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Yvonite

A valid IMA mineral species
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About YvoniteHide

04073990017271929167480.jpg
Klaus Yvon
Formula:
Cu(HAsO4) · 2H2O
Colour:
Turquoise-blue
Lustre:
Vitreous
Hardness:
3½ - 4
Specific Gravity:
3.20
Crystal System:
Triclinic
Member of:
Name:
Named after Klaus Yvon (b. 1943), Professor of Crystallography at the University of Geneva, Switzerland.

Unique IdentifiersHide

Mindat ID:
7382
Long-form identifier:
mindat:1:1:7382:6

Similar NamesHide

FeniteA rock classification type
UvaniteA valid IMA mineral species - grandfathered - questionableU26+V65+O21 · 15H2O (?)
VeeniteA valid IMA mineral speciesPb16Sb9-xAs7+xS40, x ~ 0-0.5
VeniteA rock classification type

IMA Classification of YvoniteHide

Classification of YvoniteHide

8.CB.25

8 : PHOSPHATES, ARSENATES, VANADATES
C : Phosphates without additional anions, with H2O
B : With only medium-sized cations, RO4:H2O = 1:1

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
YvIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of YvoniteHide

Vitreous
Transparency:
Transparent
Colour:
Turquoise-blue
Streak:
Blue
Hardness:
3½ - 4 on Mohs scale
Tenacity:
Brittle
Cleavage:
Perfect
On {100}, perfect; on {010}, poor.
Fracture:
Irregular/Uneven
Density:
3.20(2) g/cm3 (Measured)    3.22 g/cm3 (Calculated)

Optical Data of YvoniteHide

Type:
Biaxial (-)
RI values:
nα = 1.615(2) nβ = 1.660(2) nγ = 1.700(2)
2V:
Measured: 82° (2), Calculated: 84°
Max. Birefringence:
δ = 0.085
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
r > v medium
Optical Extinction:
On (010): X ∧ c = 42°; Z ⊥ (010).
On (100): Z' ∧ [001] = 0-2.5°; X' ∧ c = 3-5.5°.
Pleochroism:
Weak
Comments:
X = light blue to colorless; Y = light blue; Z = blue.
Comments:
Absorption: Z > Y > X.

Chemistry of YvoniteHide

Mindat Formula:
Cu(HAsO4) · 2H2O
Element Weights:
Element% weight
O40.081 %
As31.282 %
Cu26.532 %
H2.104 %

Calculated from ideal end-member formula.
O
As
Cu
H

Crystallography of YvoniteHide

Crystal System:
Triclinic
Class (H-M):
1 - Pinacoidal
Space Group:
P1
Cell Parameters:
a = 7.632(3) Å, b = 11.168(3) Å, c = 6.020(3) Å
α = 89.32(3)°, β = 86.55(5)°, γ = 74.43(3)°
Ratio:
a:b:c = 0.683 : 1 : 0.539
Unit Cell V:
493.38 ų (Calculated from Unit Cell)
Z:
4
Morphology:
Elongated along [001], flattened on {010}, with prominent {100} and {010}. Small crystals also exhibit minor {hkl} and {001} forms.
Twinning:
Multiple laminae, with composition plane {010}, twin axis ⊥ {010}.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0001977YvoniteSarp H, Cerny R (1998) Description and crystal structure of yvonite, Cu(AsO3OH)2H2O American Mineralogist 83 383-38919980293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
7.35 Å(100)
5.239 Å(50)
4.40 Å(60)
3.936 Å(60)
3.302 Å(40)
3.008 Å(50)
2.840 Å(35)
Comments:
Salsigne mine, France. Data from type description.

