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Ferrotochilinite
A valid IMA mineral species
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About Ferrotochilinite
Formula:
Fe2+6(Fe2+,Mg)5S6(OH)10
Colour:
dark bronze
Lustre:
Sub-Metallic
Hardness:
1
Specific Gravity:
3.467 (Calculated)
Crystal System:
Monoclinic
Member of:
Name:
For the mineral tochilinite and its iron content.
Unique Identifiers
Mindat ID:
41905
Long-form identifier:
mindat:1:1:41905:5
IMA Classification of Ferrotochilinite
Approved
IMA Formula:
6Fe2+S2-·5Fe2+(OH)2
Approval year:
2011
First published:
2013
Type description reference:
Pekov, I. V., Sereda, E. V., Polekhovsky, Yu. S., Britvin, S. N., Chukanov, N. V., Yapaskurt, V. O., Bryzgalov, I. A. (2013) Ferrotochilinite, 6FeS · 5Fe(OH)2, a new mineral from the Oktyabr’sky deposit, Noril’sk district, Siberia, Russia. Geology of Ore Deposits, 55 (7) 567-574 doi:10.1134/s1075701513070106
Classification of Ferrotochilinite
2.FD.35
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
F : Sulfides of arsenic, alkalies; sulfides with halide, oxide, hydroxide, H2O
D : With O, OH, H2O
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
F : Sulfides of arsenic, alkalies; sulfides with halide, oxide, hydroxide, H2O
D : With O, OH, H2O
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference for Standard |
|---|---|---|
| Ftch | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Ferrotochilinite
Sub-Metallic
Transparency:
Opaque
Colour:
Dark bronze
Comment:
With time, it becomes dull and darkens to almost black, with a blue violet or golden brown iridescence.
Streak:
Black
Hardness:
1 on Mohs scale
Hardness:
VHN100=13 - Vickers
Tenacity:
Flexible
Cleavage:
Perfect
{001}
{001}
Fracture:
Micaceous
Comment:
fracture is laminated
Density:
3.467 g/cm3 (Calculated)
Optical Data of Ferrotochilinite
Anisotropism:
Distinct, gray bluish to yellowish beige rotation colors.
Bireflectance:
Distinct.
Reflectivity:
| Wavelength | R1 (%) | R2 (%) |
|---|---|---|
| 400nm | 12.6% | 10.8% |
| 420nm | 12.3% | 10.9% |
| 440nm | 12.0% | 11.0% |
| 460nm | 11.7% | 11.1% |
| 470nm | 11.6% | 11.4% |
| 480nm | 11.5% | 11.3% |
| 500nm | 11.4% | 11.5% |
| 520nm | 11.3% | 11.8% |
| 540nm | 11.2% | 12.2% |
| 546nm | 11.2% | 12.4% |
| 560nm | 11.2% | 12.7% |
| 580nm | 11.1% | 13.3% |
| 589nm | 11.1% | 13.6% |
| 600nm | 11.1% | 14.0% |
| 620nm | 11.0% | 14.6% |
| 640nm | 11.0% | 15.2% |
| 650nm | 11.0% | 15.5% |
| 660nm | 10.9% | 15.8% |
| 680nm | 10.8% | 16.3% |
| 700nm | 10.8% | 16.9% |
Graph shows reflectance levels at different wavelengths (in nm). Peak reflectance is 16.9%.
R1 shown in black, R2 shown in red
Colour in reflected light:
Gray.
Internal Reflections:
None.
Pleochroism:
Visible
Comments:
Gray with a hue ranging from bluish (Rmin) to pale beige (Rmax).
Chemistry of Ferrotochilinite
Mindat Formula:
Fe2+6(Fe2+,Mg)5S6(OH)10
Element Weights:
Crystallography of Ferrotochilinite
Crystal System:
Monoclinic
Cell Parameters:
a = 5.463(5) Å, b = 15.865(17) Å, c = 10.825(12) Å
β = 93.7(1)°
β = 93.7(1)°
Ratio:
a:b:c = 0.344 : 1 : 0.682
Unit Cell V:
936.25 ų (Calculated from Unit Cell)
Z:
2
Comment:
Space group C2/m, Cm or C2.
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 10.83 Å | (13) |
| 5.392 Å | (100) |
| 3.281 Å | (7) |
| 2.777 Å | (7) |
| 2.696 Å | (12) |
| 2.524 Å | (12) |
| 2.152 Å | (8) |
| 1.837 Å | (11) |
Reference:
Pekov, I. V., Sereda, E. V., Polekhovsky, Yu. S., Britvin, S. N., Chukanov, N. V., Yapaskurt, V. O., Bryzgalov, I. A. (2013) Ferrotochilinite, 6FeS · 5Fe(OH)2, a new mineral from the Oktyabr’sky deposit, Noril’sk district, Siberia, Russia. Geology of Ore Deposits, 55 (7) 567-574 doi:10.1134/s1075701513070106
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 7: Great Oxidation Event | <2.4 |
| 47a : [Near-surface hydration of prior minerals] |
Type Occurrence of Ferrotochilinite
General Appearance of Type Material:
flattened parallel to [001] prismatic to elongated lamellar crystals. Aggregates (up to 6.5 mm in size) are fanlike, rosettelike, or chaotic.
