approved, "saimaite" of Peng et al. (1963).
Dimorph of:
Rengeite
The Zr analogue of matsubaraite. Perrierite subgroup. Chemically intermediate between rengeite and perrierite.

Structurally similar to rengeite. One of the differences is that O(1), O(2) and O(3) sites in hezuolinite structure are split in rengeite's; the Si(1)-O(7)-Si(2) angle is less bent than in rengeite.


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Unique IdentifiersHide

Mindat ID:
41142
Long-form identifier:
mindat:1:1:41142:4

IMA Classification of HezuoliniteHide

Classification of HezuoliniteHide

Strunz-mindat (2026):
9.BE.70

9 : SILICATES (Germanates)
B : Sorosilicates
E : Si2O7 groups, with additional anions; cations in octahedral [6] and greater coordination
Dana 8th ed.:
56.2.13.10

56 : SOROSILICATES Si2O7 Groups, With Additional O, OH, F and H2O
2 : Si2O7 Groups and O, OH, F, and H2O with cations in [4] and/or >[4] coordination

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
HezIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of HezuoliniteHide

Lustre:
Resinous
Transparency:
Translucent
Colour:
Black
Streak:
Dark brown
Hardness:
5½ - 6 on Mohs scale
Hardness:
VHN100=683 - 964 kg/mm2 - Vickers
Tenacity:
Brittle
Cleavage:
None Observed
Parting:
None observed.
Fracture:
Conchoidal
Density:
4.28 g/cm3 (Measured)    4.30 g/cm3 (Calculated)

Optical Data of HezuoliniteHide

Type:
Biaxial (-)
Dispersion:
r > v, strong
Pleochroism:
Strong
Comments:
X = pale brown, Y = brown, Z = dark brown
Comments:
Average refractive index: n > 1.8

Chemistry of HezuoliniteHide

Mindat Formula:
(Sr,REE)4Zr(Ti,Fe3+)4(Si2O7)2O8
Element Weights:
Element% weight
O32.072 %
Sr31.934 %
Ti17.446 %
Si10.236 %
Zr8.312 %

Calculated from ideal end-member formula.
Elements listed:
Fe, O, Si, Sr, Ti, Zr - search for minerals with similar chemistry

Crystallography of HezuoliniteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/m
Setting:
C2/m
Cell Parameters:
a = 13.973(3) Å, b = 5.6984(11) Å, c = 11.988(2) Å
β = 114.10(3)°
Ratio:
a:b:c = 2.452 : 1 : 2.104
Unit Cell V:
871.3 ų
Z:
2
Twinning:
Polysynthetic twins were observed in some cases.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0018979HezuoliniteYang Z, Giester G, Ding K, Tillmanns E (2012) Hezuolinite, (Sr,REE)4Zr(Ti,Fe3+,Fe2+)2Ti2O8(Si2O7)2, a new mineral species of the chevkinite group from Saima alkaline complex, Liaoning Province, NE China European Journal of Mineralogy 24 189-1962012Saima alkaline complex, Liaoning Province, NE China0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4b: Highly evolved igneous rocks>3.0
35 : Ultra-alkali and agpaitic igneous rocks

Type Occurrence of HezuoliniteHide

Type Locality:
ⓘ Saima complex, Dandong, Liaoning, China
General Appearance of Type Material:
Non-metamict, anhedral crystals up to several micrometres in size.
Place of Conservation of Type Material:
Museum of the Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing (China). Registration no.: KDX016.
Geological Setting of Type Material:
Accessory mineral in a green-aegirine nepheline syenite.
Associated Minerals at Type Locality:
AegirineBiotiteEudialyteMicroclineNepheline
Rinkite-(Ce)Titanite
Reference:
Yang, Zhuming, Giester, Gerald, Ding, Kuishou, Tillmanns, Ekkehart (2012) Hezuolinite, (Sr,REE)4Zr(Ti,Fe3+,Fe2+)2Ti2O8(Si2O7)2, a new mineral species of the chevkinite group from Saima alkaline complex, Liaoning Province, NE China. European Journal of Mineralogy, 24 (1) 189-196 doi:10.1127/0935-1221/2011/0023-2158

Synonyms of HezuoliniteHide

Other Language Names for HezuoliniteHide

German:Hezuolinit
Simplified Chinese:何作霖矿

Relationship of Hezuolinite to other SpeciesHide

Member of:
Perrierite Subgroup > Chevkinite Group
Other Members of Perrierite Subgroup:
MatsubaraiteSr4Ti5(Si2O7)2O8Mon. 2/m : P21/b
Perrierite-(Ce)Ce4MgFe3+2Ti2(Si2O7)2O8Mon. 2/m : P21/b
Perrierite-(La)(La,Ce,Ca)4(Fe2+,Mn)(Ti,Fe3+,Al)4[(Si2O7)O4]2Mon. 2/m : P21/b
'Perrierite-(Nd)'Nd4MgFe3+2Ti2(Si2O7)2O8 ?
RengeiteSr4ZrTi4(Si2O7)2O8Mon. 2/m : P21/b
Strontiochevkinite(Sr,La,Ce,Ca)4Fe2+(Ti,Zr)2Ti2(Si2O7)2O8Mon. 2/m : P21/b

Related Minerals - Strunz-mindat GroupingHide

9.BE.ZinkgruvaniteBa4Mn2+4Fe3+2(Si2O7)2(SO4)2O2(OH)2Tric. 1 : P1
9.BE.Calciomurmanite(Na,◻)2Ca(Ti,Mg,Nb)4[Si2O7]2O2(OH,O)2(H2O)4Tric. 1 : P1
9.BE.CámaraiteBa3Na(Fe2+,Mn)8Ti4(Si2O7)4O4(OH,F)7Tric. 1
9.BE.AlfredcaspariteSr2TiO(Si2O7)Tet. 4mm : P4bm
9.BE.Batievaite-(Y)Y2Ca2Ti(Si2O7)2(OH)2(H2O)4Tric. 1 : P1
9.BE.Nacareniobsite-(Y)Na3Ca3YNb(Si2O7)2OF3Mon. 2/m : P21/b
9.BE.Alexkuznetsovite-(Ce)Ce2Mn(CO3)(Si2O7)Mon. 2/m : P21/b
9.BE.BobshannoniteNa2KBa(Mn,Na)8(Nb,Ti)4(Si2O7)4O4(OH)4(O,F)2Tric.
9.BE.ParalomonosoviteNa6◻4Ti4(Si2O7)2[PO3OH][PO2(OH)2]O2(OF)Tric. 1 : P1
9.BE.MadeiraiteNa2Ca2Fe2Zr2(Si2O7)2O2F2Mon. 2/m : P21/b
9.BE.BortolaniteCa2(Ca1.5Zr0.5)Na(NaCa)Ti(Si2O7)2(OF)F2Tric. 1 : P1
9.BE.Longshoushanite-(Ce)Ce4MgAl2Ti2(Si2O7)2O8Mon. 2/m : P21/b
9.BE.MoxuanxueiteNaCa6Zr(Si2O7)2OF3Tric. 1 : P1
9.BE.Delhuyarite-(Ce)Ce4Mg(Fe3+,W)3◻(Si2O7)2O6(OH)2Mon. 2/m : B2/m
9.BE.Christofschäferite-(Ce)Ce3CaMnTiFe3+Ti2(Si2O7)2O8 Mon. 2/m : P21/m
9.BE.XAsimowiteFe2+4O(Si2O7)Orth. mmm(2/m2/m2/m) : Imma
9.BE.Biraite-(La)La2Fe2+(CO3)(Si2O7)Mon. 2/m : P21/b
9.BE.PilanesbergiteNa2Ca2Fe2Ti2(Si2O7)2O2F2Mon. 2/m : P21/b
