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Libbyite

A valid IMA mineral species
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About LibbyiteHide

03680270017271954051639.jpg
Willard Frank Libby (December 17, 1908 – September 8, 1980)
Formula:
(NH4)2(Na2◻)[(UO2)2(SO4)3(H2O)]2 · 7H2O
Colour:
light green
Lustre:
Vitreous
Hardness:
2½
Specific Gravity:
3.465 (Calculated)
Crystal System:
Tetragonal
Name:
Libbyite is named in honour of American nuclear chemist Willard F. Libby (December 17, 1908 – September 8, 1980) for his work on nuclear and radiochemistry. Dr. Libby developed the method of radiocarbon dating (published in 1952) for which he was awarded the Nobel Prize in Chemistry for 1960.
This page provides mineralogical data about Libbyite.


Unique IdentifiersHide

Mindat ID:
470492
Long-form identifier:
mindat:1:1:470492:4

Similar NamesHide

IMA Classification of LibbyiteHide

Approved
IMA Formula:
(N3-H4)2(Na2◻)[(U6+O2)2(S6+O4)3(H2O)]2·7H2O
Approval year:
2022

Classification of LibbyiteHide

7.EC.

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
E : Uranyl sulfates
C : With medium-sized and large cations

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
LyIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of LibbyiteHide

Vitreous
Transparency:
Transparent
Colour:
Light green
Streak:
Very pale green yellow
Hardness:
2½ on Mohs scale
Tenacity:
Brittle
Cleavage:
Very Good
excellent on {001}
Fracture:
Sub-Conchoidal
Density:
3.465 g/cm3 (Calculated)

Optical Data of LibbyiteHide

Type:
Uniaxial (-)
RI values:
nω = 1.581(2) nε = 1.540(2)
Max. Birefringence:
δ = 0.041
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Moderate (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized uniaxial interference figure - the conoscopic (convergent-light, Bertrand-lens-in) view, for a grain cut with the optic axis centred and vertical. The coloured rings are isochromatics, computed with the same physics as the Michel-Lévy bar above; the dark cross is the isogyre.

For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.
Pleochroism:
Visible
Comments:
The pleochroism is O yellow, E pale yellow; O > E.

Chemistry of LibbyiteHide

Mindat Formula:
(NH4)2(Na2◻)[(UO2)2(SO4)3(H2O)]2 · 7H2O
Element Weights:
Element% weight
U50.093 %
O34.513 %
S10.122 %
Na2.419 %