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Moraesite

A valid IMA mineral species - grandfathered
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About MoraesiteHide

07419850017271925379419.jpg
Luciano Jacques de Moraes (1896–1968)
Formula:
Be2(PO4)(OH) · 4H2O
Colour:
White
Lustre:
Silky
Specific Gravity:
1.805
Crystal System:
Monoclinic
Name:
Named in 1953 by Marie Louise Lindberg (Smith), William T. Pecora, and Aluízio Licínio de Miranda Barbosa in honor of Dr. Luciano Jacques de Moraes [1896–1968], Brazilian mineralogist and geologist.
This page provides mineralogical data about Moraesite.


Unique IdentifiersHide

Mindat ID:
2778
Long-form identifier:
mindat:1:1:2778:2

Similar NamesHide

IMA Classification of MoraesiteHide

Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
Be2PO4(OH)·4H2O
First published:
1953

Classification of MoraesiteHide

8.DA.05

8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
A : With small (and occasionally larger) cations
42.6.1.1

42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
6 : A2(XO4)Zq·xH2O
19.3.1

19 : Phosphates
3 : Phosphates of Be and Mg

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
MaeIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of MoraesiteHide

Silky
Transparency:
Translucent
Colour:
White
Streak:
White
Cleavage:
Perfect
Parallel to b and c axes.
Density:
1.805 g/cm3 (Measured)    1.806 g/cm3 (Calculated)
Comment:
Measured with a pycnometer

Optical Data of MoraesiteHide

Type:
Biaxial (-)
RI values:
nα = 1.462 nβ = 1.482 nγ = 1.490
2V:
Measured: 65° , Calculated: 62°
Max. Birefringence:
δ = 0.028
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Moderate (negative)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
r > v strong
Optical Extinction:
Z = b, Y ∧ c = 11°.

Chemistry of MoraesiteHide

Mindat Formula:
Be2(PO4)(OH) · 4H2O
Element Weights:
Element% weight
O71.262 %
P15.329 %
Be8.920 %
H4.489 %

Calculated from ideal end-member formula.
O
P
Be
H

Crystallography of MoraesiteHide

Crystal System:
Monoclinic
Class (H-M):
m - Domatic
Space Group:
Bb
Setting:
Cc
Cell Parameters:
a = 8.553(6) Å, b = 36.957(18) Å, c = 7.155(8) Å
β = 97.93°
Ratio:
a:b:c = 0.231 : 1 : 0.194
Unit Cell V:
2,240.02 ų (Calculated from Unit Cell)
Z:
12
Morphology:
Acicular parallel to the c-axis [001], and tabular parallel to the orthopinacoid {100}. The pyramid face (131) is usually better developed than (131) and in some crystals gives the general appearance of a basal plane of a triclinic mineral. The faces (130) and (130) are better developed than (130) and (130). The orthopinacoid and prism faces of the forms {100} and {130} are striated parallel to the c-axis.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0011025MoraesiteMerlino S, Pasero M (1992) Crystal chemistry of beryllophosphates: The crystal structure of moraesite, Be2(PO4)(OH)*4H2O Zeitschrift fur Kristallographie 201 253-2621992Humaita, Brazil0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
7.00 Å(100)
3.278 Å(90)
4.24 Å(60)
3.023 Å(60)
2.819 Å(60)
6.15 Å(40)
2.325 Å(40)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Near-surface Processes
22 : Hydration and low-? subsurface aqueous alteration (see also #23)

Type Occurrence of MoraesiteHide

General Appearance of Type Material:
Occurs in tufted or radial aggregates, in fibrous coatings, or in spherulitic masses Delicate needles grade into crusts with a coarse fibrous structure. Crystals are minute singly terminated needle-like laths.
Place of Conservation of Type Material:
National Museum, Rio de Janeiro, Brazil.
National School of Mines, Paris, France, number 50740.
National Museum of Natural History (Smithsonian), Washington, D.C., USA, number 106577.
Geological Setting of Type Material:
Pegmatite
Associated Minerals at Type Locality:

Other Language Names for MoraesiteHide

Dutch:Moraesiet
German:Moraesit
Spanish:Moraesita

Common AssociatesHide

Associations Based on Photo Data:
13 photos of Moraesite associated with BerylloniteNaBePO4
12 photos of Moraesite associated with HydroxylherderiteCaBe(PO4)(OH)
9 photos of Moraesite associated with ZanazziiteCa2Mg5Be4(PO4)6(OH)4 · 6H2O
8 photos of Moraesite associated with QuartzSiO2
8 photos of Moraesite associated with EosphoriteMn2+Al(PO4)(OH)2 · H2O
6 photos of Moraesite associated with GreifensteiniteCa2Fe2+5Be4(PO4)6(OH)4 · 6H2O
6 photos of Moraesite associated with RoscheriteCa2Mn2+5Be4(PO4)6(OH)4 · 6H2O
5 photos of Moraesite associated with BerylBe3Al2(Si6O18)
4 photos of Moraesite associated with Wilancookite(Ba5Li2◻)Ba6Be24P24O96 · 26H2O
4 photos of Moraesite associated with AlbiteNa(AlSi3O8)