9.BE.02WadsleyiteMg4O(Si2O7)Orth. mmm(2/m2/m2/m) : Imma
9.BE.02Ohtaniite Mg3(Si0.5◻0.5)Si2O8Orth. mmm(2/m2/m2/m) : Imma
9.BE.05LawsoniteCaAl2(Si2O7)(OH)2 · H2OOrth. mmm(2/m2/m2/m) : Cmcm
9.BE.05HennomartiniteSrMn3+2(Si2O7)(OH)2 · H2OOrth. mmm(2/m2/m2/m) : Cmcm
9.BE.05CortesognoiteCaV2(Si2O7)(OH)2 · H2OOrth. mmm(2/m2/m2/m) : Cmcm
9.BE.05NoelbensoniteBaMn3+2(Si2O7)(OH)2 · H2OOrth. mm2
9.BE.05ItoigawaiteSrAl2(Si2O7)(OH)2 · H2OOrth. mmm(2/m2/m2/m) : Cmcm
9.BE.07IlvaiteCaFe3+Fe2+2(Si2O7)O(OH)Orth. mmm(2/m2/m2/m)
9.BE.07Amamoorite CaMn2+2Mn3+(Si2O7)O(OH)Mon. 2/m : P21/b
9.BE.07ManganilvaiteCaFe2+Fe3+Mn2+(Si2O7)O(OH)Mon. 2/m : P21/b
9.BE.10SuoluniteCa2(H2Si2O7) · H2OOrth. mm2 : Fdd2
9.BE.12JaffeiteCa6(Si2O7)(OH)6Trig. 3 : P3
9.BE.15FresnoiteBa2Ti(Si2O7)OTet. 4mm : P4bm
9.BE.17Janhaugite(Na,Ca)3(Mn2+,Fe2+)3(Ti,Zr,Nb)2(Si2O7)2O2(OH,F)2Mon. 2/m : P21/m
9.BE.17BurpaliteNa2CaZr(Si2O7)F2Mon. 2/m : P21/b
9.BE.17Niocalite(Ca,Nb)4(Si2O7)(O,OH,F)2Mon. m
9.BE.17NormanditeNaCa(Mn,Fe)(Ti,Nb,Zr)(Si2O7)OFMon. 2/m : P21/b
9.BE.17HiortdahliteNa2Ca4(Ca0.5Zr0.5)Zr(Si2O7)2OF3Tric. 1 : P1
9.BE.17LåveniteNa2Ca2Mn2Zr2(Si2O7)2O2F2Mon. 2/m : P21/b
9.BE.17CuspidineCa8(Si2O7)2F4Mon. 2/m : P21/b
9.BE.17WöhleriteNa2Ca4ZrNb(Si2O7)2O3FMon. 2 : P21
9.BE.17BaghdaditeCa6Zr2(Si2O7)2O4Mon. 2/m : P21/b
9.BE.20Nacareniobsite-(Ce)Na3Ca3(Ce,REE)Nb(Si2O7)2OF3Mon. 2/m : P21/b
9.BE.20Roumaite(Ca,Na,REE,◻)7(Nb,Ti)[Si2O7]2OF3Mon. m : Bb
9.BE.20Rinkite-(Ce)(Ca3Ce)Na(NaCa)Ti(Si2O7)2(OF)F2Mon. 2/m : P21/b
9.BE.20Nacareniobsite-(Nd) Ca2(CaNd)Na3Nb(Si2O7)2(OF)F2Mon. 2/m : P21/b
9.BE.20Rinkite-(Y)Na2Ca4YTi(Si2O7)2OF3Mon. 2/m : P21/b
9.BE.20Mosandrite-(Ce)(Ca3REE)[(H2O)2Ca0.5◻0.5]Ti(Si2O7)2(OH)2(H2O)2Mon. 2/m : P21/b
9.BE.22Hainite-(Y)Na2Ca4(Y,REE)Ti(Si2O7)2OF3Tric. 1 : P1
