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Veszelyite

A valid IMA mineral species - grandfathered
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About VeszelyiteHide

Formula:
(Cu,Zn)2Zn(PO4)(OH)3 · 2H2O
Colour:
Green, blue, greenish blue, dark blue; greenish blue in transmitted light
Lustre:
Vitreous
Hardness:
3½ - 4
Specific Gravity:
3.4
Crystal System:
Monoclinic
Name:
Named after Ágost Veszely (1821-1879), a Hungarian mining engineer who discovered the species.
The P analogue of arsenoveszelyite.

A rare secondary Cu-Zn mineral occurring in the oxidised zones of base metal deposits.


Unique IdentifiersHide

Mindat ID:
4176
Long-form identifier:
mindat:1:1:4176:4

IMA Classification of VeszelyiteHide

Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
(Cu2+,Zn2+)2Zn2+(PO4)(OH)3·2H2O
First published:
1874

Classification of VeszelyiteHide

8.DE.30

8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
E : With only medium-sized cations, (OH, etc.):RO4 = 3:1
42.2.3.1

42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
2 : (AB)3(XO4)Zq·xH2O
19.6.5

19 : Phosphates
6 : Phosphates of Zn

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
VszIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of VeszelyiteHide

Vitreous
Transparency:
Translucent
Colour:
Green, blue, greenish blue, dark blue; greenish blue in transmitted light
Streak:
Green to white
Hardness:
3½ - 4 on Mohs scale
Cleavage:
Distinct/Good
On {001} and {110}.
Density:
3.4 g/cm3 (Measured)    3.42 g/cm3 (Calculated)

Optical Data of VeszelyiteHide

Type:
Biaxial (+)
RI values:
nα = 1.618 - 1.64 nβ = 1.622 - 1.658 nγ = 1.658 - 1.695
2V:
Measured: 35° to 71°, Calculated: 38° to 72°
Max. Birefringence:
δ = 0.040 - 0.055
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
r > v
Pleochroism:
Weak
Comments:
Z = Blue
X = Greenish blue

Chemistry of VeszelyiteHide

Mindat Formula:
(Cu,Zn)2Zn(PO4)(OH)3 · 2H2O
Element Weights:
Element% weight
O38.450 %
Cu33.937 %
Zn17.458 %
P8.271 %
H1.884 %

Calculated from ideal end-member formula.
O
Cu
Zn
P
H

Crystallography of VeszelyiteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/c
Cell Parameters:
a = 9.8275 Å, b = 10.2244 Å, c = 7.5322 Å
β = 103.18°
Ratio:
a:b:c = 0.961 : 1 : 0.737
Unit Cell V:
736.90 ų (Calculated from Unit Cell)
Z:
4
Morphology:
Crystals short prismatic {100}, elongated [001]. Commonly pseudo-octahedral {100} and {011}, modified by {001}, {110}, {111} and {121}; also as granular aggregates.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0019907VeszelyiteDanisi R M, Armbruster T, Lazic B, Vulic P, Kaindl R, Dimitrijevic R, Kahlenberg V (2013) In situ dehydration behavior of veszelyite (Cu,Zn)2Zn(PO4)(OH)3*2H2O: A single-crystal X-ray study American Mineralogist 98 1261-12692013Zdravo Vrelo, near Kresevo (Bosnia and Herzegovina)0293
0000408VeszelyiteGhose S, Leo S R, Wan C (1974) Structural chemistry of copper and zinc minerals. Part I. Veszelyite, (Cu,Zn)2ZnPO4(OH)3*2H2O: A novel type of sheet structure and crystal chemistry of copper-zinc substitution American Mineralogist 59 573-5811974Arakawa mine, Japan0293
0019906VeszelyiteDanisi R M, Armbruster T, Lazic B, Vulic P, Kaindl R, Dimitrijevic R, Kahlenberg V (2013) In situ dehydration behavior of veszelyite (Cu,Zn)2Zn(PO4)(OH)3*2H2O: A single-crystal X-ray study American Mineralogist 98 1261-12692013Zdravo Vrelo, near Kresevo (Bosnia and Herzegovina)0173
0019908VeszelyiteDanisi R M, Armbruster T, Lazic B, Vulic P, Kaindl R, Dimitrijevic R, Kahlenberg V (2013) In situ dehydration behavior of veszelyite (Cu,Zn)2Zn(PO4)(OH)3*2H2O: A single-crystal X-ray study American Mineralogist 98 1261-12692013Zdravo Vrelo, near Kresevo (Bosnia and Herzegovina)0473
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.642 Å(100)
6.96 Å(40)
4.489 Å(30)
3.482 Å(30)
2.771 Å(30)
7.29 Å(25)
2.956 Å(25)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 7: Great Oxidation Event<2.4
47a : [Near-surface hydration of prior minerals]
47c : [Carbonates, phosphates, borates, nitrates]
Stage 10b: Anthropogenic minerals<10 Ka
56 : Slag and smelter minerals (see also #51 and #55)
Geological Setting:
Oxidised zones of base metal deposits.

Type Occurrence of VeszelyiteHide

Synonyms of VeszelyiteHide

Other Language Names for VeszelyiteHide

German:Veszelyit
Simplified Chinese:磷砷锌铜矿
Spanish:Veszelyita

Common AssociatesHide

Associations Based on Photo Data:
294 photos of Veszelyite associated with HemimorphiteZn4Si2O7(OH)2 · H2O
56 photos of Veszelyite associated with CuprodongchuanitePb4CuZn2(PO4)4(OH)2
53 photos of Veszelyite associated with QuartzSiO2
38 photos of Veszelyite associated with Dongchuanite GroupA4 ⅥBⅣB2[(T1)O4]2[(T2)O4]2Y2
37 photos of Veszelyite associated with