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Grossular-Uvarovite Series

A solid-solution series between two end-member minerals
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About Grossular-Uvarovite SeriesHide

Crystal System:
Isometric
Series Formula:
Ca3Al2(SiO4)3 to Ca3Cr23+(SiO4)3
A series between Grossular and Uvarovite

See also Chrome-Grossular.


Unique IdentifiersHide

Mindat ID:
8634
Long-form identifier:
mindat:1:1:8634:5

Chemical AnalysisHide

Oxide wt%:
Showing 12 of 21 analyses on this page.
 123456789101112
TiO20.27 %00.10 %0.15 %0.72 %0.11 %0.15 %0.22 %0.10 %0.40 %
Al2O321.02 %22.40 %21.31 %18.33 %10.09 %12.00 %17.98 %19.75 %7.55 %8.29 %1.13 %19.64 %
Fe2O30.32 %0.00 %6.42 %2.01 %2.47 %5.20 %3.81 %1.23 %0.61 %2.46 %
Cr2O30.09 %13.92 %12.25 %0.00 %18.87 %18.65 %27-04 %0.48 %
MnO0.31 %0.60 %9.44 %35.63 %0.31 %0.05 %0.24 %0.05 %0.68 %0.03 %1.13 %
MgO0.26 %0.36 %0.15 %0.20 %0.00 %0.01 %0.06 %0.58 %0-04 %0.68 %
CaO37.53 %37.07 %17.2 %33.62 %34.04 %37.27 %36.5 %33.79 %33.33 %33.31 %34.82 %
V2O30.61 %0.45 %0.17 %2.99 %
SiO239.2 %38.09 %38.26 %39.79 %36.37 %38.68 %39.29 %39.56 %36.22 %37.40 %35.88 %38.61 %
FeO00.63 %13.45 %0.41 %0.07 %
Na2O0.00 %
K2O0.00 %
H2O00.10 %
ZrO20.00 %
Y2O3
Total:99.61 %98.99 %100.02 %100.32 %97.64 %99.64 %99.9 %100.43 %97.99 %99.81 %99.81 %98.82 %
Empirical formulas:
Sample IDEmpirical Formula
13(Ca2.8,Mg0.06,Fe0.05)2.91(Al1.00,Cr0.94,Fe0.06)2 (SiO4)3.034
6Ca2.87,Mg0.02,Fe0.02)2.91(Al1.11,Cr0.76,Fe0.13)2 (SiO4)3.04
7Ca3.06(Al1.63Fe3+0.30Ti0.01)( Si3.01O12)
14(Ca2.88Fe0.11Mn0.02Mg0.01)3.03(Al1.42Fe0.50Ti0.04)1.96Si2.97O12
8(Ca2.97Fe0.02Mn0.01)3.00(Al1.76Fe0.22Ti0.02)2.00Si3.00O12
10(Mg0.07Mn0.05Ca2.86)2.98(Al0.78Fe3+0.04Cr1.18V0.01Ti0.01)2.02Si2.997
15(Ca2.94Mg0.03Mn0.01)( Cr1.79Fe0.15Al0.06Ti0.08)( Si2.93O12)
Sample references:
IDLocalityReferenceNotes
1Sรธr Rondane Mountains, Queen Maud Land, East Antarctica, AntarcticaSample: Green (tsavorite) porphyroblast Method: Microprobe
2Jeffrey Mine, Val-des-Sources, Les Sources RCM, Estrie, Quรฉbec, CanadaSample: Light brown and pale orange coloured crystal. Method: Electron-probe micro-analyses were performed with a HITACHI X-569S microprobe operating at an accelerating voltage of 15 kV and a beam current of 15 nA
3Wazuka-cho, Soraku District, Kyoto Prefecture, JapanSample: An intermediate grossular, almandine, spessartine composition from a metamorphosed marl.
4Bellecombe, Chรขtillon, Aosta Valley, ItalySample: Red euhedral grossular (hessonite) crystals associated with clinochlore from rodingite. Method: Quantitative chemical compositions, line scans, backscattered electron (BSE) images, and X-ray elemental maps were collected with a JEOL JXA-8200 WD-ED electron-probe microanalysis (EPMA). The JEOL operating program on a Solaris platform was used for ZAF (atomic number, Z; absorption, A; fluorescence, F) correction and data reduction
5Saranovskii Mine, Sarany, Gornozavodskii District, Perm Krai, RussiaGrs46.35uv42,9prp0.61sps0.72and5.90CaTi2.11glm1.41
6Luikonlahti Mine, Kaavi, North Savo, FinlandSample from pyrrhotite-garnet quartzite. Wet chemical analysis
7Flekkeren, Skien, Telemark, NorwayEMPA analysed garnet from a contact metamorphic limestone.
8Grallagh, Clifden, Connemara, Galway County, Connacht, IrelandEMPA analysis (University of Glasgow) of the core of a skarn garnet.
9Saranovskii Mine, Sarany, Gornozavodskii District, Perm Krai, RussiaAl- rich uvarovite. uv59.68Gr35.59And3.7Pyr0.25Sps0.12CaTi0.66
10Outokumpu mining district, North Karelia, FinlandMicroprobe analysis of a single crystal of uvarovite enclosed in quartz, Outokumpu. The analytical data provided here is the average of 12 analyses taken with 0.5mm spacing across a single crystal (rim-core-rim). The crystal is relatively homogeneous with the composition ranging from uv59.1gr32.8 to uv63.4gr30.7.
11  "  "Wet chemical analysis of uvarovite in uvarovite-tremolite-tawmawite-pyrrhotine vein, Analyst: L. Lokka (in P. Eskola, 1933)
12Tsavorite mining area, Gogogogo, Gogogogo Commune, Ampanihy District, Atsimo-Andrefana, Madagascar
13Luikonlahti Mine, Kaavi, North Savo, FinlandSample from pyrrhotite/diopside/garnet ore. Wet chemical analysis.
14Grallagh, Clifden, Connemara, Galway County, Connacht, IrelandEMPA analysis (University of Glasgow) of the rim of a skarn garnet.
15Flekkeren, Skien, Telemark, NorwayEMPA analysed garnet from a contact metamorphic limestone.

