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Chromo-alumino-povondraite

A valid IMA mineral species
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About Chromo-alumino-povondraiteHide

Formula:
NaCr3(Al4Mg2)(Si6O18)(BO3)3(OH)3O
Colour:
Green
Lustre:
Vitreous
Hardness:
7½
Specific Gravity:
3.227 (Calculated)
Crystal System:
Trigonal
Name:
For the chemical relationship to Povondraite
Tourmaline group.
The Cr analogue of vanadio-oxy-dravite and bosiite.
Ideally, chromo-alumino-povondraite is related to oxy-dravite and oxy-chromium-dravite by the homovalent substitution Cr3+ ↔ Al3+.


Approved by CNMNC-IMA in 2010 (IMA2009-088), with type locality in Orissa, India, but withdrawn in january 2013 after subsequent analytical work undertaken by the authors showed this material to be a chromium-dravite. Resubmitted as IMA2013-089 with a new type locality, the Pereval marble quarry in Russia.

Tourmaline with chemical compositions classified as chromo-alumino-povondraite can be either Al-dominant or Cr-dominant as a result of the compositional boundaries along the solid solution between Al and Cr3+ that are determined at Y+Z(Cr1.5Al5.5), corresponding to NaY(Cr1.5Al1.5)Z(Al4Mg2)Si6O18(BO3)3(OH)3O, and Y+Z(Cr5Al2), corresponding to NaY(Cr3)Z(Cr2Al2Mg2)Si6O18(BO3)3(OH)3O (Reznitskii et al. 2014).


Unique IdentifiersHide

Mindat ID:
39891
Long-form identifier:
mindat:1:1:39891:0

IMA Classification of Chromo-alumino-povondraiteHide

Classification of Chromo-alumino-povondraiteHide

9.CK.05

9 : SILICATES (Germanates)
C : Cyclosilicates
K : [Si6O18]12- 6-membered single rings, with insular complex anions

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
CapovIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of Chromo-alumino-povondraiteHide

Vitreous
Transparency:
Transparent
Colour:
Green
Streak:
Pale-green
Hardness:
7½ on Mohs scale
Comment:
approximately 7½
Tenacity:
Brittle
Fracture:
Conchoidal
Density:
3.227 g/cm3 (Calculated)

Optical Data of Chromo-alumino-povondraiteHide

Type:
Uniaxial (-)
RI values:
nω = 1.745(5) nε = 1.685(5)
Max. Birefringence:
δ = 0.060
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized uniaxial interference figure - the conoscopic (convergent-light, Bertrand-lens-in) view, for a grain cut with the optic axis centred and vertical. The coloured rings are isochromatics, computed with the same physics as the Michel-Lévy bar above; the dark cross is the isogyre.

For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.
Pleochroism:
Visible
Comments:
O = emerald green and E = pale yellowish green.

Chemistry of Chromo-alumino-povondraiteHide

Mindat Formula:
NaCr3(Al4Mg2)(Si6O18)(BO3)3(OH)3O
Element Weights:
Element% weight
O47.899 %
Si16.274 %
Cr15.065 %
Al10.423 %
Mg4.695 %
B3.132 %
Na2.220 %
H0.292 %

Calculated from ideal end-member formula.
O
Si
Cr
Al
Mg
B
Na
H

Crystallography of Chromo-alumino-povondraiteHide

Crystal System:
Trigonal
Class (H-M):
3m - Ditrigonal Pyramidal
Space Group:
R3m
Setting:
R3m
Cell Parameters:
a = 16.0277(2) Å, c = 7.3085(1) Å
Ratio:
a:c = 1 : 0.456
Unit Cell V:
1625.93 ų
Z:
3
Morphology:
Elongated {1010} and {1120} prisms terminated by a prominent {0001} pedion and small, minor {1011} pyramidal faces.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0020335Chromo-alumino-povondraiteReznitskii L, Clark C M, Hawthorne F C, Grice J D, Skogby H, Halenius U, Bosi F (2014) Chromo-alumino-povondraite, NaCr3(Al4Mg2)(Si6O18)(BO3)3(OH)3O, a new mineral species of the tourmaline supergroup American Mineralogist 99 1767-17732014Sludyanka, Lake Baikal, Russia0293
0020261Chromo-alumino-povondraiteBosi F, Skogby H, Halenius U, Reznitskii L (2013) Crystallographic and spectroscopic characterization of Fe-bearing chromo-alumino-povondraite and its relations with oxy-chromium-dravite and oxy-dravite American Mineralogist 98 1557-15642013Sludyanka crystalline complex, Lake Baikal, Russia0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Geological EnvironmentHide

