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Lindgrenite

A valid IMA mineral species - grandfathered
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About LindgreniteHide

09206280017271924772502.jpg
Waldemar Lindgren
Formula:
Cu3(MoO4)2(OH)2
Colour:
Green, yellowish green; pale green to yellow-green in transmitted light
Lustre:
Sub-Vitreous, Resinous
Hardness:
4½
Specific Gravity:
4.2
Crystal System:
Monoclinic
Name:
Named by Charles Palache in 1935 in honour of Waldemar Lindgren [February 14, 1860 Kalmar, Sweden - November 3, 1939 Brighton, Massachusetts, USA], Swedish-American economic geologist, professor at Massachusetts Institute of Technology, Cambridge, Massachusetts. He was a profound theorist on ore deposit formation.
A rare secondary mineral occurring in the oxidised zones of molybdenum-bearing copper deposits.


Unique IdentifiersHide

Mindat ID:
2405
Long-form identifier:
mindat:1:1:2405:7

IMA Classification of LindgreniteHide

Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
Cu2+3(Mo6+O4)2(OH)2
First published:
1935

Classification of LindgreniteHide

7.GB.05

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
G : Molybdates, Wolframates and Niobates
B : With additional anions and/or H2O
48.3.1.1

48 : ANHYDROUS MOLYBDATES AND TUNGSTATES
3 : Basic Anhydrous Molybdates and Tungstates
27.3.1

27 : Sulphites, Chromates, Molybdates and Tungstates
3 : Molybdates

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
LgrIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of LindgreniteHide

Sub-Vitreous, Resinous
Transparency:
Transparent
Colour:
Green, yellowish green; pale green to yellow-green in transmitted light
Streak:
Pale green
Hardness:
4½ on Mohs scale
Tenacity:
Brittle
Cleavage:
Perfect
On {010}, perfect; on {101} and {100}, very poor.
Fracture:
Micaceous
Density:
4.2 g/cm3 (Measured)    4.29 g/cm3 (Calculated)

Optical Data of LindgreniteHide

Type:
Biaxial (-)
RI values:
nα = 1.930 nβ = 2.002 nγ = 2.020
2V:
Measured: 71° , Calculated: 50°
Birefringence:
0.090
Max. Birefringence:
δ = 0.090
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
r > v strong
Optical Extinction:
Z ∧ c = 9°.

Chemistry of LindgreniteHide

Mindat Formula:
Cu3(MoO4)2(OH)2
Element Weights:
Element% weight
Mo35.243 %
Cu35.007 %
O29.380 %
H0.370 %

Calculated from ideal end-member formula.
Mo
Cu
O
H

Crystallography of LindgreniteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/c
Setting:
P21/n
Cell Parameters:
a = 5.394 Å, b = 14.023 Å, c = 5.608 Å
β = 98.5°
Ratio:
a:b:c = 0.385 : 1 : 0.4
Unit Cell V:
419.53 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Crystals tabular or platy {010}, exhibiting {010}, which may be striated parallel [001]. Also may exhibit forms {100}, {021}, and several others. Rarely acicular along [101] with a square outline; crusts; massive.

Forms include {001}, {010}, {100}, {120}, {110}, {210}, {012}, {101}, {111}, {113}, {111}, {121}. {121}, {131}.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0018341LindgreniteBao R L, Kong Z P, Cu M, Yue B, Weng L H, He H Y (2006) Hydrothermal synthesis and thermal stability of natural mineral lindgrenite Chemical Research in Chinese Universities 22 679-6832006synthetic0293
0014795LindgreniteHawthorne F C, Eby R K (1985) Refinement of the crystal structure of lindgrenite Neues Jahrbuch fur Mineralogie, Monatshefte 1985 234-2401985Chuquicamata, Chile0293
0005073LindgreniteCalvert L D, Barnes W H (1957) The structure of lindgrenite The Canadian Mineralogist 6 31-5119570293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
4.16 Å(50)
3.58 Å(30)
3.52 Å(100)
3.48 Å(70)
2.78 Å(20)
2.72 Å(30)
2.68 Å(40)
2.67 Å(20)
Comments:
36-0405.

