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Bournonite

A valid IMA mineral species - grandfathered
This page kindly sponsored by Mark Kucera
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About BournoniteHide

Formula:
PbCuSbS3
Colour:
Steel-gray
Lustre:
Metallic
Hardness:
2½ - 3
Specific Gravity:
5.83
Crystal System:
Orthorhombic
Name:
Named in 1805 by Robert Jameson in honor of Jacques-Louis, Comte de Bournon [21 January 1751 - 24 August 1825], crystallographer and mineralogist. Count de Bournon left France after the French Revolution to England and did not return to France until the Bourbon Restoration in 1814. Count de Bournon was an active mineralogist and researched the composition of meteorites (as early as 1802), but his research in mineralogical classification is his best-known contribution and he authored several detailed mineral collection catalogs featuring his classifications. Count de Bournon was one of the founders of the Geological Society in 1807. Count de Bournon named fibrolite.

Unique IdentifiersHide

Mindat ID:
741
Long-form identifier:
mindat:1:1:741:6

Similar NamesHide

IMA Classification of BournoniteHide

Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
Cu1+Pb2+Sb3+S2-3

Classification of BournoniteHide

2.GA.50

2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
G : Sulfarsenites, sulfantimonites, sulfbismuthites
A : Neso-sulfarsenites, etc. without additional S
3.4.3.2

3 : SULFOSALTS
4 : ø = 3
5.7.2

5 : Sulphosalts - Sulpharsenites and Sulphobismuthites (those containing Sn, Ge,or V are in Section 6)
7 : Sulpharsenites etc. of Pb and other metals

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.

SymbolSourceReference for Standard
BnnIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43
BnnThe Canadian Mineralogist (2019)The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download

Pronunciation of BournoniteHide

Pronunciation:
PlayRecorded byCountry
Jolyon RalphUnited Kingdom

Physical Properties of BournoniteHide

Metallic
Transparency:
Opaque
Colour:
Steel-gray
Streak:
Steel-gray
Hardness:
2½ - 3 on Mohs scale
Hardness:
VHN100=176 - 205 kg/mm2 - Vickers
Hardness Data:
Measured
Tenacity:
Brittle
Cleavage:
Imperfect/Fair
Imperfect on {010}, less perfect on {100}{001}
Fracture:
Irregular/Uneven, Sub-Conchoidal
Density:
5.83 g/cm3 (Measured)    5.84 g/cm3 (Calculated)

Optical Data of BournoniteHide

Anisotropism:
Weak
Reflectivity:
WavelengthR1 (%)R2 (%)
400nm37.0%37.4%
420nm36.8%37.3%
440nm36.5%37.2%
460nm36.1%37.0%
480nm35.6%36.8%
500nm35.2%36.6%
520nm34.8%36.4%
540nm34.3%36.2%
560nm33.8%35.8%
580nm33.4%35.5%
600nm33.0%35.1%
620nm32.7%34.7%
640nm32.3%34.0%
660nm32.0%33.4%
680nm31.4%32.7%
700nm30.8%32.1%


Graph shows reflectance levels at different wavelengths (in nm). Peak reflectance is 37.4%.
R1 shown in black, R2 shown in red
Colour in reflected light:
White
Pleochroism:
Weak
Comments:
Very weak.

Chemistry of BournoniteHide

Mindat Formula:
PbCuSbS3
Element Weights:
Element% weight
Pb42.398 %
Sb24.915 %
S19.684 %
Cu13.003 %

Calculated from ideal end-member formula.
Pb
Sb
S
Cu
Common Impurities:
As,Ag,Fe,Zn,Mn,Ni

Crystallography of BournoniteHide

Crystal System:
Orthorhombic
Class (H-M):
mm2 - Pyramidal
Space Group:
Pmn21
Cell Parameters:
a = 8.153(1) Å, b = 8.692(3) Å, c = 7.793(2) Å
Ratio:
a:b:c = 0.938 : 1 : 0.897
Unit Cell V:
552.26 ų (Calculated from Unit Cell)
Z:
4
Morphology:
Crystals usually short prismatic to tabular [001]. Crystals often form sub-parallel aggregates. Faces {hk0} striated [001], {h01} striated [010], {100} lustrous and striated [010], {010} usually smooth and lustrous.
Twinning:
On {110} very common often repeated, forming cruciform or wheel-like aggregates ("cogwheels"). Twin gliding: x1 {110}, δ2 [110]. Usually exhibits polysynthetic twinning on {110}, in part due to deformation.

Crystallographic forms of BournoniteHide

Crystal Atlas:
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Bournonite no.98 - {001} - Goldschmidt (1913-1926)
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Bournonite - Repeated contact twin on {110}
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Bournonite - Contact twin on {110}
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Bournonite - Tabular {001}
3d models and HTML5 code kindly provided by www.smorf.nl.

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Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0010713BournoniteEdenharter A, Nowacki W, Takeuchi Y (1970) Verfeinerung der kristallstruktur von bournonit [SbS3)2|Cu(IV)2PB(VII)Pb(VIII)] und von seligmannit [(AsS3)2)|Cu(IV)2Pb(VII)PB(VIII)] Zeitschrift fur Kristallographie 131 397-4171970Kanton Graubunden0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Loading XRD data...
Data Set:
Data courtesy of RRUFF project at University of Arizona, used with permission.
Powder Diffraction Data:
d-spacingIntensity
2.74 Å(100)
3.90 Å(80)
1.765 Å(60)
2.59 Å(50)
4.37 Å(40)
2.99 Å(40)
2.69 Å(40)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
High-𝑇 alteration and/or metamorphism
33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12])
Geological Setting:
Moderate temperature hydrothermal veins.

Type Occurrence of BournoniteHide

Synonyms of BournoniteHide

Other Language Names for BournoniteHide

Relationship of Bournonite to other SpeciesHide

Other Members of Bournonite Group:
CerromojoniteCuPbBiSe3Orth.
SeligmannitePbCuAsS3Orth. mmm(2/m2/m2/m) : Pmmn
SoučekiteCuPbBi(S,Se)3Orth. mm2
Forms a series with:

Common AssociatesHide

Associations Based on Photo Data:
979 photos of Bournonite associated with QuartzSiO2
734 photos of Bournonite associated with PyriteFeS2
553 photos of Bournonite associated with SphaleriteZnS
343 photos of Bournonite associated with ChalcopyriteCuFeS2
308 photos of Bournonite associated with SideriteFeCO3
298 photos of Bournonite associated with GalenaPbS
228 photos of Bournonite associated with