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Kafehydrocyanite

Valid as an unnamed mineral
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About KafehydrocyaniteHide

Formula:
K4[Fe(CN)6] · H2O
Colour:
Yellow, yellow-green, blue-green, white
Hardness:
2 - 2½
Crystal System:
Tetragonal
Potassium hexacyanoferrate(II) hydrate - a complex salt.

Originally reported from Medvezhii Log Au Deposit, Ol'khovskoye ore field, Sayan Mts, Tuva Republic, Eastern-Siberian Region, Russia.

Possibly originated due to cyanide leaching. Doubtful as a natural mineral.

See also: UM2009-//-CN:FeHKZn


Unique IdentifiersHide

Mindat ID:
2130
Long-form identifier:
mindat:1:1:2130:8

IMA Classification of KafehydrocyaniteHide

IMA status notes:
Published without approval, Unnamed (probably valid)

Classification of KafehydrocyaniteHide

10.AD.10

10 : ORGANIC COMPOUNDS
A : Salts of organic acids
D : Cyanates
50.2.5.1

50 : ORGANIC COMPOUNDS
2 : Mellitates, Citrates, Cyanates, Acetates and Formates
30.2

30 : Thiocyanates

Physical Properties of KafehydrocyaniteHide

Colour:
Yellow, yellow-green, blue-green, white
Hardness:
2 - 2½ on Mohs scale

Optical Data of KafehydrocyaniteHide

Type:
Uniaxial (+)
RI values:
nω = 1.577 nε = 1.584
Max. Birefringence:
δ = 0.007
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Moderate (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized uniaxial interference figure - the conoscopic (convergent-light, Bertrand-lens-in) view, for a grain cut with the optic axis centred and vertical. The coloured rings are isochromatics, computed with the same physics as the Michel-Lévy bar above; the dark cross is the isogyre.

For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.

Chemistry of KafehydrocyaniteHide

Mindat Formula:
K4[Fe(CN)6] · H2O
Element Weights:
Element% weight
K40.479 %
N21.752 %
C18.652 %
Fe14.454 %
O4.141 %
H0.522 %

Calculated from ideal end-member formula.
K
N
C
Fe
O
H

Crystallography of KafehydrocyaniteHide

Crystal System:
Tetragonal

First Recorded Occurrence of KafehydrocyaniteHide

Other Language Names for KafehydrocyaniteHide

Related Minerals - Strunz-mindat GroupingHide

10.AD.05JulieniteNa2[Co(SCN)4] · 8H2OMon. 2/m : P21/c

RadioactivityHide

Other InformationHide

Health Risks:
When heated with mineral acids, hexacyanoferrates will liberate prussic acid, HCN (gaseous), which is extremely toxic even at low levels. Contact with acids, therefore, should be prevented at all events.

Internet Links for KafehydrocyaniteHide

References for KafehydrocyaniteHide

Localities for KafehydrocyaniteHide

Showing 4 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Russia
 
  • Kemerovo Oblast
Pekov (1998)
Pekov (1998)
  • Orenburg Oblast
    • Gaysky District
      • Sakmara Zone
Pekov (1998)
  • Tuva
    • Ol'khovskoye ore field
- (1974) +1 other reference
 
and/or  
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