Crystallography of Grossular-Uvarovite SeriesHide

Crystal System:
Isometric

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0020179GrossularAntao S M (2013) Is near-endmember birefringent grossular non-cubic? New evidence from synchrotron diffraction The Canadian Mineralogist 51 771-7842013Laghman, Afghanistan0293
0020178GrossularAntao S M (2013) Is near-endmember birefringent grossular non-cubic? New evidence from synchrotron diffraction The Canadian Mineralogist 51 771-7842013Tanzania0293
0020177GrossularAntao S M (2013) Is near-endmember birefringent grossular non-cubic? New evidence from synchrotron diffraction The Canadian Mineralogist 51 771-7842013Tanzania0293
0020176GrossularAntao S M (2013) Is near-endmember birefringent grossular non-cubic? New evidence from synchrotron diffraction The Canadian Mineralogist 51 771-7842013Jeffrey mine, Asbestos, Canada0293
0020175GrossularAntao S M (2013) Is near-endmember birefringent grossular non-cubic? New evidence from synchrotron diffraction The Canadian Mineralogist 51 771-7842013Jeffrey mine, Asbestos, Canada0293
0020174GrossularAntao S M (2013) Is near-endmember birefringent grossular non-cubic? New evidence from synchrotron diffraction The Canadian Mineralogist 51 771-7842013Jeffrey mine, Asbestos, Canada0293
0020173GrossularAntao S M (2013) Is near-endmember birefringent grossular non-cubic? New evidence from synchrotron diffraction The Canadian Mineralogist 51 771-7842013Jeffrey mine, Asbestos, Canada0293
0010465GrossularResende J A L C, Fernandes N G (2005) X-ray powder refinement of a natural garnet from Diamantina, Minas Gerais, Brazil Acta Crystallographica E61 i265-i2672005Diamantina, Minas Gerais, Brazil0293
0007907GrossularQuartieri S, Chaboy J, Merli M, Oberti R, Ungaretti L (1995) Local structural environment of calcium in garnets: A combined structure-refinement and XANES investigation Physics and Chemistry of Minerals 22 159-1691995Val di Fassa, Italy0293
0007906GrossularQuartieri S, Chaboy J, Merli M, Oberti R, Ungaretti L (1995) Local structural environment of calcium in garnets: A combined structure-refinement and XANES investigation Physics and Chemistry of Minerals 22 159-1691995Bric Canizzi, Liguria, Italy0293
0007905GrossularQuartieri S, Chaboy J, Merli M, Oberti R, Ungaretti L (1995) Local structural environment of calcium in garnets: A combined structure-refinement and XANES investigation Physics and Chemistry of Minerals 22 159-1691995Voltri, Liguria, Italy0293
0000634GrossularHazen R M, Finger L W (1978) Crystal structures and compressibilities of pyrope and grossular to 60 kbar American Mineralogist 63 297-3031978Georgetown, California, USA0293
0000244UvaroviteNovak G A, Gibbs G V (1971) The crystal chemistry of the silicate garnets sample Uv American Mineralogist 56 791-8231971Washington, Nevada Co, California, USA0293
0000243GrossularNovak G A, Gibbs G V (1971) The crystal chemistry of the silicate garnets sample Gr American Mineralogist 56 791-8251971Asbestos, Quebec, Canada0293
0000242GrossularNovak G A, Gibbs G V (1971) The crystal chemistry of the silicate garnets sample Mn-Gr American Mineralogist 56 791-8251971unknown0293
0000635GrossularHazen R M, Finger L W (1978) Crystal structures and compressibilities of pyrope and grossular to 60 kbar American Mineralogist 63 297-3031978Georgetown, California, USA1.9293
0000636GrossularHazen R M, Finger L W (1978) Crystal structures and compressibilities of pyrope and grossular to 60 kbar American Mineralogist 63 297-3031978Georgetown, California, USA3.5293
0000637GrossularHazen R M, Finger L W (1978) Crystal structures and compressibilities of pyrope and grossular to 60 kbar American Mineralogist 63 297-3031978Georgetown, California, USA6.1293