Paragenetic Mode(s):

Type Occurrence of Chromo-alumino-povondraiteHide

Synonyms of Chromo-alumino-povondraiteHide

Other Language Names for Chromo-alumino-povondraiteHide

Relationship of Chromo-alumino-povondraite to other SpeciesHide

Other Members of Tourmaline:
AdachiiteCaFe3Al6(Si5AlO18)(BO3)3(OH)3(OH)Trig. 3m : R3m
Alumino-oxy-rossmanite◻Al3Al6(Si5AlO18)(BO3)3(OH)3OTrig. 3m : R3m
BosiiteNaFe3+3(Al4Mg2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
Celleriite◻(Mn2+2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
Chromium-draviteNaMg3Cr3+6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
DarrellhenryiteNa(Al2Li)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
DraviteNaMg3Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
DutrowiteNa(Fe2+2.5Ti0.5)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
ElbaiteNa(Li1.5Al1.5)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
ErtliteNaAl3Al6(Si4B2O18)(BO3)3(OH)3OTrig. 3m : R3m
Ferro-bosiiteNaFe3+3(Al4Fe2+2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
FeruviteCaFe2+3(Al5Mg)(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
Fluor-buergeriteNaFe3+3Al6(Si6O18)(BO3)3O3FTrig. 3m : R3m
Fluor-draviteNaMg3Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
Fluor-elbaiteNa(Li1.5Al1.5)Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
Fluor-liddicoatiteCa(Li2Al)Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
Fluor-rossmanite◻(Al2Li)Al6(Si6O18)(BO3)3(OH)3FTrig. 3m(32/m) : R3m
Fluor-schorlNaFe2+3Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
Fluor-tsilaisiteNaMn2+3Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
Fluor-uviteCaMg3(Al5Mg)(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
Foitite◻(Fe2+2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
LiddicoatiteCa(Li2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
LucchesiiteCaFe2+3 Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
Magnesio-dutrowiteNa(Mg2.5Ti0.5)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
Magnesio-foitite◻(Mg2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
Magnesio-lucchesiiteCaMg3Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
MaruyamaiteK(Al2Mg)(Al5Mg)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
OleniteNaAl3Al6(Si6O18)(BO3)3O3(OH)Trig. 3m : R3m
Oxy-chromium-draviteNaCr3(Cr4Mg2)(Si6O18)(BO3)3(OH)3O Trig. 3m : R3m
Oxy-draviteNa(Al2Mg)(Al5Mg)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
Oxy-foitite◻(Fe2+Al2)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m(32/m) : R3m
Oxy-schorlNa(Fe2+2Al)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
Oxy-vanadium-draviteNaV3(V4Mg2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
PovondraiteNaFe3+3(Mg2Fe3+4)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
PrincivalleiteNa(Mn2Al)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
Rossmanite◻(LiAl2)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
SchorlNaFe2+3Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
TsilaisiteNaMn2+3Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
'UM2000-64-SiO:BFeHKMg'(K,Na)Fe3+3(Mg2Fe3+4)Si6O18(BO3)3(OH)3O
'UM2008-52-SiO:AlBCaFFeHLiMgNa'(Ca,Na,◻)(Al,Li,Fe,Mg)3Al6[Si6O18](BO3)3(OH,O)3(F,O)
'Unnamed (F analogue of feruvite)'CaFe2+3(Al5Mg)(Si6O18)(BO3)3(OH)3F
'Unnamed (Mn2+-F-analogue of foitite)'◻(Mn2+2Al)Al6(Si6O18)(BO3)3(OH)3F ?
'Unnamed (Pb-analogue of Fluor-liddicoatite)'Pb(Li2Al)Al6(Si6O18)(BO3)3(OH)3F
UviteCaMg3(Al5Mg)(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
Vanadio-oxy-chromium-draviteNaV3(Cr4Mg2)(Si6O18)(BO3)3(OH)3O Trig. 3m : R3m
Vanadio-oxy-draviteNaV3(Al4Mg2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m

Common AssociatesHide

Associations Based on Photo Data:
3 photos of Chromo-alumino-povondraite associated with 'Chrome-Tremolite'◻{Ca2}{Mg5}(Si8O22)(OH)2
1 photo of Chromo-alumino-povondraite associated with Tremolite◻Ca2Mg5(Si8O22)(OH)2

