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Ferrierite-NH4

A valid IMA mineral species
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About Ferrierite-NH4Hide

03331850017271923163465.jpg
Walter F. Ferrier
Formula:
(NH4,Mg0.5)5(Al5Si31O72) · 22H2O
Colour:
White
Lustre:
Silky
Specific Gravity:
2.154 (Calculated)
Crystal System:
Orthorhombic
Name:
Ammonium dominant member of ferrierite group.
Zeolite supergroup. First (or second - after ammonioleucite) natural ammonium-dominant zeolite.


Name EncodingHide

Formatted:
ferrierite-NH4
HTML:
ferrierite-NH<sub>4</sub>
LaTeX:
ferrierite-NH\$\_4\$

Unique IdentifiersHide

Mindat ID:
52850
Long-form identifier:
mindat:1:1:52850:2

Similar NamesHide

Ferrierite-NaA valid IMA mineral species(Na,K)5(Si31Al5)O72 · 18H2O

IMA Classification of Ferrierite-NH4Hide

Classification of Ferrierite-NH4Hide

9.GD.50

9 : SILICATES (Germanates)
G : Tektosilicates with zeolitic H2O; zeolite family
D : Chains of 6-membered rings – tabular zeolites

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
Frr-NH4IMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of Ferrierite-NH4Hide

Silky
Transparency:
Transparent
Colour:
White
Streak:
White
Cleavage:
None Observed
Density:
2.154 g/cm3 (Calculated)

Optical Data of Ferrierite-NH4Hide

Type:
Biaxial (+)
RI values:
nα = 1.518(2) nβ = 1.520(2) nγ = 1.522(2)
Max. Birefringence:
δ = 0.004
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 ”m thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Low (negative)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.

No measured or calculated 2V is on file for this mineral, so the value used here (90°) is estimated from its recorded refractive indices and optic sign, not from a direct 2V measurement.
Optical Extinction:
Z = c.
Pleochroism:
Non-pleochroic

Chemistry of Ferrierite-NH4Hide

Mindat Formula:
(NH4,Mg0.5)5(Al5Si31O72) · 22H2O
Element Weights:
Element% weight
O56.880 %
Si32.929 %
Al5.102 %
N2.649 %
H2.440 %

Calculated from ideal end-member formula.
O
Si
Al
N
H

Crystallography of Ferrierite-NH4Hide

Crystal System:
Orthorhombic
Class (H-M):
mmm(2/m2/m2/m) - Dipyramidal
Space Group:
Immm
Setting:
Immm
Cell Parameters:
a = 19.10(1) Å, b = 14.15(1) Å, c = 7.489(3) Å
Ratio:
a:b:c = 1.35 : 1 : 0.529
Unit Cell V:
2,024.01 ų (Calculated from Unit Cell)
Z:
1
Morphology:
Very thin flattened prismatic crystals elongated along (001).

X-Ray Powder DiffractionHide

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 10a: Neoproterozoic oxygenation/terrestrial biosphere<0.6
49 : Oxic cellular biomineralization (see also #44)<0.54
50 : Coal and/or oil shale minerals<0.36
53 : Other minerals with taphonomic origins<0.4

Type Occurrence of Ferrierite-NH4Hide

General Appearance of Type Material:
Radiating aggregates up to 2 mm across consisting of thin flattened prismatic crystals.
Place of Conservation of Type Material:
Type material is deposited in the collections of the Fersman Mineralogical Museum, Russian Academy of Sciences, Moscow, Russia, registration number 5120/1.
Geological Setting of Type Material:
Coal deposit.
Associated Minerals at Type Locality:

Synonyms of Ferrierite-NH4Hide

Other Language Names for Ferrierite-NH4Hide

Relationship of Ferrierite-NH4 to other SpeciesHide

Other Members of Ferrierite Subgroup:
Ferrierite-K(K,Na)5(Si31Al5)O72 · 18H2OOrth. mmm(2/m2/m2/m) : Immm
Ferrierite-Mg[Mg2(K,Na)2Ca0.5](Si29Al7)O72 · 18H2OOrth. mmm(2/m2/m2/m) : Pnnm
Ferrierite-Na(Na,K)5(Si31Al5)O72 · 18H2OMon. 2/m : P21/c

Common AssociatesHide

Associations Based on Photo Data:
1 photo of Ferrierite-NH4 associated with SideriteFeCO3
1 photo of Ferrierite-NH4 associated with MarcasiteFeS2

Related Minerals - Strunz-mindat GroupingHide

9.GD.05Gmelinite-CaCa2(Si8Al4)O24 · 11H2OHex. 6/mmm(6/m2/m2/m) : P63/mmc
9.GD.05