0000450GrossularMeagher E P (1975) The crystal structures of pyrope and grossularite at elevated temperatures garnet American Mineralogist 60 218-22819750298
0008734UvaroviteAndrut M, Wildner M (2002) The crystal chemistry of birefringent natural uvarovites. Part III. Application of the superposition model of crystal fields with a characterization of synthetic cubic uvarovite Physics and Chemistry of Minerals 29 595-60820020293
0002775GrossularRodehorst U, Geiger C A, Armbruster T (2002) The crystal structures of grossular and spessartine between 100 and 600 K and the crystal chemistry of grossular-spessartine solid solutions American Mineralogist 87 542-54920020293
0002774GrossularRodehorst U, Geiger C A, Armbruster T (2002) The crystal structures of grossular and spessartine between 100 and 600 K and the crystal chemistry of grossular-spessartine solid solutions American Mineralogist 87 542-54920020293
0002773GrossularRodehorst U, Geiger C A, Armbruster T (2002) The crystal structures of grossular and spessartine between 100 and 600 K and the crystal chemistry of grossular-spessartine solid solutions American Mineralogist 87 542-54920020293
0002772GrossularRodehorst U, Geiger C A, Armbruster T (2002) The crystal structures of grossular and spessartine between 100 and 600 K and the crystal chemistry of grossular-spessartine solid solutions American Mineralogist 87 542-54920020293
0002771GrossularRodehorst U, Geiger C A, Armbruster T (2002) The crystal structures of grossular and spessartine between 100 and 600 K and the crystal chemistry of grossular-spessartine solid solutions American Mineralogist 87 542-54920020293
0002770GrossularRodehorst U, Geiger C A, Armbruster T (2002) The crystal structures of grossular and spessartine between 100 and 600 K and the crystal chemistry of grossular-spessartine solid solutions American Mineralogist 87 542-54920020293
0002769GrossularRodehorst U, Geiger C A, Armbruster T (2002) The crystal structures of grossular and spessartine between 100 and 600 K and the crystal chemistry of grossular-spessartine solid solutions American Mineralogist 87 542-54920020293
0002768GrossularRodehorst U, Geiger C A, Armbruster T (2002) The crystal structures of grossular and spessartine between 100 and 600 K and the crystal chemistry of grossular-spessartine solid solutions American Mineralogist 87 542-54920020293
0002767GrossularRodehorst U, Geiger C A, Armbruster T (2002) The crystal structures of grossular and spessartine between 100 and 600 K and the crystal chemistry of grossular-spessartine solid solutions American Mineralogist 87 542-54920020293
0002766GrossularRodehorst U, Geiger C A, Armbruster T (2002) The crystal structures of grossular and spessartine between 100 and 600 K and the crystal chemistry of grossular-spessartine solid solutions American Mineralogist 87 542-54920020293
0002725UvaroviteWildner M, Andrut M (2001) The crystal chemistry of birefringent natural uvarovites: Part II. Single-crystal X-ray structures American Mineralogist 86 1231-125120010293
0002724UvaroviteWildner M, Andrut M (2001) The crystal chemistry of birefringent natural uvarovites: Part II. Single-crystal X-ray structures American Mineralogist 86 1231-125120010293
0002723UvaroviteWildner M, Andrut M (2001) The crystal chemistry of birefringent natural uvarovites: Part II. Single-crystal X-ray structures American Mineralogist 86 1231-125120010293
0001927GrossularGeiger C A, Armbruster T (1997) Mn3Al2Si3O12 spessartine and Ca3Al2Si3O12 grossular garnet: Structural dynamics and thermodynamic properties American Mineralogist 82 740-74719970293
