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Konyaite

A valid IMA mineral species
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About KonyaiteHide

Formula:
Na2Mg(SO4)2 · 5H2O
Colour:
White, colourless
Hardness:
2½
Specific Gravity:
2.088
Crystal System:
Monoclinic
Name:
After the locality near Cakmak, Great Konya Basin, Konya Province, Central Anatolia Region, Turkey.
Higher-hydrate counterpart of blödite.

A water-soluble mineral that occurs as a component of salt efflorescences on saline soils, formed between 30°C and 50°C by evaporation of ground and surface waters.

Related to the Picromerite Group.

Compare UM2008-50-SO:HMgNa and uklonskovite.


Unique IdentifiersHide

Mindat ID:
2251
Long-form identifier:
mindat:1:1:2251:0

Similar NamesHide

KenyaiteA valid IMA mineral speciesNa2Si22O41(OH)8 · 6H2O

IMA Classification of KonyaiteHide

Approved
IMA Formula:
Na2Mg(S6+O4)2·5H2O
Approval year:
1981

Classification of KonyaiteHide

7.CC.80

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
C : Sulfates (selenates, etc.) without additional anions, with H2O
C : With medium-sized and large cations
29.3.5.1

29 : HYDRATED ACID AND NORMAL SULFATES
3 : A2B(XO4)2·xH2O
25.3.10

25 : Sulphates
3 : Sulphates of Mg

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
KnyIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of KonyaiteHide

Transparency:
Transparent
Colour:
White, colourless
Streak:
White
Hardness:
2½ on Mohs scale
Density:
2.088 g/cm3 (Measured)    2.097 g/cm3 (Calculated)

Optical Data of KonyaiteHide

Type:
Biaxial (+)
RI values:
nα = 1.464 nβ = 1.468 nγ = 1.474
2V:
Measured: 74° , Calculated: 80°
Max. Birefringence:
δ = 0.010
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Moderate (negative)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
r > v strong

Chemistry of KonyaiteHide

Mindat Formula:
Na2Mg(SO4)2 · 5H2O
Element Weights:
Element% weight
O59.007 %
S18.194 %
Na13.044 %
Mg6.895 %
H2.860 %

Calculated from ideal end-member formula.
O
S
Na
Mg
H

Crystallography of KonyaiteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/b
Cell Parameters:
a = 5.78 Å, b = 24.01 Å, c = 8.67 Å
β = 95.41°
Ratio:
a:b:c = 0.241 : 1 : 0.361
Unit Cell V:
1,197.84 ų (Calculated from Unit Cell)
Z:
4

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0017884KonyaiteMills S J, Wilson S A, Dipple G M, Raudsepp M (2010) The decomposition of konyaite: importance in CO2 fixation in mine tailings Mineralogical Magazine 74 903-9172010synthetic0293
0004958KonyaiteLeduc E M S, Peterson R C, Wang R (2009) The crystal structure and hydrogen bonding of synthetic konyaite, Na2Mg(SO4)2*5H2O American Mineralogist 94 1005-10112009synthetic0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
4.541 Å(100)
4.017 Å(45)
3.960 Å(45)
2.597 Å(45)
12.01 Å(40)
4.202 Å(40)
2.659 Å(40)
Comments:
Synthetic. The data are from the type description. Lines for a natural sample are also given, but without intensities.

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Near-surface Processes
25 : Evaporites (prebiotic)
Stage 7: Great Oxidation Event<2.4
45b : [Other oxidized fumarolic minerals]
Stage 10a: Neoproterozoic oxygenation/terrestrial biosphere<0.6
48 : Soil leaching zone minerals<0.6
50 : Coal and/or oil shale minerals<0.36
Geological Setting:
Occurs in salt efflorescences on saline soils, formed between 30° C and 50° C by evaporation of ground and surface waters.