9.BE.22RosenbuschiteNa6Ca6Zr3Ti(Si2O7)4O2F6Tric. 1 : P1
9.BE.22GötzeniteNaCa6Ti(Si2O7)2OF3Tric. 1 : P1
9.BE.22Fogoite-(Y)Na3Ca2Y2Ti(Si2O7)2OF3Tric. 1 : P1
9.BE.22KochiteNa3Ca2MnZrTi(Si2O7)2OF3Tric. 1 : P1
9.BE.23DovyreniteCa6Zr(Si2O7)2(OH)4Orth. mmm(2/m2/m2/m) : Pnnm
9.BE.25Lamprophyllite(Na,Mn2+)3(Sr,Na)2(Ti,Fe3+)3(Si2O7)2O2(OH,O,F)2Mon. 2/m
9.BE.25SeidozeriteNa4MnZr2Ti(Si2O7)2O2F2Mon. 2/m : P2/b
9.BE.25Nabalamprophyllite(BaNa)Ti2Na3Ti(Si2O7)2O2(OH)2Mon. 2/m : P2/m
9.BE.25SchülleriteBa2Na(Mn,Ca)(Fe3+,Mg,Fe2+)2Ti2(Si2O7)2(O,F)4Tric. 1 : P1
9.BE.25EricssoniteBaMn2+2Fe3+(Si2O7)O(OH)Mon. 2/m : B2/m
9.BE.25GrenmariteNa4MnZr3(Si2O7)2O2F2Mon. 2/m : P2/b
9.BE.25KazanskyiteBaNa3Ti2Nb(Si2O7)2O2(OH)2(H2O)4Tric. 1 : P1
9.BE.25SaamiteBa◻Na3Ti2Nb(Si2O7)2O2(OH)F(H2O)2Tric. 1 : P1
9.BE.25EmmerichiteBa2Na(Na,Fe2+)2(Fe3+,Mg)Ti2(Si2O7)2O2F2Mon. 2/m : B2/m
9.BE.25Barytolamprophyllite(Ba,Na)2(Na,Ti,Fe3+)4Ti2(Si2O7)2O(OH,F)Mon.
9.BE.25'Ericssonite-2O'BaMn2+2Fe3+(Si2O7)O(OH)Orth.
9.BE.25Fluorbarytolamprophyllite(Ba,Sr)2[(Na,Fe2+)3(Ti,Mg)F2][Ti2(Si2O7)2O2]Mon. 2/m : B2/m
9.BE.25FluorlamprophylliteNa3(SrNa)Ti3(Si2O7)2O2F2Mon. 2/m : B2/m
9.BE.25LileyiteBa2(Na,Fe,Ca)3MgTi2(Si2O7)2O2F2Mon. 2/m : B2/m
9.BE.27KolskyiteCaNa2Ti4(Si2O7)2O4(H2O)7Tric. 1 : P1
9.BE.27VigrishiniteNaZnTi4(Si2O7)2O3(OH)(H2O)4Tric. 1 : P1
9.BE.27SelivanovaiteNaFe3+Ti4(Si2O7)2O4(H2O)4Tric. 1 : P1
9.BE.27MurmaniteNa2Ti2(Si2O7)O2 · 2H2OTric. 1 : P1
9.BE.30Epistolite(Na◻)Nb2Na3Ti(Si2O7)2O2(OH)2(H2O)4Tric. 1 : P1
9.BE.32LomonosoviteNa5Ti2(Si2O7)(PO4)O2Tric. 1 : P1
9.BE.35VuonnemiteNa11Ti4+Nb2(Si2O7)2(PO4)2O3(F,OH)Tric.
9.BE.37SoboleviteNa13Ca2Mn2Ti3(Si2O7)2(PO4)4O3F3Mon. m : Pb
9.BE.40Ferroinnelite Ba4Ti2Na(NaFe2+)Ti(Si2O7)2[(SO4)(PO4)]O2[O(OH)]Tric. 1 : P1