0001924GrossularGeiger C A, Armbruster T (1997) Mn3Al2Si3O12 spessartine and Ca3Al2Si3O12 grossular garnet: Structural dynamics and thermodynamic properties American Mineralogist 82 740-74719970293
0001570GrossularGanguly J, Cheng W, O'Neill H St C (1993) Syntheses, volume, and structural changes of garnets in the pyrope-grossular join: Implications for stability and mixing properties Sample JW11 American Mineralogist 78 583-59319930293
0001569GrossularGanguly J, Cheng W, O'Neill H St C (1993) Syntheses, volume, and structural changes of garnets in the pyrope-grossular join: Implications for stability and mixing properties Sample JW15 American Mineralogist 78 583-59319930293
0001568GrossularGanguly J, Cheng W, O'Neill H St C (1993) Syntheses, volume, and structural changes of garnets in the pyrope-grossular join: Implications for stability and mixing properties Sample JW3 American Mineralogist 78 583-59319930293
0001567GrossularGanguly J, Cheng W, O'Neill H St C (1993) Syntheses, volume, and structural changes of garnets in the pyrope-grossular join: Implications for stability and mixing properties Sample JW22 American Mineralogist 78 583-59319930293
0001148GrossularAllen F M, Buseck P R (1988) XRD, FTIR, and TEM studies of optically anisotropic grossular garnets American Mineralogist 73 568-58419880293
0001147GrossularAllen F M, Buseck P R (1988) XRD, FTIR, and TEM studies of optically anisotropic grossular garnets American Mineralogist 73 568-58419880293
0001109GrossularLager G A, Rossman G R, Rotella F J, Schultz A J (1987) Neutron-diffraction structure of a low-water grossular at 20K American Mineralogist 72 766-76819870293
0007369GrossularArni R, Langer K, Tillmanns E (1985) Mn3+ in garnets III. Absence of Jahn-Teller distortion in synthetic Mn3+ -bearing garnet Physics and Chemistry of Minerals 12 279-28219850293
0017956GrossularMenzer G (1926) Die Kristallstruktur von Granat. _cod_database_code 1011055 Zeitschrift fur Kristallographie 63 157-15819260293
0001926GrossularGeiger C A, Armbruster T (1997) Mn3Al2Si3O12 spessartine and Ca3Al2Si3O12 grossular garnet: Structural dynamics and thermodynamic properties American Mineralogist 82 740-74719970100
0001923GrossularGeiger C A, Armbruster T (1997) Mn3Al2Si3O12 spessartine and Ca3Al2Si3O12 grossular garnet: Structural dynamics and thermodynamic properties American Mineralogist 82 740-74719970100
0001928GrossularGeiger C A, Armbruster T (1997) Mn3Al2Si3O12 spessartine and Ca3Al2Si3O12 grossular garnet: Structural dynamics and thermodynamic properties American Mineralogist 82 740-74719970500
0001925GrossularGeiger C A, Armbruster T (1997) Mn3Al2Si3O12 spessartine and Ca3Al2Si3O12 grossular garnet: Structural dynamics and thermodynamic properties American Mineralogist 82 740-74719970550
0000451GrossularMeagher E P (1975) The crystal structures of pyrope and grossularite at elevated temperatures garnet American Mineralogist 60 218-22819750638
0000452GrossularMeagher E P (1975) The crystal structures of pyrope and grossularite at elevated temperatures garnet American Mineralogist 60 218-22819750948
CIF Raw Data - click here to close

Common AssociatesHide

Associations Based on Photo Data:
1 photo of Grossular-Uvarovite Series associated with 'Nephrite'

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Grossular-Uvarovite Series in petrologyHide

An essential component of rock names highlighted in red, an accessory component in rock names highlighted in green.

Internet Links for Grossular-Uvarovite SeriesHide

References for Grossular-Uvarovite SeriesHide

Reference List:

Localities for Grossular-Uvarovite SeriesHide

Showing 2,892 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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