Type Occurrence of KonyaiteHide

General Appearance of Type Material:
Intimate intergrowths with associated minerals.
Place of Conservation of Type Material:
Nationaal Natuurhistorisch Museum, Leiden, Netherlands (type).
Geological Setting of Type Material:
Salt efflorescences on saline soil. The salts originate at the soil surface by evaporation of ground and surface waters.
Associated Minerals at Type Locality:

Synonyms of KonyaiteHide

Other Language Names for KonyaiteHide

Dutch:Konyaiet
German:Konyait
Spanish:Konyaita

Relationship of Konyaite to other SpeciesHide

Structurally related to group(s):
Picromerite GroupA2M(XO4)2 · 6H2O

Common AssociatesHide

Associations Based on Photo Data:
2 photos of Konyaite associated with ThénarditeNa2SO4
2 photos of Konyaite associated with BlöditeNa2Mg(SO4)2 · 4H2O
1 photo of Konyaite associated with PicromeriteK2Mg(SO4)2 · 6H2O

Related Minerals - Strunz-mindat GroupingHide

7.CC.CobaltoblöditeNa2Co(SO4)2 · 4H2OMon. 2/m : P21/b
7.CC.AndychristyitePbCu2+Te6+O5(H2O)Tric. 1 : P1
7.CC.Ammoniovoltaite(NH4)2Fe2+5Fe3+3Al(SO4)12(H2O)18Iso. m3m(4/m32/m) : Fd3c
7.CC.05KrausiteKFe(SO4)2 · H2OMon. 2/m : P21/m
7.CC.10TamarugiteNaAl(SO4)2 · 6H2OMon. 2/m : P21/b
7.CC.15MendoziteNaAl(SO4)2 · 11H2OMon. 2/m : B2/b
7.CC.15KaliniteKAl(SO4)2 · 11H2OMon. 2/m : B2/b
7.CC.20Alum-(Na)NaAl(SO4)2 · 12H2OIso. m3(2/m3) : Pa3
7.CC.20Lonecreekite(NH4)Fe3+(SO4)2 · 12H2OIso. m3(2/m3) : Pa3
7.CC.20Alum-(K)KAl(SO4)2 · 12H2OIso. m3(2/m3) : Pa3
7.CC.20Tschermigite(NH4)Al(SO4)2 · 12H2OIso. m3(2/m3) : Pa3
7.CC.20LanmuchangiteTl+Al(SO4)2 · 12H2OIso. m3(2/m3) : Pa3
7.CC.25ZincovoltaiteK2Zn5Fe3+3Al(SO4)12 · 18H2OIso. m3m(4/m32/m) : Fd3c
7.CC.25VoltaiteK2Fe2+5Fe3+3Al(SO4)12 · 18H2OIso. m3m(4/m32/m) : Fd3c
7.CC.25MagnesiovoltaiteK2Mg5Fe3+3Al(SO4)12 · 18H2OIso. m3m(4/m32/m) : Fd3c
7.CC.25PertlikiteK2(Fe2+,Mg)2(Mg,Fe3+)4Fe3+2Al(SO4)12 · 18H2OTet. 4/mmm(4/m2/m2/m) : I41/acd
7.CC.25Ammoniomagnesiovoltaite(NH4)2Mg2+5Fe3+3Al(SO4)12 · 18H2OIso. m3m(4/m32/m) : Fd3c
7.CC.30KröhnkiteNa2Cu(SO4)2 · 2H2OMon. 2/m : P21/b
7.CC.35FerrinatriteNa3Fe(SO4)3 · 3H2OTrig. 3 : P3
7.CC.40GoldichiteKFe(SO4)2 · 4H2OMon. 2/m : P21/b
7.CC.45LöweiteNa12Mg7(SO4)13 · 15H2OTrig. 3 : R3
7.CC.50NickelblöditeNa2Ni(SO4)2 · 4H2OMon. 2/m : P21/b
7.CC.50BlöditeNa2Mg(SO4)2 · 4H2OMon. 2/m : P21/b
7.CC.50ChangoiteNa2Zn(SO4)2 · 4H2OMon. 2/m : P21/b
7.CC.55