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Ferrovorontsovite
A valid IMA mineral species
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Formula:
(Fe5Cu)Σ6TlAs4S12
Colour:
Black
Lustre:
Metallic
Hardness:
3½
Specific Gravity:
4.744 (Calculated)
Crystal System:
Isometric
Member of:
Name:
For being the iron analogue of vorontsovite. The root name is for the type locality, but also honors the mining engineer Vladimir Vasilyevich Vorontsov (1842 – after 1908), superintendent of the Bogoslovskiy mining district.
Type Locality:
Isostructural with:
The Fe analogue of voronstovite and Fe-Tl analogue of galkhaite. Chemically similar to ferrostalderite.
Unique Identifiers
Mindat ID:
51817
Long-form identifier:
mindat:1:1:51817:0
IMA Classification of Ferrovorontsovite
Approved
IMA Formula:
(Fe2+5Cu1+)Tl1+As3+4S2-12
Approval year:
2017
First published:
2018
Type description reference:
Kasatkin, Anatoly, Nestola, Fabrizio, Agakhanov, Atali, Škoda, Radek, Karpenko, Vladimir, Tsyganko, Mikhail, Plášil, Jakub (2018) Vorontsovite, (Hg5Cu)Σ6TlAs4S12, and Ferrovorontsovite, (Fe5Cu)Σ6TlAs4S12: The Tl- and Tl-Fe-Analogues of Galkhaite from the Vorontsovskoe Gold Deposit, Northern Urals, Russia. Minerals, 8 (5) 185 doi:10.3390/min8050185
Classification of Ferrovorontsovite
2.GB.20
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
G : Sulfarsenites, sulfantimonites, sulfbismuthites
B : Neso-sulfarsenites, etc. with additional S
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
G : Sulfarsenites, sulfantimonites, sulfbismuthites
B : Neso-sulfarsenites, etc. with additional S
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Fvor | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Ferrovorontsovite
Metallic
Transparency:
Opaque
Colour:
Black
Streak:
Black
Hardness:
3½ on Mohs scale
Hardness:
VHN10=166 - 174 kg/mm2 - Vickers
Tenacity:
Brittle
Cleavage:
None Observed
Parting:
None observed
Fracture:
Irregular/Uneven
Density:
4.744 g/cm3 (Calculated)
Optical Data of Ferrovorontsovite
Bireflectance:
None observed
Reflectivity:
| Wavelength | R1 (%) |
|---|---|
| 400nm | 24.90% |
| 420nm | 25.02% |
| 440nm | 25.21% |
| 460nm | 25.43% |
| 470nm | 25.54% |
| 480nm | 25.64% |
| 500nm | 25.87% |
| 520nm | 26.11% |
| 540nm | 26.41% |
| 546nm | 26.49% |
| 560nm | 26.71% |
| 580nm | 27.06% |
| 589nm | 27.26% |
| 600nm | 27.47% |
| 620nm | 27.52% |
| 640nm | 27.83% |
| 650nm | 27.90% |
| 660nm | 27.98% |
| 680nm | 28.39% |
| 700nm | 28.83% |
Graph shows reflectance levels at different wavelengths (in nm). Peak reflectance is 28.83%.
Colour in reflected light:
Light gray
Internal Reflections:
None observed
Pleochroism:
Non-pleochroic
Chemistry of Ferrovorontsovite
Mindat Formula:
(Fe5Cu)Σ6TlAs4S12
Crystallography of Ferrovorontsovite
Crystal System:
Isometric
Class (H-M):
43m - Hextetrahedral
Space Group:
I43m
Cell Parameters:
a = 10.2390(7) Å
Unit Cell V:
1,073.43 ų (Calculated from Unit Cell)
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 4.175 Å | (93) |
| 3.646 Å | (13) |
| 2.952 Å | (100) |
| 2.735 Å | (57) |
| 2.562 Å | (18) |
| 1.869 Å | (11) |
| 1.810 Å | (40) |
| 1.543 Å | (24) |
Reference:
Kasatkin, Anatoly, Nestola, Fabrizio, Agakhanov, Atali, Škoda, Radek, Karpenko, Vladimir, Tsyganko, Mikhail, Plášil, Jakub (2018) Vorontsovite, (Hg5Cu)Σ6TlAs4S12, and Ferrovorontsovite, (Fe5Cu)Σ6TlAs4S12: The Tl- and Tl-Fe-Analogues of Galkhaite from the Vorontsovskoe Gold Deposit, Northern Urals, Russia. Minerals, 8 (5) 185 doi:10.3390/min8050185
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| High-? alteration and/or metamorphism | |
| 33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12]) |
Type Occurrence of Ferrovorontsovite
General Appearance of Type Material:
Black anhedral grains to 0.2 mm in dolomite-calcite matrix.
Place of Conservation of Type Material:
Type material is deposited in the collections of the Fersman Mineralogical Museum, Russian Academy of Sciences, Moscow, Russia, registration number 4976/1.
Reference:
Kasatkin, Anatoly, Nestola, Fabrizio, Agakhanov, Atali, Škoda, Radek, Karpenko, Vladimir, Tsyganko, Mikhail, Plášil, Jakub (2018) Vorontsovite, (Hg5Cu)Σ6TlAs4S12, and Ferrovorontsovite, (Fe5Cu)Σ6TlAs4S12: The Tl- and Tl-Fe-Analogues of Galkhaite from the Vorontsovskoe Gold Deposit, Northern Urals, Russia. Minerals, 8 (5) 185 doi:10.3390/min8050185
Synonyms of Ferrovorontsovite
Other Language Names for Ferrovorontsovite
Dutch:Ferrovorontsoviet
German:Ferrovorontsovit
Relationship of Ferrovorontsovite to other Species
Member of:
Other Members of Galkhaite Group:
| Galkhaite | (Hg5Cu)CsAs4S12 | Iso. 43m : I43m |
| Vorontsovite | (Hg5Cu)Σ6TlAs4S12 | Iso. 43m : I43m |
Related Minerals - Strunz-mindat Grouping
| 2.GB. | 'Polybasite-Tac' | [Ag6Sb2S7][Ag9CuS4] |
| 2.GB. | Kenoargentotetrahedrite-(Zn) | [Ag6]4+(Cu4Zn2)Sb4S12◻ |
| 2.GB. | Argentotetrahedrite-(Hg) | Ag6(Cu4Hg2)Sb4S12S |
| 2.GB. | Annivite-(Zn) | Cu6(Cu4Zn2)Bi4S12S |
| 2.GB. | Pošepnýite | (Cu+3◻3)(Hg2+4Cu+2)Sb4Se12(Se0.5◻0.5) |
| 2.GB. | Tennantite-(Cu) | Cu6(Cu4Cu2)As4S12S |
| 2.GB. | Argentopolybasite | [Ag6Sb2S7][Ag9AgS4] |
| 2.GB. | Tennantite-(Mn) | Cu6(Cu4Mn2)As4S12S |
| 2.GB. | Argentotetrahedrite-(Cd) | Ag6(Cu4Cd2)Sb4S12S |
| 2.GB. | Stibioústalečite | (Cu4Cu2)(Cu4Cu+2)(Sb2Te2)Se12Se |
| 2.GB. | Stibiogoldfieldite | (Cu4Cu2)(Cu4Cu+2)(Sb2Te2)S12S |
| 2.GB. | Argentotetrahedrite-(Zn) | Ag6(Cu4Zn2)Sb4S12S |
| 2.GB. | Tetrahedrite-(Cd) | Cu6(Cu4Cd2)Sb4S12S |
| 2.GB. | Arsenogoldfieldite | (Cu4Cu2)(Cu4Cu+2)(As2Te2)S12S |
| 2.GB. | Arsenoústalečite | (Cu4Cu2)(Cu4Cu+2)(As2Te2)Se12Se |
| 2.GB. | Tennantite-(In) | Cu6(Cu5In)As4S13 |
| 2.GB. | Zvěstovite-(Fe) | Ag6(Ag4Fe2+2)As4S12S |
| 2.GB. | Hakite-(Fe) | Cu6(Cu4Fe2+2)Sb4Se12Se |
| 2.GB. | Tennantite-(Cd) | Cu6(Cu4Cd2)As4S12S |
| 2.GB.X | Kenorozhdestvenskayaite-(Fe) | [Ag6]4+(Ag4Fe2+2)Sb4S12◻ |
| 2.GB. | Tetrahedrite-(Cu) | Cu6(Cu4Cu2+2)Sb4S12S |
| 2.GB. | Hakite-(Zn) | Cu6(Cu4Zn2)Sb4Se12Se |
| 2.GB. | Zvěstovite-(Zn) | Ag6(Ag4Zn2)As4S12S |
| 2.GB. | Hakite-(Cd) | Cu6(Cu4Cd2)Sb4Se12Se |
| 2.GB. | Kenoargentotennantite-(Fe) | [Ag6]4+(Cu4Fe2)As4S12◻ |
| 2.GB. | Tennantite-(Hg) | Cu6(Cu4Hg2)As4S12S |
| 2.GB. | Tetrahedrite-(Mn) | Cu6(Cu4Mn2)Sb4S12S |
| 2.GB. | Tennantite-(Ni) | Cu6(Cu4Ni2)As4S12S |
| 2.GB. | Tetrahedrite-(Ni) | Cu6(Cu4Ni2)Sb4S12S |
| 2.GB.05 | Hakite-(Hg) | Cu6(Cu4Hg2)Sb4Se12Se |
| 2.GB.05 | Rozhdestvenskayaite-(Zn) | Ag6(Ag4Zn2)Sb4S12S |
| 2.GB.05 | Argentotennantite-(Zn) | Ag6(Cu4Zn2)As4S12S |
| 2.GB.05 | Argentotennantite-(Fe) | Ag6(Cu4Fe2)As4S12S |
| 2.GB.05 | Freibergite Subgroup | (Ag6,[Ag6]4+)(Cu4 C2+2)Sb4S12S0-1 |
| 2.GB.05 | Tennantite Subgroup | Cu6(Cu4C2+2)As4S12S |
| 2.GB.05 | Tennantite-(Zn) | Cu6(Cu4Zn2)As4S12S |
| 2.GB.05 | Tetrahedrite-(Zn) | Cu6(Cu4Zn2)Sb4S12S |
| 2.GB.05 | Tetrahedrite Subgroup | Cu6(Cu4C2+2)Sb4S12S |
| 2.GB.05 | Tennantite-(Fe) | Cu6(Cu4Fe2+2)As4S12S |
| 2.GB.05 | Tetrahedrite-(Fe) | Cu6(Cu4Fe2+2)Sb4S12S |
| 2.GB.05 | Tetrahedrite-(Hg) | Cu6(Cu4Hg2)Sb4S12S |
| 2.GB.05 | Kenoargentotetrahedrite-(Fe) | [Ag6]4+(Cu4Fe2+2)Sb4S12◻ |
| 2.GB.05 | Giraudite-(Zn) | Cu6(Cu4Zn2)As4Se12Se |
| 2.GB.05 | Argentotetrahedrite-(Fe) | Ag6(Cu4Fe2)Sb4S12S |
| 2.GB.05 | Goldfieldite | (Cu4◻2)(Cu4Cu+2)Te4S12S |
| 2.GB.05 | 'UM1992-21-S:AgFeSb' | Ag6(Ag4Fe2+2)Sb4S12S |
| 2.GB.10 | Selenostephanite | Ag5SbSe4 |
| 2.GB.10 | Stephanite | Ag5SbS4 |
| 2.GB.15 | 'UM2003-14-S:AgBiFeTe' | Ag16FeBiTe3S8 |
| 2.GB.15 | 'UM1979-17-S:BiCuFe' | ~Cu18Fe4BiS16 |
| 2.GB.15 | Pearceite | [Ag6As2S7][Ag9CuS4] |
| 2.GB.15 | Argentopearceite | Ag16As2S11 |
| 2.GB.15 |