Related Minerals - Strunz-mindat GroupingHide

9.CK.AdachiiteCaFe3Al6(Si5AlO18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.Magnesio-dutrowiteNa(Mg2.5Ti0.5)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.DarrellhenryiteNa(Al2Li)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.Fluor-schorlNaFe2+3Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
9.CK.PrincivalleiteNa(Mn2Al)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.Alumino-oxy-rossmanite◻Al3Al6(Si5AlO18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.DutrowiteNa(Fe2+2.5Ti0.5)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.Ferro-bosiiteNaFe3+3(Al4Fe2+2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.BosiiteNaFe3+3(Al4Mg2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.Celleriite◻(Mn2+2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05FeruviteCaFe2+3(Al5Mg)(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Chromium-draviteNaMg3Cr3+6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Fluor-rossmanite◻(Al2Li)Al6(Si6O18)(BO3)3(OH)3FTrig. 3m(32/m) : R3m
9.CK.05Oxy-schorlNa(Fe2+2Al)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05Fluor-elbaiteNa(Li1.5Al1.5)Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
9.CK.05DraviteNaMg3Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Fluor-uviteCaMg3(Al5Mg)(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
9.CK.05Foitite◻(Fe2+2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Vanadio-oxy-draviteNaV3(Al4Mg2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05Fluor-buergeriteNaFe3+3Al6(Si6O18)(BO3)3O3FTrig. 3m : R3m
9.CK.05'Unnamed (F analogue of feruvite)'CaFe2+3(Al5Mg)(Si6O18)(BO3)3(OH)3F
9.CK.05ErtliteNaAl3Al6(Si4B2O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05TsilaisiteNaMn2+3Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Fluor-liddicoatiteCa(Li2Al)Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
9.CK.05UviteCaMg3(Al5Mg)(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05ElbaiteNa(Li1.5Al1.5)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Fluor-tsilaisiteNaMn2+3Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
9.CK.05Oxy-foitite◻(Fe2+Al2)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m(32/m) : R3m
9.CK.05LiddicoatiteCa(Li2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Vanadio-oxy-chromium-draviteNaV3(Cr4Mg2)(Si6O18)(BO3)3(OH)3O Trig. 3m : R3m
9.CK.05Rossmanite◻(LiAl2)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Oxy-vanadium-draviteNaV3(V4Mg2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05OleniteNaAl3Al6(Si6O18)(BO3)3O3(OH)Trig. 3m : R3m
9.CK.05'UM2000-64-SiO:BFeHKMg'(K,Na)Fe3+3(Mg2Fe3+4)Si6O18(BO3)3(OH)3O
9.CK.05Magnesio-lucchesiiteCaMg3Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05PovondraiteNaFe3+3(Mg2Fe3+4)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05LucchesiiteCaFe2+3 Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05Fluor-draviteNaMg3Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
9.CK.05Oxy-draviteNa(Al2Mg)(Al5Mg)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05Oxy-chromium-draviteNaCr3(Cr4Mg2)(Si6O18)(BO3)3(OH)3O Trig. 3m : R3m
9.CK.05'Luinaite-(OH)'NaFe2+3Al6(Si6O18)(BO3)3(OH)3(OH)Mon. m : Bm
9.CK.05SchorlNaFe2+3Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Magnesio-foitite◻(Mg2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05MaruyamaiteK(Al2Mg)(Al5Mg)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.10Abenakiite-(Ce)Na26Ce6(Si6O18)(PO4)6(CO3)6(SO2)OTrig. 3 : R3
9.CK.15ScawtiteCa7(Si3O9)2CO3 · 2H2OMon. 2/m : B2/m
9.CK.20Thorosteenstrupine(Ca,Th,Mn)3Si4O11F · 6H2O
9.CK.20Steenstrupine-(Ce)Na14Mn2+2Fe3+2Ce6Zr(Si6O18)2(PO4)6(PO3OH)(OH)2 · 2H2OTrig. 3m(32/m) : R3m

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for Chromo-alumino-povondraiteHide

References for Chromo-alumino-povondraiteHide

Reference List:

Localities for Chromo-alumino-povondraiteHide

Showing 3 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
India
 
  • Odisha
    • Keonjhar District
IMA Approvals - Feb. 2010
Russia (TL)
 
  • Irkutsk Oblast
    • Slyudyansky District
      • Slyudyanka
Mineralogical Magazine +2 other references
USA
 
  • New York
    • St. Lawrence County
      • Fowler
        • Balmat
Lupulescu et al. (2011)
 
and/or  
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