Related Minerals - Strunz-mindat GroupingHide

8.DA.05BearsiteBe2(AsO4)(OH) · 4H2OMon.
8.DA.10ZanazziiteCa2Mg5Be4(PO4)6(OH)4 · 6H2OMon. 2/m : B2/b
8.DA.10AtencioiteCa2Fe2+3Mg2Be4(PO4)6(OH)4 · 6H2OTric. 1 : P1
8.DA.10GuimarãesiteCa2Be4Zn5(PO4)6(OH)4 · 6H2OMon. 2/m : B2/b
8.DA.10FootemineiteCa2Mn2+Mn2+2Mn2+2Be4(PO4)6(OH)4 · 6H2OTric. 1 : P1
8.DA.10GreifensteiniteCa2Fe2+5Be4(PO4)6(OH)4 · 6H2OMon. 2/m : B2/b
8.DA.10RoscheriteCa2Mn2+5Be4(PO4)6(OH)4 · 6H2OMon. 2/m : B2/m
8.DA.10RuifrancoiteCa2(◻,Mn)2(Fe3+,Mn,Mg)4Be4(PO4)6(OH)4(OH,H2O)2 · 4H2OMon. 2/m : B2/b
8.DA.10OkruschiteCa2Mn2+5Be4(AsO4)6(OH)4 · 6H2OMon. 2/m : B2/b
8.DA.15UraloliteCa2Be4(PO4)3(OH)3 · 5H2OMon. 2/m : P21/c
8.DA.20WeinebeneiteCaBe3(PO4)2(OH)2 · 4H2OMon. m : Bb
8.DA.25TiptopiteK2(Na,Ca)2Li3Be6(PO4)6(OH)2 · H2OHex. 6 : P63
8.DA.40SpenceriteZn4(PO4)2(OH)2 · 3H2OMon. 2/m : P2/b
8.DA.45GlucineCaBe4(PO4)2(OH)4 · 0.5H2O

Other InformationHide

Notes:
Soluble in dilute HCl, HNO3, and H2SO4.
When heated, it decrepitates, giving off water, but does not fuse into a globular mass.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for MoraesiteHide

References for MoraesiteHide

Localities for MoraesiteHide

Showing 43 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Australia
 
  • Western Australia
    • Coolgardie Shire
      • Nepean
Pinch (1978)
Brazil
 
  • Minas Gerais
    • Divino das Laranjeiras
      • Linópolis
King et al. (1993)
Martin Slama collection +1 other reference
Atencio et al. (2005)
Menezes (n.d.) +1 other reference
    • Galiléia
      • Sapucaia do Norte
Lindberg et al. (1953)
    • Itinga
Cassedanne et al. (1987)
Sergio Varvello collection
      • Monte Belo
Sergio Varvello collection
      • Taquaral
        • Piauí valley
Chukanov et al. (2007)
Luis Menezes +1 other reference
    • Mendes Pimentel
Pers. Comm. from Paulo Anselmo Matioli
Atencio et al. (2005)
Finland
 
  • Pirkanmaa
    • Orivesi
      • Eräjärvi area
Sandström et al. (2009)
France
 
  • Nouvelle-Aquitaine
    • Haute-Vienne
      • Bellac
        • Saint-Léger-Magnazeix
          • Beaubatou
Lebocey (2016)
  • Occitanie
    • Aveyron
      • Villefranche-de-Rouergue
        • La Capelle-Bleys
Boisson et al. (2014) +2 other references
Germany
 
  • Bavaria
    • Lower Bavaria
      • Freyung-Grafenau District
        • Waldkirchen
          • Oberfrauenwald
Habel et al. (1994) +1 other reference
Namibia
 
  • ǁKaras Region
    • Karasburg East
      • Tantalite Valley
von Bezing (2007)
Peru
 
  • Puno
    • Carabaya Province
O'Connor et al. (2018)
Li (2016)
Russia
 
  • Chelyabinsk Oblast
    • Kaslinsky District
Pekov (1998)
  • Murmansk Oblast
...
    • Lovozersky District
Arzamastsev et al. (2008)
Pekov (2000)
  • Zabaykalsky Krai
    • Ononsky District
      • Durulgui granite-pegmatite system
Lykova I. S. et al. (2017)
USA
 
  • Connecticut
    • Middlesex County
      • East Hampton
        • Cobalt
Schooner (1961) +1 other reference
      • Portland
        • Collins Hill
          • Strickland pegmatite
Moritz (n.d.)
  • Maine
    • Cumberland County
      • Baldwin
        • West Baldwin
Collections of Elmar Lackner and Jason ...
    • Oxford County
      • Greenwood
        • Uncle Tom Mountain
Mineral News (1995) +2 other references
      • Newry
King et al. (1994) +1 other reference
King et al. (1994) +1 other reference
King et al. (1994) +1 other reference
      • Paris
King et al. (1991) +1 other reference
www.mindat.org (n.d.) +1 other reference
  • New Hampshire
    • Cheshire County
      • Walpole
Tom Mortimer (Oct. 2010) +1 other reference
    • Grafton County
      • Alexandria
Smith (2005) +1 other reference
      • Groton
Rocks & Min. 80:251
Smith (2005)
Moore (1973) +1 other reference
Janules +1 other reference
      • Orange
Thompson et al. (2022)
    • Sullivan County
      • Newport
Smith (2005)
  • North Carolina
    • Cleveland County
      • Kings Mountain
Smithsonian Institution Mineral ...
 
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