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Pseudoboleite

A valid IMA mineral species - grandfathered
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About PseudoboleiteHide

Formula:
Pb31Cu24Cl62(OH)48
Colour:
Indigo blue, green-blue
Lustre:
Vitreous, Pearly
Hardness:
2½
Specific Gravity:
4.85
Crystal System:
Tetragonal
Name:
From the Greek "false" and boleite.
Closely related to boleite on which it may form epitaxial overgrowths.

See also the related blue Pb-Cu-chlorides diaboleite and cumengeite.


Unique IdentifiersHide

Mindat ID:
3301
Long-form identifier:
mindat:1:1:3301:1

IMA Classification of PseudoboleiteHide

Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
Pb2+31Cu2+24Cl62(OH)48
First published:
1895

Classification of PseudoboleiteHide

3.DB.10

3 : HALIDES
D : Oxyhalides, hydroxyhalides and related double halides
B : With Pb, Cu, etc.
10.6.8.1

10 : OXYHALIDES AND HYDROXYHALIDES
6 : AmBn(O,OH)pXq
8.8.14

8 : Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and Fluosilicates
8 : Halides of Pb

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
PbolIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of PseudoboleiteHide

Vitreous, Pearly
Transparency:
Translucent
Comment:
Pearly on cleavages.
Colour:
Indigo blue, green-blue
Streak:
Light green
Hardness:
2½ on Mohs scale
Cleavage:
Perfect
Perfect on {001}, nearly perfect on {101}
Density:
4.85 g/cm3 (Measured)    5.07 g/cm3 (Calculated)

Optical Data of PseudoboleiteHide

Type:
Uniaxial (-)
RI values:
nω = 2.03 nε = 2
Max. Birefringence:
δ = 0.030
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized uniaxial interference figure - the conoscopic (convergent-light, Bertrand-lens-in) view, for a grain cut with the optic axis centred and vertical. The coloured rings are isochromatics, computed with the same physics as the Michel-Lévy bar above; the dark cross is the isogyre.

For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.

Chemistry of PseudoboleiteHide

Mindat Formula:
Pb31Cu24Cl62(OH)48
Element Weights:
Element% weight
Pb58.591 %
Cl20.051 %
Cu13.912 %
O7.005 %
H0.441 %

Calculated from ideal end-member formula.
Pb
Cl
Cu
O
H

Crystallography of PseudoboleiteHide

Crystal System:
Tetragonal
Class (H-M):
4/mmm(4/m2/m2/m) - Ditetragonal Dipyramidal
Space Group:
I4/mmm
Cell Parameters:
a = 15.24(2) Å, c = 30.74(5) Å
Ratio:
a:c = 1 : 2.017
Unit Cell V:
7,139.60 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Rarely single crystals (pseudo-cubic, thick tabular). Commonly epitaxial overgrowths on boleite with mutually parallel {001}.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0014859PseudoboleiteGiuseppetti G, Mazzi F, Tadini C (1992) The crystal structure of pseudoboleite: Pb31Cu24Cl62(OH)48; its relations with the structures of boleite and cumengeite Neues Jahrbuch fur Mineralogie, Monatshefte 1992 113-1261992Boleo, Baja California, Mexico0293
CIF Raw Data - click here to close

Epitaxial Relationships of PseudoboleiteHide

Epitaxial Minerals:
'Boleite'KPb26Ag9Cu24(OH)48Cl62

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
4.43 Å(100)
3.83 Å(100)
2.707 Å(95)
2.551 Å(60)
2.389 Å(60)
2.334 Å(65)
1.990 Å(60)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 7: Great Oxidation Event<2.4
47a : [Near-surface hydration of prior minerals]
47g : [Halogen-bearing surface weathering minerals]
Geological Setting:
Secondary mineral of lead deposits. Smelter slag immersed in seawater.

Type Occurrence of PseudoboleiteHide

Other Language Names for PseudoboleiteHide

Simplified Chinese:水氯铜铅矿
Traditional Chinese:水氯銅鉛礦

Common AssociatesHide

Associations Based on Photo Data:
71 photos of Pseudoboleite associated with BoleiteKPb26Ag9Cu24(OH)48Cl62
17 photos of Pseudoboleite associated with CumengeitePb21Cu20Cl42(OH)40 · 6H2O
14 photos of Pseudoboleite associated with PhosgenitePb2CO3Cl2
12 photos of Pseudoboleite associated with ParatacamiteCu3(Cu,Zn)(OH)6Cl2
9 photos of Pseudoboleite associated with PenfielditePb2Cl3(OH)
8 photos of Pseudoboleite associated with LaurionitePbCl(OH)
8 photos of Pseudoboleite associated with GypsumCaSO4 · 2H2O
5 photos of Pseudoboleite associated with AtacamiteCu2(OH)3Cl
5 photos of Pseudoboleite associated with BindheimitePb2Sb2O6O
5 photos of Pseudoboleite associated with ParalaurionitePbCl(OH)

Related Minerals - Strunz-mindat GroupingHide

3.DB.RickturneritePb7O4[Mg(OH)4](OH)Cl3Orth. mmm(2/m2/m2/m) : Pnma
3.DB.05DiaboleitePb2CuCl2(OH)4Tet. 4mm : P4mm
3.DB.15BoleiteKPb26Ag9Cu24(OH)48Cl62Iso. m3m(4/m32/m) : Pm3m
3.DB.20CumengeitePb21Cu20Cl42(OH)40 · 6H2OTet. 4/mmm(4/m2/m2/m) : I4/mmm
3.DB.25BideauxitePb2AgCl3(F,OH)2Iso. m3m(4/m32/m) : Fd3m
3.DB.30ChloroxiphitePb3CuO2Cl2(OH)2Mon. 2/m : P21/m
3.DB.35HematophanitePb4Fe3O8(OH,Cl)Tet. 4mm : P4mm
3.DB.40ParkinsonitePb7MoO9Cl2Tet.
3.DB.40JanchevitePb9V5+(O10.25◻0.75)Cl2.5Tric. 1 : P1
3.DB.40AsisitePb7SiO9Cl2 Tet. 4/mmm(4/m2/m2/m) : I4/mmm
3.DB.45