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Berndtite

A valid IMA mineral species
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About BerndtiteHide

04188530017271921597373.jpg
Fritz Berndt
Formula:
SnS2
Colour:
Yellow-brown
Lustre:
Resinous
Hardness:
1 - 2
Specific Gravity:
4.5
Crystal System:
Trigonal
Member of:
Name:
For Dr. Fritz Berndt, born 14 November 1916, German Mineralogist at Corporation Minera de Bolivia, Oruro.
There are two polytypes, -2T and -4H.

Not isostructural with is chemical Ge analogue, radvaniceite (not a true analogy).


Unique IdentifiersHide

Mindat ID:
637
Long-form identifier:
mindat:1:1:637:4

Similar NamesHide

BrandtiteA valid IMA mineral species - grandfatheredCa2Mn2+(AsO4)2 · 2H2O

IMA Classification of BerndtiteHide

Classification of BerndtiteHide

2.EA.20

2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
E : Metal Sulfides, M: S <= 1:2
A : M:S = 1:2 - With Cu, Ag, Au
2.12.14.5

2 : SULFIDES
12 : AmBnXp, with (m+n):p = 1:2
3.6.3

3 : Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)
6 : Sulphides etc. of Sb and Pb

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
BtiIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of BerndtiteHide

Resinous
Transparency:
Transparent, Translucent
Colour:
Yellow-brown
Streak:
Golden yellow
Hardness:
1 - 2 on Mohs scale
Cleavage:
Distinct/Good
On {0001}
Density:
4.5 g/cm3 (Measured)    4.55 g/cm3 (Calculated)
Comment:
Measured on synthetic material

Optical Data of BerndtiteHide

Type:
Uniaxial (-)
RI values:
nω = 1.93 nε = 1.705
Max. Birefringence:
δ = 0.225
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized uniaxial interference figure - the conoscopic (convergent-light, Bertrand-lens-in) view, for a grain cut with the optic axis centred and vertical. The coloured rings are isochromatics, computed with the same physics as the Michel-Lévy bar above; the dark cross is the isogyre.

For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.
Anisotropism:
Dark greenish gray
Colour in reflected light:
Gray
Internal Reflections:
Intense brownish to orange-yellow
Pleochroism:
Strong

Chemistry of BerndtiteHide

Mindat Formula:
SnS2
Element Weights:
Element% weight
Sn64.926 %
S35.074 %

Calculated from ideal end-member formula.
Sn
S

Crystallography of BerndtiteHide

Crystal System:
Trigonal
Class (H-M):
3m(32/m) - Hexagonal Scalenohedral
Space Group:
P3m1
Setting:
P3m1
Cell Parameters:
a = 3.639 Å, c = 5.868 Å
Ratio:
a:c = 1 : 1.613
Unit Cell V:
67.30 ų (Calculated from Unit Cell)
Z:
1
Morphology:
Tabular hexagonal crystals.
Comment:
On C6 polymorph

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0000625BerndtiteHazen R M, Finger L W (1978) The crystal structures and compressibilities of layer minerals at high pressure. I. SnS2, berndtite American Mineralogist 63 289-29219780293
0011799BerndtiteWyckoff R W G (1963) Second edition. Interscience Publishers, New York, New York Crystal Structures 1 239-44419630293
0018172BerndtiteOftedal I (1926) Die Kristallstruktur von Sn S2 _cod_database_code 1011330 Norsk Geologisk Tidsskrift 9 225-23319260293
0000626BerndtiteHazen R M, Finger L W (1978) The crystal structures and compressibilities of layer minerals at high pressure. I. SnS2, berndtite American Mineralogist 63 289-29219781.2293
0000627BerndtiteHazen R M, Finger L W (1978) The crystal structures and compressibilities of layer minerals at high pressure. I. SnS2, berndtite American Mineralogist 63 289-29219783293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
5.89 Å(100)
2.784 Å(55)
3.162 Å(30)
1.824 Å(30)
2.155 Å(25)
1.743 Å(20)
1.669 Å(8)
Comments:
Synthetic

Type Occurrence of BerndtiteHide

General Appearance of Type Material:
Very fine inclusions in pyrite which has replaced stannite. Tabular habit .
Place of Conservation of Type Material:
National Museum of Natural History, Washington, D.C., USA, numbers 114486 and C5354A.
Geological Setting of Type Material:
Secondary mineral in a tin deposit.
Associated Minerals at Type Locality:

Other Language Names for BerndtiteHide

Dutch:Berndtiet
German:Berndtit
Spanish:Berndtita

Relationship of Berndtite to other SpeciesHide

Member of:
Other Members of Melonite Group:
KitkaiteNiTeSeTrig. 3m(32/m) : P3m1
MeloniteNiTe2Trig. 3m(32/m) : P3m1
MerenskyitePdTe2Trig. 3m : P3m1
MoncheitePt(Te,Bi)2Trig. 3m(32/m) : P3m1
ShuangfengiteIrTe2Trig. 3m : P3m1
SudovikovitePtSe2Trig. 3m(32/m) : P3m1

Common AssociatesHide

Associations Based on Photo Data:
1 photo of Berndtite associated with HerzenbergiteSnS
1 photo of Berndtite associated with OttemanniteSn2S3
1 photo of Berndtite associated with Tschermigite(NH4)Al(SO4)2 · 12H2O

Related Minerals - Strunz-mindat GroupingHide

2.EA.RadvaniceiteGeS2Mon. m : Pb
2.EA.ZavyaloviteAg2TeS3Mon. m : Bb
2.EA.05SylvaniteAgAuTe4Mon. 2/m : P2/b
2.EA.10CalaveriteAuTe2Mon.
2.EA.15KostoviteCuAuTe4Orth.
2.EA.15KrenneriteAu3AgTe8Orth. mm2 : Pma2
2.EA.20MeloniteNiTe2Trig. 3m(32/m) : P3m1
2.EA.20MerenskyitePdTe2Trig. 3m : P3m1
2.EA.20OgnititeNiBiTeTrig. 3m : P3m1
2.EA.20ShuangfengiteIrTe2Trig. 3m : P3m1
2.EA.20SudovikovitePtSe2Trig. 3m(32/m) : P3m1
2.EA.20KitkaiteNiTeSeTrig. 3m(32/m) : P3m1
2.EA.20MoncheitePt(Te,Bi)2Trig. 3m(32/m) : P3m1
2.EA.25VerbeekitePdSe2Mon.
2.EA.30DrysdalliteMoSe2Hex. 6/mmm(6/m2/m2/m) : P63/mmc
2.EA.30JordisiteMoS2Amor.
2.EA.30MolybdeniteMoS2Hex. 6/mmm(6/m2/m2/m) : P63/mmc
2.EA.30TungsteniteWS2Trig. 3m : R3m
2.EA.40PampaloiteAuSbTeMon. 2/m : B2/b

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for BerndtiteHide