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Mendozite

A valid IMA mineral species - grandfathered
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About MendoziteHide

08592580017271925081525.jpg
Flag of Mendoza province, Argentina
Formula:
NaAl(SO4)2 · 11H2O
Colour:
Colourless (turns white upon exposure); colourless in transmitted light.
Hardness:
3
Specific Gravity:
1.730
Crystal System:
Monoclinic
Name:
Named after the province of Mendoza, Argentina, that includes the supposed type locality of St. Juan.

Closely related to the members of the Alum Group.


Unique IdentifiersHide

Mindat ID:
2643
Long-form identifier:
mindat:1:1:2643:3

IMA Classification of MendoziteHide

Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
NaAl(S6+O4)2·11H2O

Classification of MendoziteHide

7.CC.15

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
C : Sulfates (selenates, etc.) without additional anions, with H2O
C : With medium-sized and large cations
29.5.4.1

29 : HYDRATED ACID AND NORMAL SULFATES
5 : AB(XO4)2·xH2O
25.6.13

25 : Sulphates
6 : Sulphates of Al and Tl

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
MzIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of MendoziteHide

Transparency:
Transparent
Colour:
Colourless (turns white upon exposure); colourless in transmitted light.
Hardness:
Cleavage:
Distinct/Good
{100}, good; {001} and {010}, indistinct.
Density:
1.730 g/cm3 (Measured)    1.781 g/cm3 (Calculated)

Optical Data of MendoziteHide

Type:
Biaxial (-)
RI values:
nα = 1.449(1) nβ = 1.461(3) nγ = 1.463(3)
2V:
Measured: 56° (1), Calculated: 44°
Max. Birefringence:
δ = 0.014
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Moderate
Dispersion:
r > v distinct

Chemistry of MendoziteHide

Mindat Formula:
NaAl(SO4)2 · 11H2O
Element Weights:
Element% weight
O69.047 %
S14.566 %
Al6.129 %
Na5.222 %
H5.037 %

Calculated from ideal end-member formula.

Crystallography of MendoziteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/b
Setting:
C2/c
Cell Parameters:
a = 21.75(3) Å, b = 9.11(1) Å, c = 8.30(1) Å
β = 92.28(5)°
Ratio:
a:b:c = 2.387 : 1 : 0.911
Unit Cell V:
1,643.28 ų (Calculated from Unit Cell)
Z:
4
Morphology:
Artificial crystals are prismatic [001] with large {100}; also pseudo-rhombohedral with {100} and {211}. Fibrous masses.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0000289MendoziteFang J H, Robinson P D (1972) Crystal structures and mineral chemistry of double-salt hydrates: II. The crystal structure of mendozite, NaAl(SO4)2.11H2O American Mineralogist 57 1081-108819720293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.50 Å(100)
4.76 Å(85)
4.58 Å(65)
4.15 Å(50)
3.60 Å(35)
2.644 Å(35)
10.9 Å(30)
Comments:
synthetic

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 7: Great Oxidation Event<2.4
45a : [Sulfates, arsenates, selenates, antimonates]
47a : [Near-surface hydration of prior minerals]
47b : [Sulfates and sulfites]
Stage 10a: Neoproterozoic oxygenation/terrestrial biosphere<0.6
50 : Coal and/or oil shale minerals<0.36
Stage 10b: Anthropogenic minerals<10 Ka
55 : Anthropogenic mine minerals
56 : Slag and smelter minerals (see also #51 and #55)

Type Occurrence of MendoziteHide

Synonyms of MendoziteHide

Other Language Names for MendoziteHide

Related Minerals - Strunz-mindat GroupingHide

7.CC.CobaltoblöditeNa2Co(SO4)2 · 4H2OMon. 2/m : P21/b
7.CC.AndychristyitePbCu2+Te6+O5(H2O)Tric. 1 : P1
7.CC.Ammoniovoltaite(NH4)2Fe2+5Fe3+3Al(SO4)12(H2O)18Iso. m3m(4/m32/m) : Fd3c
7.CC.05KrausiteKFe(SO4)2 · H2OMon. 2/m : P21/m
7.CC.10TamarugiteNaAl(SO4)2 · 6H2OMon. 2/m : P21/b
7.CC.15KaliniteKAl(SO4)2 · 11H2OMon. 2/m : B2/b
7.CC.20Alum-(Na)NaAl(SO4)2 · 12H2OIso. m3(2/m3) : Pa3
7.CC.20Lonecreekite(NH4)Fe3+(SO4)2 · 12H2OIso. m3(2/m3) : Pa3
7.CC.20Alum-(K)KAl(SO4)2 · 12H2OIso. m3(2/m3) : Pa3
7.CC.20Tschermigite(NH4)Al(SO4)2 · 12H2OIso. m3(2/m3) : Pa3
7.CC.20LanmuchangiteTl+Al(SO4)2 · 12H2OIso. m3(2/m3) : Pa3
7.CC.25ZincovoltaiteK2Zn5Fe3+3Al(SO4)12 · 18H2OIso. m3m(4/m32/m) : Fd3c
7.CC.25VoltaiteK2Fe2+5Fe3+3Al(SO4)12 · 18H2OIso. m3m(4/m32/m) : Fd3c
7.CC.25MagnesiovoltaiteK2Mg5Fe3+3Al(SO4)12 · 18H2OIso. m3m(4/m32/m) : Fd3c
7.CC.25PertlikiteK2(Fe2+,Mg)2(Mg,Fe3+)4Fe3+2Al(SO4)12 · 18H2OTet. 4/mmm(4/m2/m2/m) : I41/acd
7.CC.25Ammoniomagnesiovoltaite(NH4)2Mg2+5Fe3+3Al(SO4)12 · 18H2OIso. m3m(4/m32/m) : Fd3c
7.CC.30KröhnkiteNa2Cu(SO4)2 · 2H2OMon. 2/m : P21/b
7.CC.35FerrinatriteNa3Fe(SO4)3 · 3H2OTrig. 3 : P3
7.CC.40GoldichiteKFe(SO4)2 · 4H2OMon. 2/m : P21/b
7.CC.45LöweiteNa12Mg7(SO4)13 · 15H2OTrig. 3 : R3
7.CC.50NickelblöditeNa2Ni(SO4)2 · 4H2OMon. 2/m : P21/b
7.CC.50