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Gurzhiite

A valid IMA mineral species
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About GurzhiiteHide

Formula:
Al(UO2)(SO4)2F · 10H2O
Colour:
Pale yellow (crystals) to lemon yellow (aggregates)
Lustre:
Vitreous
Hardness:
2
Specific Gravity:
2.52
Crystal System:
Triclinic
Name:
Honors Russian mineralogist and crystallographer, Dr. Vladislav V. Gurzhiy (Владислав Васильевич Гуржий), due to his contributions to uranium mineralogy and crystallography.
A lower hydrate counterpart of strassmannite, being structurally different from it.

Crystal structure details:

* based on uranyl-sulfate chains, topologically resembling these in bobcookite or svornostite group;
* intra-chain Al-octahedra are: Al1(H2O)6 and Al2F2(H2O)4;
* a complex network of H-bonds.


Unique IdentifiersHide

Mindat ID:
55758
Long-form identifier:
mindat:1:1:55758:6

IMA Classification of GurzhiiteHide

Approved
IMA Formula:
Al(U6+O2)(S6+O4)2F·10H2O
Approval year:
2021
First published:
2022

Classification of GurzhiiteHide

7.EB.

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
E : Uranyl sulfates
B : With medium-sized cations

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
GrzIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of GurzhiiteHide

Vitreous
Transparency:
Transparent
Colour:
Pale yellow (crystals) to lemon yellow (aggregates)
Streak:
White
Hardness:
Comment:
ca.
Tenacity:
Brittle
Cleavage:
Distinct/Good
on {001}
Fracture:
Irregular/Uneven
Density:
2.52(3) g/cm3 (Measured)    2.605 g/cm3 (Calculated)

Optical Data of GurzhiiteHide

Type:
Biaxial (-)
RI values:
nα = 1.528(3) nβ = 1.538(2) nγ = 1.544(3)
2V:
Measured: 80° (10), Calculated: 75.1°
Max. Birefringence:
δ = 0.016
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
None to Very Low
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.

Chemistry of GurzhiiteHide

Mindat Formula:
Al(UO2)(SO4)2F · 10H2O
Element Weights:
Element% weight
O46.491 %
U34.583 %
S9.317 %
Al3.920 %
H2.929 %
F2.760 %

Calculated from ideal end-member formula.
O
U
S
Al
H
F

Crystallography of GurzhiiteHide

Crystal System:
Triclinic
Class (H-M):
1 - Pinacoidal
Space Group:
P1
Cell Parameters:
a = 7.193(2) Å, b = 11.760(2) Å, c = 11.792(2) Å
α = 67.20(3)°, β = 107.76(3)°, γ = 89.99(3)°
Ratio:
a:b:c = 0.612 : 1 : 1.003
Unit Cell V:
867.72 ų (Calculated from Unit Cell)

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
10.24 Å(100)
6.76 Å(10)
5.40 Å(14)
5.11 Å(54)
3.618 Å(8)
3.405 Å(11)
3.348 Å(7)
3.065 Å(11)

Type Occurrence of GurzhiiteHide

General Appearance of Type Material:
Fine-grained aggregates, comprising bladed crystals up to 0.1 mm across, forming veinlets up to 50 cm long, in cracks of a brecciated rock.
Place of Conservation of Type Material:
Collections of the Fersman Mineralogical Museum, Russian Academy of Sciences, Leninskiy Prospekt 18–2, Moscow 119071, Russia, registration number 5756/1.
Geological Setting of Type Material:
Uranium deposit.
Associated Minerals at Type Locality:

