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Neptunite Group
A group of related mineral species
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About Neptunite Group
The general formula can be given as KNa2(M12M22)M3(Si4O12)2, where the similar octahedrally coordinated M1 and M2 sites are grouped for nomenclature purposes and may contain Fe2+, Mn2+, Mg2+, Ti4+ and V4+.
M1' = Li, Fe2+, M2 = Fe2+, Mn2+, Mg and M3 = Ti, Fe2+, V4+.
M1' = Li, Fe2+, M2 = Fe2+, Mn2+, Mg and M3 = Ti, Fe2+, V4+.
Unique Identifiers
Mindat ID:
39911
Long-form identifier:
mindat:1:1:39911:3
Chemical Analysis
Oxide wt%:
| 1 | 2 | |
|---|---|---|
| SiO2 | 51.53 % | 52.29 % |
| TiO2 | 18.13 % | 17.38 % |
| FeO | 10.91 % | 11.92 % |
| MnO | 4.97 % | 2.27 % |
| MgO | 0.49 % | 1.55 % |
| K2O | 4.88 % | 5.58 % |
| Na2O | 9.26 % | 6.81 % |
| CaO | 0.62 % | |
| Li2O | 1.63 % | |
| Total: | 100.17 % | 100.05 % |
Sample references:
| ID | Type | Locality | Reference | Notes |
|---|---|---|---|---|
| 1 | Type Specimen | Narssârssuk pegmatite, Narsaarsuk Plateau, Igaliku, Kujalleq, Greenland | Wet-chemical analysis (Flink), analysis incomplete, Li not analyzed | |
| 2 | California State Gem Mine, Santa Rita Peak, San Benito County, California, USA | Microprobe |
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
| ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
|---|---|---|---|---|---|---|---|
| 0015717 | Manganoneptunite | Zolotarev A A, Krivovichev S V, Yakovenchuk V N (2007) Refinement of the mangan-neptunite structure Zapiski Vserossijskogo Mineralogicheskogo Obshchestva 136 118-123 | 2007 | Mt. Kaskasnyuncharr, the Khibiny alkaline pluton, Russia | 0 | 293 | |
| 0013131 | Watatsumiite | Matsubara S, Miyawaki R, Kurosawa M, Suzuki Y (2003) Watatsumiite, KNa2LiMn2V2Si8O24, a new mineral from the Tanohata mine, Iwate Prefecture, Japan Journal of Mineralogical and Petrological Sciences 98 142-150 | ![]() | 2003 | metamorphosed manganese ore deposit, Tanohata mine, Iwate Prefecture, Japan | 0 | 293 |
| 0018847 | Neptunite | Cannillo E, Mazzi F, Rossi G (1966) The crystal structure of neptunite Acta Crystallographica 21 200-208 | ![]() | 1966 | San Benito, California, USA | 0 | 293 |
| 0018809 | Manganoneptunite | Borisov S V, Klevtsova R F, Bakakin V V, Belov N V (1966) The crystal structure of neptunite Soviet Physics Crystallography 10 684-689 | 1966 | Lovozero, Russia | 0 | 293 |
CIF Raw Data - click here to close
Relationship of Neptunite Group to other Species
Neptunite Group Members:
| Magnesioneptunite | KNa2Li(Mg)2Ti2[Si4O12]2 | Mon. 2/m : B2/b |
| Manganoneptunite | KNa2Li(Mn2+)2Ti2[Si4O12]2 | Mon. m : Bb |
| Neptunite | KNa2Li(Fe2+)2Ti2[Si4O12]2 | Mon. m : Bb |
| Rotherkopfite | KNa2Fe2+(Fe2+)2(Ti1.5Fe2+0.5)[Si4O12]2 | Mon. 2/m : B2/b |
| Watatsumiite | KNa2Li(Mn2+)2V4+2[Si4O12]2 | Mon. m : Bb |
Click on any node to view relationships. Formula-derived relationship network for the group members above. Use Find related species to add formula-neighbour species outside the current group view. Solid links show inferred chemical differences; dashed violet links show same-formula crystallographic differences. Hydration states are not treated as relationship changes. These relationships do not imply any real-world substitution reactions between these species.
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Neptunite Group
mindat.org URL:
https://www.mindat.org/min-39911.html
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References for Neptunite Group
Reference List:
Kampf, A. R., Möhn, G., Ma, C., Rossman, G. R., Désor, J., Guan, Y. (2024) Rotherkopfite, KNa₂(Fe²⁺2.5Ti⁴⁺1.5)Fe²⁺(Si₄O₁₂)₂, a new neptunite-group mineral without essential lithium, from Rother Kopf, Eifel volcanic fields, Germany. European Journal of Mineralogy, 36 (4). 605-614 doi:10.5194/ejm-36-605-2024
Localities for Neptunite Group
Showing 109 localities.
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.









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The
California State Gem Mine, Santa Rita Peak, San Benito County, California, USA