9.BE.40PhosphoinneliteNa3Ba4Ti3(Si2O7)2(PO4,SO4)2O2FTric.
9.BE.40Innelite Ba4Ti2Na(NaMn2+)Ti(Si2O7)2[(SO4)(PO4)]O2[O(OH)]Tric. 1 : P1
9.BE.42YoshimuraiteBa2Mn2Ti(Si2O7)(PO4)O(OH)Tric. 1 : P1
9.BE.42HoriiteBa2Mn2Mn4Ti2(Si2O7)2(PO4)2O2(OH)2Tric. 1 : P1
9.BE.45QuadruphiteNa6Na2(CaNa)2Na2Ti2Na2Ti2(Si2O7)2(PO4)4O4F2Tric. 1 : P1
9.BE.47PolyphiteNa5(Na4Ca2)Ti2(Si2O7)(PO4)3O2F2Tric. 1 : P1
9.BE.50Shkatulkalite Na2Nb2Na3Ti(Si2O7)2O2(FO)(H2O)4(H2O)3Tric. 1 : P1
9.BE.50BornemaniteNa6BaTi2Nb(Si2O7)2(PO4)O2(OH)FTric. 1 : P1
9.BE.55HejtmaniteBa2Mn2+4Ti2(Si2O7)2O2(OH)2F2Tric. 1
9.BE.55Bykovaite(Ba,Na,K)2(Na,Ti,Mn)4(Ti,Nb)2(Si2O7)2O2(H2O,F,OH)2 · 3.5H2OMon. 2/m
9.BE.55Nechelyustovite(Ba,Sr,K)2(Na,Ti,Mn)4(Ti,Nb)2(Si2O7)2O2(O,H2O,F)2 · 4.5H2OMon. 2/m : B2/m
9.BE.55BafertisiteBa2Fe2+4Ti2(Si2O7)2O2(OH)2F2Tric.
9.BE.60Delindeite(Na,K)2(Ba,Ca)2(Ti,Fe,Al)3(Si2O7)2O2(OH)2 · 2H2OMon. 2/m : B2/m
9.BE.62'Orthochevkinite'(Ce,La,Ca,Na,Th)4(Fe2+,Mg)2(Ti,Fe3+)3Si4O22Orth.
9.BE.62 va'Strontium Perrierite'(Ce,Sr,La,Ca)4Fe2+(Ti,Zr,Fe)2Ti2(Si2O7)2O8
9.BE.62'Chevkinite-(Nd)'(Nd,REE)4(Fe2+,Mg)(Fe2+,Ti,Fe3+)2(Ti,Fe3+)2(Si2O7)2O8 ?
9.BE.62'Perrierite-(Nd)'Nd4MgFe3+2Ti2(Si2O7)2O8 ?
9.BE.65BusseniteNa2Ba2Fe2+Ti(Si2O7)(CO3)(OH)3FTric. 1 : P1
9.BE.67JinshajiangiteBaNaFe2+4Ti2(Si2O7)2O2(OH)2FTric. 1 : P1
9.BE.67PerraultiteBaNaMn2+4Ti2(Si2O7)2O2(OH)2FTric. 1
9.BE.70Dingdaohengite-(Ce)(Ce,La)4Fe2+(Ti,Fe2+,Mg,Fe3+)2Ti2(Si2O7)2O8Mon. 2/m : P21/b
9.BE.70Perrierite-(Ce)Ce4MgFe3+2Ti2(Si2O7)2O8Mon. 2/m : P21/b
9.BE.70Karnasurtite-(Ce)(Ce,La,Th)(Ti,Nb)(Al,Fe)(Si2O7)(OH)4 · 3H2OAmor.
9.BE.70Maoniupingite-(Ce)(Ce,Ca)4(Fe3+,Ti,Fe2+,◻)(Ti,Fe3+,Fe2+,Nb)4(Si2O7)2O8Mon. 2/m : B2/m
9.BE.70MatsubaraiteSr4Ti5(Si2O7)2O8Mon. 2/m : P21/b
9.BE.70RengeiteSr4ZrTi4(Si2O7)2O8Mon. 2/m : P21/b