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 7: Great Oxidation Event<2.4
47a : [Near-surface hydration of prior minerals]

Type Occurrence of LindgreniteHide

General Appearance of Type Material:
Thin green plates, with brilliant facets on their edges to a maximum diameter of about 4 mm.
Place of Conservation of Type Material:
The Natural History Museum, London, England: #1936,102.
Harvard University, Cambridge, Massachusetts, USA: #97527, 97528.
Geological Setting of Type Material:
Oxidized zone of a copper deposit.
Associated Minerals at Type Locality:

Other Language Names for LindgreniteHide

Common AssociatesHide

Associations Based on Photo Data:
12 photos of Lindgrenite associated with BrochantiteCu4(SO4)(OH)6
10 photos of Lindgrenite associated with PowelliteCa(MoO4)
9 photos of Lindgrenite associated with ChalcophylliteCu18Al2(AsO4)4(SO4)3(OH)24 · 36H2O
8 photos of Lindgrenite associated with MolybdeniteMoS2
5 photos of Lindgrenite associated with MalachiteCu2(CO3)(OH)2
4 photos of Lindgrenite associated with CalciteCaCO3
3 photos of Lindgrenite associated with SzenicsiteCu3(MoO4)(OH)4
3 photos of Lindgrenite associated with BorniteCu5FeS4
3 photos of Lindgrenite associated with QuartzSiO2
2 photos of Lindgrenite associated with HueniteCu4(MoO4)3(OH)2

Related Minerals - Strunz-mindat GroupingHide

7.GB.Stunorthropite(NH4)4[Mo2O6(MoO4)2]Tric. 1 : P1
7.GB.HartkoppeiteCa4Mn2+Mo6+6As5+4O32(OH)2(H2O)14 · 5H2OTric. 1 : P1
7.GB.WangpuiteK3(PO4)(Mo12O36)Iso. m3m(4/m32/m) : Pn3m
7.GB.AlexearliteHg3S2(MoO4)Orth. mmm(2/m2/m2/m) : Pnma
7.GB.OotanniteTh4+2W6+4O16 · 5H2OMon. 2/m : P21/c
7.GB.NatromolybditeNa2MoO4 · 2H2OOrth. mmm(2/m2/m2/m) : Pbca
7.GB.Marsaalamite-(Y)Y(MoO4)(OH)Mon. 2/m : P21/c
7.GB.10SzenicsiteCu3(MoO4)(OH)4Orth. mmm(2/m2/m2/m) : Pnnm
7.GB.15'UM1999-38-WO:CrV'(V, Cr, W, O, H) [V:Cr:W ratio about 2:1:3]
7.GB.15HueniteCu4(MoO4)3(OH)2Trig. 3m : P31c
7.GB.15CuprotungstiteCu2(WO4)(OH)2Tet. 422 : P41212
7.GB.20Phyllotungstite(H2O,M)x(W,Fe)(O,OH)3 · yH2O (M = Ca, Cs, Pb or K)Hex. 6/mmm(6/m2/m2/m) : P63/mmc
7.GB.25RankachiteCa0.5(V4+,V5+)(W6+,Fe3+)2O8(OH) · 2H2OMon. 2/m : P21/m
7.GB.30FerrimolybditeFe2(MoO4)3 · nH2OOrth. mmm(2/m2/m2/m) : Pmmn
7.GB.35MpororoiteWAlO3(OH)3 · 2(H2O)Tric.
7.GB.35AnthoiniteAlWO3(OH)3Tric. 1
7.GB.40Obradovicite-KCu[K2(H2O)17Cu(H2O)6][Mo8As2Fe3+3O34(OH)3]Orth. mmm(2/m2/m2/m) : Pmna
7.GB.45Paramendozavilite[KAl4(H2O)30][Mo12P6Fe3+6O60(OH)13]Mon.
7.GB.45Mendozavilite-NaFe[Na2(H2O)15Fe3+(H2O)6][Mo8P2Fe3+3O35(OH)2]Mon. 2/m : B2/m
7.GB.45Obradovicite-NaCuNa2(H2O)17Cu(H2O)6][Mo8As2Fe3+3O34(OH)3] Orth. mmm(2/m2/m2/m) : Pmna
7.GB.45Obradovicite-NaNa[Na2(H2O)16Na(H2O)6][Mo8As2Fe3+3O33(OH)4] Orth.
7.GB.50Tancaite-(Ce)FeCe(MoO4)3 · 3H2O Trig. 3 : R3
7.GB.50Mendozavilite-NaCu[Na2(H2O)15Cu(H2O)6][Mo8P2Fe3+3O34(OH)3] Mon. 2/m : B2/m
7.GB.50Mendozavilite-KCa[K2(H2O)15Ca(H2O)6][Mo8P2Fe3+3O34(OH)3] Mon. 2/m : B2/m
7.GB.60PeterandreseniteMn4Nb6O19 · 14H2OMon. 2/m : B2/m
7.GB.60HansesmarkiteCa2Mn2Nb6O19 · 20H2OTric. 1 : P1
7.GB.60MelcheriteBa2Na2Mg[Nb6O19] · 6H2OTrig. 3 : R3
7.GB.65IchnusaiteTh(MoO4)2 · 3H2OMon. 2/m : P21/c
7.GB.70MarkascheriteCu3(MoO4)(OH)4Mon. 2/m : P21/m
7.GB.75NuragheiteTh(MoO4)2 · H2OMon. 2/m : P21/c
7.GB.80OphiriteCa2Mg4[Zn2Mn3+2(H2O)2(Fe3+W9O34)2] · 46H2OTric. 1 : P1