Geological EnvironmentHide

Paragenetic Mode(s):

Type Occurrence of YvoniteHide

General Appearance of Type Material:
Aggregates or radiated spherule to 1 mm. Individual crystals of maximum size 0.3 x 0.15 x 0.06 mm.
Place of Conservation of Type Material:
Natural History Museum, Geneva University, Geneva, Switzerland, 450/33.
Geological Setting of Type Material:
Secondary mineral from mine dumps.
Associated Minerals at Type Locality:

Synonyms of YvoniteHide

Other Language Names for YvoniteHide

Dutch:Yvoniet
German:Yvonit
Russian:Ивонит
Spanish:Yvonita

Relationship of Yvonite to other SpeciesHide

Member of:
Other Members of Krautite Group:
KrautiteMn(HAsO4) · H2OMon. 2 : P21

Common AssociatesHide

Associations Based on Photo Data:
36 photos of Yvonite associated with GeminiteCu2+(AsO3OH) · H2O
29 photos of Yvonite associated with PushcharovskiteK0.6Cu18[AsO2(OH)2]4[AsO3OH]10(AsO4)(OH)9.6 · 18.6H2O
11 photos of Yvonite associated with Native BismuthBi
4 photos of Yvonite associated with ArsenopyriteFeAsS
1 photo of Yvonite associated with ArsenoliteAs2O3

Related Minerals - Strunz-mindat GroupingHide

8.CB.KrupičkaiteCu6[AsO3(OH)]6 · 8H2OMon. 2/m : P21/c
8.CB.XHonzaiteNi2(AsO3OH)2 · 5H2OMon. 2/m : P21/m
8.CB.XRedonditeAlPO4 · 2H2O
8.CB.05ErmeloiteAl(PO4) · H2OMon. 2/m : B2/b
8.CB.05SerrabrancaiteMnPO4 · H2OMon. 2/m : B2/b
8.CB.10NyholmiteCd3Zn2(AsO3OH)2(AsO4)2 · 4H2OMon. 2/m : B2/b
8.CB.10Villyaellenite(Mn,Ca)Mn2Ca2(AsO3OH)2(AsO4)2 · 4H2OMon. 2/m : B2/b
8.CB.10GiftgrubeiteCaMn2Ca2(AsO4)2(AsO3OH)2 · 4H2OMon. 2/m : B2/b
8.CB.10HureauliteMn2+5(PO3OH)2(PO4)2 · 4H2OMon. 2/m : B2/b
8.CB.10MiguelromeroiteMn2+5(AsO3OH)2(AsO4)2(H2O)4Mon. 2/m : B2/b
8.CB.10'UM1997-09-AsO:CaHMgZn'(Mg,Ca,Zn)5(AsO4)2(HAsO4)2 · 4H2OMon.
8.CB.15KrautiteMn(HAsO4) · H2OMon. 2 : P21
8.CB.20CobaltkoritnigiteCo(AsO3OH) · H2OTric. 1 : P1
8.CB.20MagnesiokoritnigiteMg(AsO3OH) · H2OTric. 1 : P1
8.CB.20KoritnigiteZn(AsO3OH) · H2OTric. 1 : P1
8.CB.30GeminiteCu2+(AsO3OH) · H2OTric. 1 : P1
8.CB.35SchubneliteFe3+VO4 · H2OTric. 1 : P1
8.CB.40RadovaniteCu2Fe3+(AsO4)(HAs3+O3)2 · H2OOrth. mmm(2/m2/m2/m) : Pnma
8.CB.45KazakhstaniteFe3+5V4+3V5+12O39(OH)9 · 9H2OMon.
8.CB.50KolovratiteNixZny(VO4)0.67(x+y) · nH2O
8.CB.60BurgessiteCo2(H2O)4[AsO3(OH)]2(H2O)Mon. 2/m : P21/c
8.CB.65CarditeZn5.5(AsO4)2(AsO3OH)(OH)3 · 3H2OOrth. mmm(2/m2/m2/m) : Cmcm

Fluorescence of YvoniteHide

Not fluorescent (LW or SW).

Other InformationHide

Notes:
Rapidly soluble in HCl.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for YvoniteHide

References for YvoniteHide

Localities for YvoniteHide

Showing 4 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Czech Republic
 
  • Karlovy Vary Region
    • Karlovy Vary District
M.E. Ciriotti - 04.06.2008 - Probed
France (TL)
 
  • Occitanie
    • Aude
      • Carcassonne
        • Salsigne
Sarp et al. (1998)
  • Provence-Alpes-Côte d'Azur
    • Var
      • Toulon
        • Le Pradet
Sarp et al. (1997) +2 other references
Namibia
 
  • Oshikoto Region
    • Tsumeb
von Bezing et al. (2016)
 
and/or  
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