9.BE.70Polyakovite-(Ce)(Ce,Ca)4(Mg,Fe2+)(Cr3+,Fe3+)2(Ti,Nb)2(Si2O7)2O8Mon. 2/m : B2/m
9.BE.70'UM2008-53-SiO:SrTiZr'Sr4ZrTi4(Si2O7)2O8Orth. mmm(2/m2/m2/m) : Pbca
9.BE.70Chevkinite-(Ce)Ce4(Ti,Fe2+,Fe3+)5O8(Si2O7)2Mon. 2/m : P21/b
9.BE.70Perrierite-(La)(La,Ce,Ca)4(Fe2+,Mn)(Ti,Fe3+,Al)4[(Si2O7)O4]2Mon. 2/m : P21/b
9.BE.70Strontiochevkinite(Sr,La,Ce,Ca)4Fe2+(Ti,Zr)2Ti2(Si2O7)2O8Mon. 2/m : P21/b
9.BE.72FersmaniteCa4(Na,Ca)4(Ti,Nb)4(Si2O7)2O8F3Tric.
9.BE.75BelkoviteBa3(Nb,Ti)6(Si2O7)2O12Hex. 6m2 : P62m
9.BE.77NasonitePb6Ca4(Si2O7)3Cl2Hex. 6/m : P63/m
9.BE.80MelanotekitePb2Fe3+2(Si2O7)O2Orth. 222 : C2221
9.BE.80KentrolitePb2Mn3+2(Si2O7)O2Orth. mmm(2/m2/m2/m) : Pbcm
9.BE.82Alexkuznetsovite-(La)La2Mn(CO3)(Si2O7)Mon. 2/m : P21/b
9.BE.82TilleyiteCa5(Si2O7)(CO3)2Mon. 2/m : P21/b
9.BE.85KillalaiteCa6.4(H0.6Si2O7)2(OH)2Mon. 2/m : P21/m
9.BE.87Stavelotite-(La)(La,Nd,Ca)3Mn2+3Cu(Mn3+,Fe3+,Mn4+)26(Si2O7)6O30Trig. 3 : P31
9.BE.90Magnesiorowlandite-(Y)Y4(Mg,Fe)(Si2O7)2F2Tric. 1 : P1
9.BE.90Biraite-(Ce)Ce2Fe2+(Si2O7)(CO3)Mon. 2/m : P21/b
9.BE.92Cervandonite-(Ce)(Ce,Nd,La)(Fe3+,Fe2+,Ti,Al)3O2(Si2O7)(As3+O3)(OH)Trig. 3m : R3m
9.BE.92Chirvinskyite(Na,Ca)13(Fe,Mn,◻)2(Ti,Zr)5(Si2O7)4(OH,O)12 · 2H2OTric. 1 : P1
9.BE.95RusinoviteCa10(Si2O7)3Cl2 Orth. mmm(2/m2/m2/m) : Cmcm
9.BE.95BatisiviteBaV3+8Ti6(Si2O7)O22Tric. 1 : P1
9.BE.97Schlüterite-(Y)(Y,REE)2AlSi2O7(OH)2FMon. 2/m : P21/b

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for HezuoliniteHide

References for HezuoliniteHide

Localities for HezuoliniteHide

Showing 3 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
China
 
  • Liaoning
    • Dandong
      • Kuandian County
- (1978) +2 other references
Williams et al. (2011) +3 other references
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