Other InformationHide

Notes:
Readily soluble in HCl and HNO3.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for LindgreniteHide

References for LindgreniteHide

Reference List:

Localities for LindgreniteHide

Showing 28 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Chile
 
  • Antofagasta
    • Antofagasta Province
      • Sierra Gorda
        • Caracoles mining district
          • Caracoles
A.Molina & M. Dini collections - ...
    • El Loa Province
      • Calama
        • Chuquicamata District
Palache (1935) +2 other references
  • Atacama
    • Chañaral Province
      • Diego de Almagro
        • San Pedro de Cachiyuyo mining district
          • Delirio mine
pers. comm. T. Szenics to C. Lemanski (2006)
    • Copiapó Province
      • Copiapó
        • Cachiyuyo de Llampos mining district
          • Carrera Pinto
Maurizio Dini collection
    • Huasco Province
      • Vallenar
Samples analysed by Dr. Jochen Schluter
  • O'Higgins
    • Cachapoal Province
      • Rancagua
        • El Teniente
Royal Ontario Museum
Europe
 
  • Ore Mountains
Sejkora et al. (2023)
France
 
  • Nouvelle-Aquitaine
    • Haute-Vienne
      • Bellac
        • Vaulry
          • Vaulry Mines
Queneau (n.d.)
Japan
 
  • Nara Prefecture
Miyazaki et al (2000) +1 other reference
Morocco
 
  • Drâa-Tafilalet Region
Favreau et al. (2019)
Norway
 
  • Telemark
    • Tokke
Raade (1983) +1 other reference
      • Klauvreid
        • Bandaksli copper mines
Raade (1983) +1 other reference
Turkey
 
  • Kirklareli Province
    • Demirköy District
Erik Vercammen Find and Collection
UK
 
  • England
    • Cumbria
      • Eden
        • Mungrisdale
Kingsbury et al. (1955) +3 other references
USA
 
  • Arizona
    • Gila County
      • Miami-Inspiration Mining District
        • Inspiration
          • Miami-Inspiration deposit
Anthony et al. (1995)
Reed et al. (1962)
Galbraith et al. (1959) +2 other references
    • Maricopa County
      • Palo Verde Mountains
Schaller (1932) +2 other references
    • Pima County
      • Sierrita Mountains
        • Pima Mining District
Anthony et al. (1995)
    • Pinal County
      • Bunker Hill Mining District (Copper Creek Mining District)
        • Copper Creek (Copper Creek Canyon)
Anthony et al. (1995)
      • Riverside Mining District
        • Kelvin
Anthony et al. (1995)
Anthony et al. (1995)
  • California
    • Plumas County
      • Last Chance Mining District
        • Adams Peak
Pemberton (1983)
Dunning et al. (2005)
  • Colorado
    • San Miguel County
Kampf et al. (2019)
  • Idaho
    • Adams County
Rocks & Min. 70:244
        • Cuprum
Ream (2004)
Ream (1995)
 
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