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Chukhrovite-(Ca)

A valid IMA mineral species

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Chukhrovite-(Ca)

Valvassera mine, Valganna, Varese Province, Lombardy, Italy

Chukhrovite-(Ca)

Valvassera mine, Valganna, Varese Province, Lombardy, Italy

Chukhrovite-(Ca)

Valvassera mine, Valganna, Varese Province, Lombardy, Italy

Chukhrovite-(Ca)

Valvassera mine, Valganna, Varese Province, Lombardy, Italy

Chukhrovite-(Ca)

Valvassera mine, Valganna, Varese Province, Lombardy, Italy

Chukhrovite-(Ca)

Valvassera mine, Valganna, Varese Province, Lombardy, Italy

Chukhrovite-(Ca)

Valvassera mine, Valganna, Varese Province, Lombardy, Italy

Chukhrovite-(Ca)

Valvassera mine, Valganna, Varese Province, Lombardy, Italy

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About Chukhrovite-(Ca)Hide

Russian mineralogist and geochemist Fedor Vasil’evich Chukhrov.

Formula:

Ca₃Ca_1.5Al₂(SO₄)F₁₃ · 12H₂O

Also given as Ca_4.5Al₂(SO₄)F₁₃ · 12H₂O.

Colour:

Colorless, white

Lustre:

Vitreous

Hardness:

3½

Specific Gravity:

2.23 (Calculated)

Crystal System:

Isometric

Member of:

Chukhrovite Group

Name:

Named in 2011 by P. Vignola, F. Hatert, Olaf Medenbach, D. Bersani, V. Diella, P. Gentile, and A. Risplendente in honor of Fedor Vasil'evich Chukhrov and for its being the Ca analogue of chukrovite-(Ce).

Type Locality:

ⓘ Val Cavallizza mine, Cavagnano, Cuasso al Monte, Varese Province, Lombardy, Italy

Very closely related to meniaylovite.

Unique IdentifiersHide

Mindat ID:

41907

Long-form identifier:

mindat:1:1:41907:3

Similar NamesHide

Chukhrovite	A synonym
Chukhrovite-(Ce)	A valid IMA mineral species	Ca₃CeAl₂(SO₄)F₁₃ · 12H₂O
Chukhrovite-(Nd)	A valid IMA mineral species	Ca₃NdAl₂(SO₄)F₁₃ · 12H₂O
Chukhrovite-(Y)	A valid IMA mineral species	Ca₃YAl₂(SO₄)F₁₃ · 12H₂O

IMA Classification of Chukhrovite-(Ca)Hide

IMA status:

Approved

IMA Formula:

Ca₃Ca_1.5Al₂(S⁶⁺O₄)F₁₃·12H₂O

Approval year:

2011

First published:

2012

Type description reference:

Vignola, Pietro, Hatert, Frédéric, Bersani, Danilo, Diella, Valeria, Gentile, Paolo, Risplendente, Andrea (2012) Chukhrovite-(Ca), Ca_4.5Al₂(SO₄)F₁₃·12H₂O, a new mineral species from the Val Cavallizza Pb-Zn-(Ag) mine, Cuasso al Monte, Varese province, Italy. European Journal of Mineralogy, 24 (6) 1069-1076 doi:10.1127/0935-1221/2012/0024-2247

Classification of Chukhrovite-(Ca)Hide

Strunz-mindat (2026):

3.CG.

3 : HALIDES
C : Complex halides
G : Aluminofluorides with CO₃, SO₄, PO₄

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.

Symbol	Source	Reference for Standard
Chk-Ca	IMA–CNMNC	Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43
Chk	The Canadian Mineralogist (2019)	The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download

Physical Properties of Chukhrovite-(Ca)Hide

Lustre:

Vitreous

Transparency:

Transparent, Translucent

Colour:

Colorless, white

Streak:

White

Hardness:

3½ on Mohs scale

Tenacity:

Brittle

Cleavage:

None Observed
Without a distinct cleavage.

Density:

2.23 g/cm³ (Calculated)

Optical Data of Chukhrovite-(Ca)Hide

Type:

Isotropic

RI values:

n = 1.432(1)

Surface Relief:

High (negative)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.

Focus:

In focus

Chemistry of Chukhrovite-(Ca)Hide

Mindat Formula:

Ca₃Ca_1.5Al₂(SO₄)F₁₃ · 12H₂O

Also given as Ca_4.5Al₂(SO₄)F₁₃ · 12H₂O.

Element Weights:

Element	% weight
F	52.292 %
O	21.680 %
Al	11.426 %
S	6.789 %
Ca	6.789 %
H	1.024 %

Calculated from ideal end-member formula.

Elements listed:

Al, Ca, F, H, O, S - search for minerals with similar chemistry

Crystallography of Chukhrovite-(Ca)Hide

Crystal System:

Isometric

Class (H-M):

m3(2/m3) - Diploidal

Space Group:

Fd3

Setting:

Fd3

Cell Parameters:

a = 16.749(1) Å

Unit Cell V:

4698.6 Å³

Morphology:

Sharp octahedra up to 150 µm in diameter.

Twinning:

Twinning along the [001] axis, with a rotation of 90 deg (iron cross law), is widespread, while spinel law twins are rare.

Crystal StructureHide

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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure

ID	Species	Reference	Link	Year	Locality	Pressure (GPa)	Temp (K)
0019596	Chukhrovite-(Ca)	Vignola P, Hatert F, Bersani D, Diella V, Gentile P, Risplendente A (2012) Chukhrovite-(Ca), Ca4.5Al2(SO4)F1312H2O, a new mineral species from the Val Cavallizza Pb-Zn-(Ag) mine, Cuasso al Monte, Varese province, Italy* European Journal of Mineralogy 24 1069-1076		2012	Val Cavallizza mine, Cuasso al Monte, Varese province, Italy	0	293

CIF Raw Data - click here to close

data_global
_chemical_name_mineral 'Chukhrovite-(Ca)'
loop_
_publ_author_name
'Vignola P'
'Hatert F'
'Bersani D'
'Diella V'
'Gentile P'
'Risplendente A'
_journal_name_full 'European Journal of Mineralogy'
_journal_volume 24 
_journal_year 2012
_journal_page_first 1069
_journal_page_last 1076
_publ_section_title
;
 Chukhrovite-(Ca), Ca4.5Al2(SO4)F13*12H2O, a new mineral species from
 the Val Cavallizza Pb-Zn-(Ag) mine, Cuasso al Monte, Varese province, Italy
;
_database_code_amcsd 0019596
_chemical_compound_source 'Val Cavallizza mine, Cuasso al Monte, Varese province, Italy'
_chemical_formula_sum 'Ca4.33 Na.12 Fe.03 Al2 S F13 O16 H24'
_cell_length_a 16.749
_cell_length_b 16.749
_cell_length_c 16.749
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 90
_cell_volume 4698.581
_exptl_crystal_density_diffrn      2.237
_symmetry_space_group_name_H-M 'F d 3'
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  '3/4+y,1/4+z,1/2-x'
  '3/4+y,3/4+z,-x'
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  '-y,-z,-x'
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  '1/4-x,1/2+y,3/4-z'
  'x,3/4-y,3/4-z'
  'x,1/4-y,1/4-z'
  '1/2+x,3/4-y,1/4-z'
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loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
Ca1   0.29285   0.29285   0.29285   1.00000   0.02050
Ca2  -0.12500   0.37500   0.60300   0.05500   0.05200
Na2  -0.12500   0.37500   0.60300   0.02000   0.05200
Fe2  -0.12500   0.37500   0.60300   0.00500   0.05200
Al   0.50000   0.50000   0.50000   1.00000   0.01740
S   0.12500   0.12500   0.12500   1.00000   0.02690
F1   0.37500   0.37500   0.37500   1.00000   0.01700
F2   0.21970   0.34000   0.44940   1.00000   0.02900
O   0.07400   0.07400   0.07400   1.00000   0.03100
Owat   0.15560   0.24360   0.30710   1.00000   0.04010
H1   0.13200   0.21300   0.27600   1.00000   0.08000
H2   0.15100   0.21300   0.35000   1.00000   0.09000
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
Ca1 0.02050 0.02050 0.02050 -0.00190 -0.00190 -0.00190
Ca2 0.06000 0.04100 0.06000 -0.00400 0.00000 0.00000
Na2 0.06000 0.04100 0.06000 -0.00400 0.00000 0.00000
Fe2 0.06000 0.04100 0.06000 -0.00400 0.00000 0.00000
Al 0.01740 0.01740 0.01740 -0.00310 -0.00310 -0.00310
S 0.02690 0.02690 0.02690 0.00000 0.00000 0.00000
F1 0.01700 0.01700 0.01700 0.00000 0.00000 0.00000
F2 0.03000 0.02400 0.03300 -0.00310 -0.00210 0.01040
O 0.03100 0.03100 0.03100 -0.00200 -0.00200 -0.00200
Owat 0.03400 0.05500 0.03100 -0.01800 -0.00200 0.00200

X-Ray Powder DiffractionHide

Powder Diffraction Data:

d-spacing	Intensity
9.665 Å	(100)
5.921 Å	(31)
5.053 Å	(16)
4.190 Å	(10)
3.226 Å	(15)
2.556 Å	(10)
2.182 Å	(12)
1.915 Å	(17)

Locality:

Val Cavallizza mine, Cavagnano, Cuasso al Monte, Varese Province, Lombardy, Italy

Reference:

Geological EnvironmentHide

Paragenetic Mode(s):

Paragenetic Mode	Earliest Age (Ga)
Stage 7: Great Oxidation Event	<2.4
46 : Near-surface hydrothermal alteration of minerals (see also #22)
47a : [Near-surface hydration of prior minerals]
47b : [Sulfates and sulfites]
47g : [Halogen-bearing surface weathering minerals]
Stage 10b: Anthropogenic minerals	<10 Ka
56 : Slag and smelter minerals (see also #51 and #55)

Type Occurrence of Chukhrovite-(Ca)Hide

Type Locality:

ⓘ Val Cavallizza mine, Cavagnano, Cuasso al Monte, Varese Province, Lombardy, Italy

General Appearance of Type Material:

Colourless to whitish, transparent to translucent, sharp octahedral crystals up to 100–150 µm diameter.

Place of Conservation of Type Material:

Museum of Natural History of Milano, Italy, catalogue number M37901.
Laboratory of Mineralogy of the University of Liege, Belgium, catalogue number 20383.

Geological Setting of Type Material:

Found as low temperature hydrothermal crystallizations covering the surfaces of brittle fractures crosscutting a marcasite and REE-bearing fluorite vein.

Associated Minerals at Type Locality:

Gypsum

Marcasite

Reference:

Synonyms of Chukhrovite-(Ca)Hide

IMA2010-081

Chukhrovite (in part)

Other Language Names for Chukhrovite-(Ca)Hide

Dutch:Chukhroviet-(Ca)

German:Chukhrovit-(Ca)

Relationship of Chukhrovite-(Ca) to other SpeciesHide

Member of:

Chukhrovite Group

Other Members of Chukhrovite Group:

Chukhrovite-(Ce)	Ca₃CeAl₂(SO₄)F₁₃ · 12H₂O	Iso. m3(2/m3) : Fd3
Chukhrovite-(Nd)	Ca₃NdAl₂(SO₄)F₁₃ · 12H₂O	Iso. m3(2/m3) : Fd3
Chukhrovite-(Y)	Ca₃YAl₂(SO₄)F₁₃ · 12H₂O	Iso. m3(2/m3) : Fd3
Meniaylovite	Ca₄[(SO₄)(SiF₆)(AlF₆)]F · 12H₂O	Iso. m3(2/m3) : Fd3

Common AssociatesHide

Associations Based on Photo Data:

2 photos of Chukhrovite-(Ca) associated with Plumbojarosite	Pb_0.5Fe³⁺₃(SO₄)₂(OH)₆
2 photos of Chukhrovite-(Ca) associated with 'Limonite'
1 photo of Chukhrovite-(Ca) associated with Anglesite	PbSO₄
1 photo of Chukhrovite-(Ca) associated with Leonardsenite	MgAlF₅ · 2H₂O

Related Minerals - Strunz-mindat Grouping Hide

3.CG.05	Stenonite	Sr₂Al(CO₃)F₅	Mon. 2/m : P2₁/c
3.CG.10	Meniaylovite	Ca₄[(SO₄)(SiF₆)(AlF₆)]F · 12H₂O	Iso. m3(2/m3) : Fd3
3.CG.10	Chukhrovite-(Ce)	Ca₃CeAl₂(SO₄)F₁₃ · 12H₂O	Iso. m3(2/m3) : Fd3
3.CG.10	Chukhrovite-(Y)	Ca₃YAl₂(SO₄)F₁₃ · 12H₂O	Iso. m3(2/m3) : Fd3
3.CG.10	Chukhrovite-(Nd)	Ca₃NdAl₂(SO₄)F₁₃ · 12H₂O	Iso. m3(2/m3) : Fd3
3.CG.15	Creedite	Ca₃Al₂(SO₄)(OH)₂F₈ · 2H₂O	Mon. 2/m : B2/b
3.CG.20	Bøggildite	Na₂Sr₂Al₂PO₄F₉	Mon. 2/m : P2₁/c
3.CG.25	Thermessaite-(NH4)	(NH₄)₂AlF₃(SO₄)	Orth. mmm(2/m2/m2/m) : Pbcn
3.CG.25	Thermessaite	K₂AlF₃(SO₄)	Orth. mmm(2/m2/m2/m) : Pbcn
3.CG.30	Kruijenite	Ca₄Al₄(SO₄)F₂(OH)₁₆ · 2H₂O	Tet. 4/mmm(4/m2/m2/m) : P4/nnc

Fluorescence of Chukhrovite-(Ca)Hide

In UV light:

Non-fluorescent either under short-wave (254 nm) or long-wave (366 nm) ultraviolet light

Other InformationHide

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for Chukhrovite-(Ca)Hide

mindat.org URL:

https://www.mindat.org/min-41907.html
Please feel free to link to this page.

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External Links:

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Raman and XRD data at RRUFF project

References and PDF downloads at RRUFF project

American Mineralogist Crystal Structure Database

Handbook of Mineralogy page PDF

Mineral Dealers:

Buy from D. Joyce minerals

References for Chukhrovite-(Ca)Hide

Reference List:

Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2011) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) Newsletter 8. Mineralogical Magazine, 75 (2) 289-294 doi:10.1180/minmag.2011.075.2.289

Kolitsch, U.; Brandstätter, F.; Schreiber, F.; Fink, R.; Auer, C. (2013) Die Mineralogie der weltweit einzigartigen Schlacken von Waitschach, Kärnten. Annalen des Naturhistorischen Museums in Wien, 115. 19-87

(2015) Chukhrovite-(Ca). Handbook of Mineralogy. Mineralogical Society of America

Localities for Chukhrovite-(Ca)Hide

Showing 5 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the

symbol to view information about a locality. The

symbol next to localities in the list can be used to jump to that position on the map.

Hide all sections | Show all sections

Locality ListHide

- This locality has map coordinates listed.

- This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality.

- Good crystals or important locality for species.

- World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). ~~Struck out~~ - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.


Austria
Carinthia Sankt Veit an der Glan District Guttaring Waitschach ⓘ Slag localities	Kolitsch et al. (2013)

Germany
Saxony Erzgebirgskreis Annaberg-Buchholz Kleinrückerswalde ⓘ Uranus Mine	Möhn

Greece
Attica East Attica Lavreotiki Agios Konstantinos (Kamariza) Mercati mines ⓘ Christiana Mine No. 132	Rieck et al. (2018)

Italy (TL)
Lombardy Varese Province Cuasso al Monte Cavagnano ⓘ Val Cavallizza mine (TL)	Williams et al. (2011) +1 other reference
Valganna ⓘ Valvassera mine	Mercurio et al. (2021)

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Chukhrovite-(Ca)

About Chukhrovite-(Ca)Hide

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IMA Classification of Chukhrovite-(Ca)Hide

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Physical Properties of Chukhrovite-(Ca)Hide

Optical Data of Chukhrovite-(Ca)Hide

Chemistry of Chukhrovite-(Ca)Hide

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Related Minerals - Strunz-mindat GroupingHide

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Related Minerals - Strunz-mindat Grouping Hide