Synonyms of GurzhiiteHide

Other Language Names for GurzhiiteHide

Dutch:Gurzhiiet
German:Gurzhiit

Related Minerals - Strunz-mindat GroupingHide

7.EB.BobcookiteNaAl(UO2)2(SO4)4 · 18H2OTric. 1 : P1
7.EB.ZincorietvelditeZn(UO2)(SO4)2(H2O)5Orth. mm2 : Pmn21
7.EB.ChenowethiteMg(H2O)6[(UO2)2(SO4)2(OH)2] · 5H2OOrth. mmm(2/m2/m2/m) : Cmcm
7.EB.IShinarumpite[Co(H2O)6][(UO2)(SO4)2(H2O)] · 4H2OMon. 2/m : P21/c
7.EB.Alwilkinsite-(Y)Y(UO2)3(SO4)2O(OH)3(H2O)7 · 7H2OOrth. 222 : P212121
7.EB.05JohanniteCu(UO2)2(SO4)2(OH)2 · 8H2OTric. 1 : P1
7.EB.05Meitnerite(NH4)(UO2)(SO4)(OH) · 2H2OTric. 1 : P1
7.EB.10RietvelditeFe(UO2)(SO4)2(H2O)5Orth. mm2 : Pmn21
7.EB.10DeliensiteFe[(UO2)2(SO4)2(OH)2](H2O)7Orth. mm2 : Pnn2
7.EB.15StrassmanniteAl(UO2)(SO4)2F · 16H2OMon. 2/m : B2/b
7.EB.15LeydetiteFe(UO2)(SO4)2 · 11H2OMon. 2/m : B2/b
7.EB.15MagnesioleydetiteMg(UO2)(SO4)2 · 11H2OMon. 2/m : B2/b
7.EB.20Greenlizardite(NH4)Na(UO2)2(SO4)2(OH)2 · 4H2OTric. 1 : P1
7.EB.25MarkcooperitePb2(UO2)(TeO6)Mon. 2/m : P21/c

RadioactivityHide

Radioactivity:
Element % Content Activity (Bq/kg) Radiation Type
Uranium (U) 34.5829% 8,645,725 α, β, γ
Thorium (Th) 0.0000% 0 α, β, γ
Potassium (K) 0.0000% 0 β, γ

For comparison:

  • Banana: ~15 Bq per fruit
  • Granite: 1,000–3,000 Bq/kg
  • EU exemption limit: 10,000 Bq/kg

Note: Risk is shown relative to daily recommended maximum exposure to non-background radiation of 1000 µSv/year. Note that natural background radiation averages around 2400 µSv/year so in reality these risks are probably extremely overstated! With infrequent handling and safe storage natural radioactive minerals do not usually pose much risk.

Interactive Simulator:

Note: The mass selector refers to the mass of radioactive mineral present, not the full specimen, also be aware that the matrix may also be radioactive, possibly more radioactive than this mineral!

Activity: –

DistanceDose rateRisk
1 cm
10 cm
1 m

The external dose rate (D) from a radioactive mineral is estimated by summing the gamma radiation contributions from its Uranium, Thorium, and Potassium content, disregarding daughter-product which may have a significant effect in some cases (eg 'pitchblende'). This involves multiplying the activity (A, in Bq) of each element by its specific gamma ray constant (Γ), which accounts for its unique gamma emissions. The total unshielded dose at 1 cm is then scaled by the square of the distance (r, in cm) and multiplied by a shielding factor (μshield). This calculation provides a 'worst-case' or 'maximum risk' estimate because it assumes the sample is a point source and entirely neglects any self-shielding where radiation is absorbed within the mineral itself, meaning actual doses will typically be lower. The resulting dose rate (D) is expressed in microsieverts per hour (μSv/h).

D = ((AU × ΓU) + (ATh × ΓTh) + (AK × ΓK)) / r2 × μshield

Fluorescence of GurzhiiteHide

Bright yellow-green (both SWUV and LWUV).

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for GurzhiiteHide

References for GurzhiiteHide

Localities for GurzhiiteHide

Showing 1 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Russia (TL)
 
  • Stavropol Krai
    • Predgorny District
      • Byk Mountain
Miyawaki et al. (2022) +1 other reference
 
and/or  
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