Place of Conservation of Type Material:
Fersman Mineralogical Museum of Russian Academy of Sciences, Moscow, registration number 4058/1
Associated Minerals at Type Locality:
Reference:
Pekov, I. V., Sereda, E. V., Polekhovsky, Yu. S., Britvin, S. N., Chukanov, N. V., Yapaskurt, V. O., Bryzgalov, I. A. (2013) Ferrotochilinite, 6FeS · 5Fe(OH)2, a new mineral from the Oktyabr’sky deposit, Noril’sk district, Siberia, Russia. Geology of Ore Deposits, 55 (7) 567-574 doi:10.1134/s1075701513070106
Synonyms of Ferrotochilinite
Other Language Names for Ferrotochilinite
Dutch:Ferrotochiliniet
German:Ferrotochilinit
Relationship of Ferrotochilinite to other Species
Member of:
Other Members of Valleriite Group:
| Ekplexite | (Nb,Mo,W)S2 · (Mg1-xAlx)(OH)2+x | Trig. |
| Ferrovalleriite | 2(Fe,Cu)S · 1.5Fe(OH)2 | Trig. |
| Haapalaite | (Fe2+,Ni)2(Mg,Fe2+)1.61S2(OH)3.22 | Hex. |
| Tochilinite | Fe2+5-6(Mg,Fe2+)5S6(OH)10 | Mon. |
| Valleriite | (Fe2+,Cu)4(Mg,Al)3S4(OH,O)6 | Trig. |
| Yushkinite | (Mg,Al)V4+S2(OH)2 | Trig. 3m(32/m) : P3m1 |
Related Minerals - Strunz-mindat Grouping
| 2.FD. | Ferrovalleriite | 2(Fe,Cu)S · 1.5Fe(OH)2 |
| 2.FD.05 | Kermesite | Sb2S2O |
| 2.FD.10 | Viaeneite | (Fe,Pb)4S8O |
| 2.FD.20 | Erdite | NaFeS2 · 2H2O |
| 2.FD.25 | Coyoteite | NaFe3S5 · 2H2O |
| 2.FD.30 | Yushkinite | (Mg,Al)V4+S2(OH)2 |
| 2.FD.30 | Valleriite | (Fe2+,Cu)4(Mg,Al)3S4(OH,O)6 |
| 2.FD.30 | Ekplexite | (Nb,Mo,W)S2 · (Mg1-xAlx)(OH)2+x |
| 2.FD.30 | Haapalaite | (Fe2+,Ni)2(Mg,Fe2+)1.61S2(OH)3.22 |
| 2.FD.35 | Kaskasite | (Mo,Nb)S2 · (Mg1-xAlx)(OH)2+x |
| 2.FD.35 | Manganokaskasite | (Mo,Nb)S2 · (Mn1-xAlx)(OH)2+x |
| 2.FD.35 | Tochilinite | Fe2+5-6(Mg,Fe2+)5S6(OH)10 |
| 2.FD.40 | Wilhelmramsayite | Cu3FeS3 · 2H2O |
| 2.FD.45 | Vyalsovite | FeCaAlS(OH)5 |
| 2.FD.50 | Bazhenovite | Ca8S2(S3)(S2O3)(OH)12 · 20H2O |
| 2.FD.55 | 'UM2004-56-OS:BiCuPb' | PbCu4Bi4S2(O,OH,H2O)16 (?) |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Ferrotochilinite
mindat.org URL:
https://www.mindat.org/min-41905.html
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References for Ferrotochilinite
Reference List:
Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2011) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) Newsletter 8. Mineralogical Magazine, 75 (2) 289-294 doi:10.1180/minmag.2011.075.2.289
Pekov, I. V., Sereda, E. V., Polekhovsky, Yu. S., Britvin, S. N., Chukanov, N. V., Yapaskurt, V. O., Bryzgalov, I. A. (2013) Ferrotochilinite, 6FeS · 5Fe(OH)2, a new mineral from the Oktyabr’sky deposit, Noril’sk district, Siberia, Russia. Geology of Ore Deposits, 55 (7) 567-574 doi:10.1134/s1075701513070106
Localities for Ferrotochilinite
Showing 4 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Australia | |
| R Bottrill unpub. Data |
Costa Rica | |
| Garvie (2021) |
Czech Republic | |
| Veselovskỳ et al. (2018) |
Russia (TL) | |
| Williams et al. (2011) +2 other references |
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The
Oktyabrsky Mine, Talnakh Cu-Ni Deposit, Norilsk-Talnakh Mining Region, Taimyr Peninsula, Taymyrskiy Autonomous Okrug, Krasnoyarsk Krai, Russia