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Moissanite

A valid IMA mineral species - grandfathered
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About MoissaniteHide

01206380017271925306840.jpg
Portrait of Henri Moissan
Formula:
SiC
Colour:
Green, black, blue, colourless, green yellow, yellow
Lustre:
Vitreous
Hardness:
9½
Specific Gravity:
3.218 - 3.22
Crystal System:
Hexagonal
Name:
Named in 1905 after Ferdinand Frederick Henri Moissan (28 September 1852 – 20 February 1907), a French chemist who, after years of research of high-temperature methods and furnaces for the production of carbides and synthetic diamonds, discovered the natural occurrence in the Canyon Diablo meteorite.

Moissan was the first to isolate elemental fluorine and received the 1906 Nobel Prize in Chemistry for that.
Dimorph of:
Moissanite, found as tiny crystals in some meteorites (originally formed in star dust) and kimberlites, is a naturally occurring silicon carbide, SiC (in synthetic form a very important high-performance ceramic, more commonly known as abrasive "carborundum").

A large number of polytypes (predominantly hexagonal or rhombohedral) is known.
Most of the natural moissanite grains are 6H and 15R polytypes (Shiryaev et al., 2011).

An unusual example of rock-forming moissanite, also of kimberlitic origin, is known from Turkey (Di Pierro et al., 2003).

Compare 'UM1982-06-C:Si'.




Unique IdentifiersHide

Mindat ID:
2743
Long-form identifier:
mindat:1:1:2743:0

Similar NamesHide

MiseniteA valid IMA mineral species - grandfatheredK8H6(SO4)7
β-MoissaniteA synonym of 'Moissanite-3C'

IMA Classification of MoissaniteHide

Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
Si4+C4-
First published:
1905

Classification of MoissaniteHide

1.DA.

1 : ELEMENTS (Metals and intermetallic alloys; metalloids and nonmetals; carbides, silicides, nitrides, phosphides)
D : Nonmetallic Carbides and Nitrides
A : Nonmetallic carbides
Dana 7th ed.:
1.3.7.1
1.3.8.1

1 : NATIVE ELEMENTS AND ALLOYS
3 : Semi-metals and non-metals
2.1

2 : Carbides, Nitrides, Silicides and Phosphides

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
MoiIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of MoissaniteHide

Vitreous
Transparency:
Transparent
Colour:
Green, black, blue, colourless, green yellow, yellow
Streak:
Greenish grey
Hardness:
9½ on Mohs scale
Cleavage:
Poor/Indistinct
{0001} Indistinct
Fracture:
Conchoidal
Density:
3.218 - 3.22 g/cm3 (Measured)    
Comment:
3.218 - 3.22, Average = 3.21

Optical Data of MoissaniteHide

Type:
Uniaxial (+)
RI values:
nω = 2.616 - 2.757 nε = 2.654 - 2.812
Birefringence:
0.2-0.3
Max. Birefringence:
δ = 0.038 - 0.055
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized uniaxial interference figure - the conoscopic (convergent-light, Bertrand-lens-in) view, for a grain cut with the optic axis centred and vertical. The coloured rings are isochromatics, computed with the same physics as the Michel-Lévy bar above; the dark cross is the isogyre.

For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.
Colour in reflected light:
Pale grey
Pleochroism:
Weak
Comments:
Pale blue to paler blue

Chemistry of MoissaniteHide

Mindat Formula:
SiC
Element Weights:
Element% weight
Si70.045 %
C29.955 %

Calculated from ideal end-member formula.
Si
C

Crystallography of MoissaniteHide

Polytype:
Formula:
Crystal System:
Class (H-M)
Space Group:
Space Group Setting:
Cell Parameters:
Ratio:
Unit Cell Volume (calc):
Z:
Comment:
Moissanite-10RMoissanite-15RMoissanite-2HMoissanite-33RMoissanite-3CMoissanite-4HMoissanite-5HMoissanite-6H
SiCSiCSiCSiCSiCSiCSiCSiC
 Trigonal      Hexagonal 
 3m - Ditrigonal Pyramidal     6mm - Dihexagonal Pyramidal
 R3m     P63mc
       P63mc

a = 3.08 Å, c = 37.85 Å





a = 3.073 Å, c = 15.08 Å
 a:c = 1 : 12.289     a:c = 1 : 4.907
 V 310.96 ų
(Calculated from Unit Cell)
     V 123.33 ų
(Calculated from Unit Cell)
       6
        

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0004279MoissaniteCapitani G C, Di Pierro S, Tempesta G (2007) The 6H-SiC structure model: Further refinement from SCXRD data from a terrestrial moissanite American Mineralogist 92 403-4072007150 km NW from Izmir, Turkey0293
0015175MoissaniteXu Y N, Ching W Y (1993) Electronic, optical, and structural properties of some wurtzite crystals Physical Review B48 4335-435119930293
0011553MoissaniteWyckoff R W G (1963) Second edition. Interscience Publishers, New York, New York Crystal Structures 1 85-23719630293
0017910MoissaniteBraekken H (1930) Zur Kristallstruktur des kubischen Karborunds _cod_database_code 1010995 Zeitschrift fur Kristallographie 75 572-57319300293
0017954MoissaniteOtt H (1925) Die Gitterstruktur des Karborunds ( Si C ) I. _cod_database_code 1011053 Zeitschrift fur Kristallographie 61 515-53119250293
0017937MoissaniteBurdick C, Owen E (1918) The Atomic Structure of Carborundum Determined by X-Rays _cod_database_code 1011031 Journal of the American Chemical Society 40 1749-175919180293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
- Å()
Comments:
X-ray powder diffraction data are given on the polytype pages.

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Pre-terrestrial "Ur-minerals">4.57
1 : Stellar atmosphere condensates
Stage 3a: Earth’s earliest Hadean crust>4.50
7 : Ultramafic igneous rocks
Near-surface Processes
26 : Hadean detrital minerals
29 : Lightning-generated minerals
Stage 4b: Highly evolved igneous rocks>3.0
35 : Ultra-alkali and agpaitic igneous rocks
36 : Carbonatites, kimberlites, and related igneous rocks
Stage 5: Initiation of plate tectonics<3.5-2.5
38 : Ophiolites
39 : High-𝑃 metamorphism (blueschist, eclogite, ultrahigh 𝑃 facies)

Type Occurrence of MoissaniteHide

General Appearance of Type Material:
Green hexagonal crystals, isolated by dissolving iron in HCl.
Geological Setting of Type Material:
Iron meteroite

Synonyms of MoissaniteHide

Other Language Names for MoissaniteHide

Italian:Moissanite
Portuguese:Moissanite
Simplified Chinese:莫桑石
Traditional Chinese:碳矽石

Common AssociatesHide

Associations Based on Photo Data:
2 photos of Moissanite associated with MuscoviteKAl2(AlSi3O10)(OH)2

Other InformationHide

Notes:
Concentrated sulfuric, nitric, and hydrochloric acids do not decompose it at their boiling point. Attacked by molten lead chromate. Does not burn in oxygen at 1000 C.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Industrial Uses:
Natural moissanite is too rare to be exploited, but synthetic silicon carbide is produdced as an abrasive, and synthetic moissanite crystals are grown to use as a gemstone and diamond simulant.

Internet Links for MoissaniteHide

References for MoissaniteHide

Reference List: