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Zincochenite

A valid IMA mineral species
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About ZincocheniteHide

Formula:
Pb4Zn(SO4)2(OH)6
Colour:
light blue
Lustre:
Vitreous, Resinous
Hardness:
3½
Specific Gravity:
5.939 (Calculated)
Crystal System:
Triclinic
Name:
The name zincochenite is indicative of this mineral being the Zn analogue of chenite, Pb4Cu(OH)6(SO4)2.
Isostructural with:
The Zn analogue of chenite.


Unique IdentifiersHide

Mindat ID:
56156
Long-form identifier:
mindat:1:1:56156:1

IMA Classification of ZincocheniteHide

Approved
IMA Formula:
Pb2+4Zn2+(OH)6(S6+O4)2
Approval history:
IMA no. 2022-025

Classification of ZincocheniteHide

7.BC.

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
B : Sulfates (selenates, etc.) with additional anions, without H2O
C : With medium-sized and large cations

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
ZcheIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of ZincocheniteHide

Vitreous, Resinous
Colour:
Light blue
Streak:
White
Hardness:
3½ on Mohs scale
Tenacity:
Brittle
Cleavage:
Imperfect/Fair
fair on {011}
Fracture:
Irregular/Uneven
Comment:
also curved fracture
Density:
5.939 g/cm3 (Calculated)

Optical Data of ZincocheniteHide

Type:
Biaxial (-)
RI values:
nα = 1.875(5) nβ = 1.900(5) nγ = 1.915(5)
2V:
Measured: 78.4° (5)
Max. Birefringence:
δ = 0.040
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
strong r > v dispersion
Pleochroism:
Non-pleochroic

Chemistry of ZincocheniteHide

Mindat Formula:
Pb4Zn(SO4)2(OH)6
Element Weights:
Element% weight
Pb69.744 %
O18.849 %
Zn5.502 %
S5.397 %
H0.509 %

Calculated from ideal end-member formula.
Pb
O
Zn
S
H

Crystallography of ZincocheniteHide

Crystal System:
Triclinic
Class (H-M):
1 - Pinacoidal
Space Group:
P1
Cell Parameters:
a = 5.883(4) Å, b = 7.938(5) Å, c = 7.948(5) Å
α = 110.511(12)°, β = 98.497(10)°, γ = 100.152(8)°
Ratio:
a:b:c = 0.741 : 1 : 1.001
Unit Cell V:
333.24 ų (Calculated from Unit Cell)
Z:
1

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
5.64 Å(53)
4.29 Å(56)
3.602 Å(100)
3.423 Å(80)
2.848 Å(45)
2.801 Å(41)
2.744 Å(44)
2.600 Å(40)

Type Occurrence of ZincocheniteHide

General Appearance of Type Material:
vary in habit including tablets, blades, and prisms, up to about 0.5 mm in maximum dimension. Crystals always occur in tightly intergrown subparallel clusters.
Place of Conservation of Type Material:
mineralogical collections of the Natural History Museum of Los Angeles County, 900 Exposition Boulevard, Los Angeles, CA 90007, USA, catalogue numbers 76220, 76221 and 76222 (cotypes)
Geological Setting of Type Material:
highly unusual secondary assemblage that comprises a variety of rare Pb-Zn-Cu sulfates, thiosulfates, and carbonates.
Associated Minerals at Type Locality:

Other Language Names for ZincocheniteHide

Relationship of Zincochenite to other SpeciesHide

Other Members of Linarite-Chenite Group:
ChenitePb4Cu(SO4)2(OH)6Tric. 1 : P1
FranksousaitePbCu(Se6+O4)(OH)2Mon. 2/m : P21/m
LinaritePbCu(SO4)(OH)2Mon. 2/m : P21/m
MunakataitePb2Cu2(Se4+O3)(SO4)(OH)4Mon. 2/m : P21/m
SchmiederitePb2Cu2(Se6+O4)(Se4+O3)(OH)4Mon. 2/m : P21/m

Common AssociatesHide

Associations Based on Photo Data:
1 photo of Zincochenite associated with Sulfatoredmondite[Pb8O2Zn(OH)6](SO4)4 · 6H2O
1 photo of Zincochenite associated with LanarkitePb2(SO4)O
1 photo of Zincochenite associated with Cherokeeite[Pb2Zn(OH)4](SO4) · H2O
1 photo of Zincochenite associated with ElyitePb4Cu(SO4)O2(OH)4 · H2O
1 photo of Zincochenite associated with QuartzSiO2
1 photo of Zincochenite associated with GalenaPbS

Related Minerals - Strunz-mindat GroupingHide

7.BC.ViskontitePb5Cu2(SO4)3(SeO3)(OH)6Orth. mm2 : Pmn21
7.BC.D'Ansite-(Mn)Na21Mn2+(SO4)10Cl3Iso. 43m : I43d
7.BC.D'Ansite-(Fe)Na21Fe2+(SO4)10Cl3Iso. 43m : I43d
7.BC.Acmonidesite(NH4,K,Pb)8NaFe2+4(SO4)5Cl8Orth. 222 : C2221
7.BC.Adranosite(NH4)4NaAl2(SO4)4Cl(OH)2Tet. 4/mmm(4/m2/m2/m) : I41/acd
7.BC.ChromviskontitePb5Cu2(CrO4)3(SeO3)(OH)6Orth. mm2 : Pmn21
7.BC.BackitePb2AlTeO6ClTrig. 32 : P312
7.BC.Adranosite-(Fe)(NH4)4NaFe3+2(SO4)4Cl(OH)2Tet. 4/mmm(4/m2/m2/m) : I41/acd
7.BC.AgaitePb3CuTeO5(OH)2(CO3) Orth. mm2 : Pca21
7.BC.WildcatiteCaFe3+Te6+O5(OH)Trig. 3m(32/m) : P31m
7.BC.HagstromitePb8Cu2+(Te6+O6)2(CO3)Cl4Orth. mmm(2/m2/m2/m) : Ibam
7.BC.05D'AnsiteNa21Mg(SO4)10Cl3Iso. 43m : I43m
7.BC.07'Apatelite'Fe3(SO4)2(OH)5 · 0.5H2O
7.BC.07'Unnamed (Ba-Fe Vanadate)'Ba, Fe, V, O, H
7.BC.10JarositeKFe3+3(SO4)2(OH)6Trig. 3m(32/m) : R3m
7.BC.10DorallchariteTlFe3+3(SO4)2(OH)6Trig. 3m(32/m) : R3m
7.BC.10ArgentojarositeAgFe3+3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10NatroaluniteNaAl3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10NatrojarositeNaFe3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10Beaverite-(Cu)Pb(Fe3+2Cu)(SO4)2(OH)6Trig. 3m(32/m) : R3m
7.BC.10Beaverite-(Zn)Pb(Fe3+2Zn)(SO4)2(OH)6Trig. 3m(32/m) : R3m
7.BC.10WalthieriteBa0.5Al3(SO4)2(OH)6Trig.
7.BC.10HuangiteCa0.5Al3(SO4)2(OH)6Trig. 3m(32/m) : R3m
7.BC.10'Natroalunite-2c'(Na,Ca0.5,K)Al3(SO4)2(OH)6Trig. 3m(32/m) : R3m
7.BC.10AluniteKAl3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10PlumbojarositePb0.5Fe3+3(SO4)2(OH)6Trig. 3m(32/m) : R3m
7.BC.10Karlseifertite Pb(Ga2Ge)(AsO4)2(OH)6Trig. 3m(32/m) : R3m
7.BC.10Hydroniumjarosite(H3O)Fe3+3(SO4)2(OH)6Trig. 3m(32/m) : R3m
7.BC.10Ammonioalunite(NH4)Al3(SO4)2(OH)6Trig.
7.BC.10Ammoniojarosite(NH4)Fe3+3(SO4)2(OH)6Trig. 3m : R3m
7.BC.10OsarizawaitePb(Al2Cu2+)(SO4)2(OH)6Trig. 3m(32/m) : R3m
7.BC.10Schlossmacherite(H3O)Al3(SO4)2(OH)6Trig. 3m(32/m) : R3m
7.BC.15Ye'elimiteCa4Al6(SO4)O12Iso. 432 : I4132
7.BC.20NabokoiteKCu7(SO4)5(Te4+O3)OClTet. 4/mmm(4/m2/m2/m) : P4/ncc
7.BC.20PuniniteNa2Cu3O(SO4)3Mon. 2/m : B2/b
7.BC.20AtlasoviteK(BiO)Cu6Fe3+(SO4)5O3ClTet. 4/mmm(4/m2/m2/m) : P4/ncc
7.BC.25ChlorothioniteK2Cu(SO4)Cl2Orth. mmm(2/m2/m2/m) : Pnma
7.BC.30EuchlorineKNaCu3(SO4)3OMon. 2/m
7.BC.30FedotoviteK2Cu3(SO4)3OMon. 2/m : B2/b
7.BC.35KamchatkiteKCu3(SO4)2OClOrth. mmm(2/m2/m2/m) : Pnma
7.BC.40PiypiteK4Cu4O2(SO4)4 · (Na,Cu)ClTet. 4 : I4
7.BC.45AlumoklyuchevskiteK3Cu3(Al,Fe3+)(SO4)4O2Tric. 1 : P1
7.BC.45BelousoviteKZn(SO4)ClMon. 2/m : P21/c
7.BC.45KlyuchevskiteK3Cu3(Fe3+,Al)(SO4)4O2Mon. 2
7.BC.47MülleritePb2Fe3+(Te6+O6)ClTrig. 32 : P3112
7.BC.50CaledonitePb5Cu2(SO4)3(CO3)(OH)6Orth. mm2 : Pmn21
7.BC.50ElasmochloiteNa3Cu6BiO4(SO4)5Mon. 2/m
7.BC.52Eleomelanite(K2Pb)Cu4O2(SO4)4Mon. 2/m : P21/c
7.BC.55FalgariteK4(VO)3(SO4)5Mon. 2/m : B2/b
7.BC.55WherryitePb7Cu2(SO4)4(SiO4)2(OH)2Mon. 2/m : B2/m
7.BC.57KrasheninnikoviteKNa2CaMg(SO4)3FHex. 6/mmm(6/m2/m2/m) : P63/mcm
7.BC.60WulffiteK3NaCu4O2(SO4)4Orth. mm2
7.BC.60ParawulffiteK5Na3Cu8O4(SO4)8Mon. 2/m : P2/b
7.BC.60MammothitePb6Cu4AlSb5+O2(OH)16Cl4(SO4)2Mon. 2 : B2
7.BC.62ShuvaloviteK2(Ca2Na)(SO4)3FOrth. mmm(2/m2/m2/m) : Pnma
7.BC.65SaccoiteCa2Mn3+2F(OH)8 · 0.5(SO4)Tet. 4/mmm(4/m2/m2/m) : P4/ncc
7.BC.65LinaritePbCu(SO4)(OH)2Mon. 2/m : P21/m
7.BC.65Therasiaite(NH4)3KNa2Fe2+Fe3+(SO4)3Cl5Mon. m : Bb
7.BC.65FranksousaitePbCu(Se6+O4)(OH)2Mon. 2/m : P21/m
7.BC.65MunakataitePb2Cu2(Se4+O3)(SO4)(OH)4Mon. 2/m : P21/m
7.BC.65SchmiederitePb2Cu2(Se6+O4)(Se4+O3)(OH)4Mon. 2/m : P21/m
7.BC.70ChenitePb4Cu(SO4)2(OH)6Tric. 1 : P1
7.BC.75KrivovichevitePb3Al(OH)6(SO4)(OH)Trig. 3m : R3c
7.BC.80AnhydrokainiteKMg(SO4)Cl

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for ZincocheniteHide

References for ZincocheniteHide

Localities for ZincocheniteHide

Showing 1 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
USA (TL)
 
  • North Carolina
    • Haywood County
      • Waterville Lake
Miyawaki et al. (2022)
 
and/or  
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