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Jeanbandyite

A valid IMA mineral species
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About JeanbandyiteHide

Formula:
Fe3+Sn(OH)5O
Colour:
Brownish orange, yellowish, reddish
Hardness:
3½
Specific Gravity:
3.81
Crystal System:
Tetragonal
Name:
Honouring Mrs. Jean A. Bandy (1900-1991), of Wickenburg, Arizona, USA, who donated to the Los Angeles Natural History Museum the collection on one of whose specimens this new mineral was discovered. The mineral bandylite was named for her husband.
Closely related to natanite.

Oxidised counterpart of natanite with partially deprotonated oxygen sites. Double perovskite of BB'(OH)6 type. The deprotonated domains have local short-range order.

A dark violet and hard mineral of the (Fe,Mn)(Sn,Ge)(OH)6 composition is reported as "Mineral D" and the Sn-analogue of stottite, from Tsumeb, Namibia (Geier & Ottemann, 1970).


Unique IdentifiersHide

Mindat ID:
2084
Long-form identifier:
mindat:1:1:2084:4

IMA Classification of JeanbandyiteHide

Approved
IMA Formula:
Fe3+Sn4+(OH)5O
Approval year:
1980

Classification of JeanbandyiteHide

4.FC.15

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
F : Hydroxides (without V or U)
C : Hydroxides with OH, without H2O; corner-sharing octahedra
6.3.7.3

6 : HYDROXIDES AND OXIDES CONTAINING HYDROXYL
3 : X(OH)3
7.11.9

7 : Oxides and Hydroxides
11 : Oxides of Sn and Pb

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
JbdIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of JeanbandyiteHide

Colour:
Brownish orange, yellowish, reddish
Streak:
Brownish yellow
Hardness:
3½ on Mohs scale
Comment:
ca. 3.5
Cleavage:
Imperfect/Fair
{001} and {100}
Density:
3.81(5) g/cm3 (Measured)    3.81 g/cm3 (Calculated)

Optical Data of JeanbandyiteHide

Type:
Uniaxial (-)
RI values:
nω = 1.837 nε = 1.833
Max. Birefringence:
δ = 0.004
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized uniaxial interference figure - the conoscopic (convergent-light, Bertrand-lens-in) view, for a grain cut with the optic axis centred and vertical. The coloured rings are isochromatics, computed with the same physics as the Michel-Lévy bar above; the dark cross is the isogyre.

For a genuinely uniaxial mineral viewed this way, that cross stays perfectly stationary if you rotate the stage - unlike a biaxial mineral, where it splits apart on rotation. That invariance is itself the standard diagnostic test for telling uniaxial and biaxial minerals apart at the microscope.

Chemistry of JeanbandyiteHide

Mindat Formula:
Fe3+Sn(OH)5O
Element Weights:
Element% weight
Sn43.075 %
O34.833 %
Fe20.264 %
H1.829 %

Calculated from ideal end-member formula.
Sn
O
Fe
H
Common Impurities:
Mn,(Mg,Si)

Crystallography of JeanbandyiteHide

Crystal System:
Tetragonal
Class (H-M):
4/m - Dipyramidal
Space Group:
P42/n
Cell Parameters:
a = 7.64 Å, c = 7.64 Å
Ratio:
a:c = 1 : 1
Unit Cell V:
445.94 ų (Calculated from Unit Cell)
Z:
4
Comment:
New refinement gives cubic cell, space group Pn-3, a=7.6427 or 7.658; on the other hand the stoichiometry (see the current formula) does not fit to such structure

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0013052JeanbandyiteMorgenstern-Badarau I, Michel A (1976) Sur l'existence d'un oxyhydroxyde double de fer(III) et d'etain(IV) Journal of Inorganic and Nuclear Chemistry 38 1400-14021976synthetic0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.83 Å(100)
2.71 Å(70)
1.71 Å(60)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 7: Great Oxidation Event<2.4
47a : [Near-surface hydration of prior minerals]

Type Occurrence of JeanbandyiteHide

Place of Conservation of Type Material:
Los Angeles County Natural History Museum (California)
Geological Setting of Type Material:
Telescoped hydrothermal tin mineralization in a highly altered acid igneous stock.
Associated Minerals at Type Locality:

Synonyms of JeanbandyiteHide

Other Language Names for JeanbandyiteHide

Relationship of Jeanbandyite to other SpeciesHide

Other Members of Schoenfliesite Subgroup:
BurtiteCa[Sn(OH)6]Hex.
Mushistonite(Cu,Zn,Fe2+)[Sn(OH)6]Orth. mmm(2/m2/m2/m) : Pnnn
NataniteFe2+[Sn(OH)6]Iso. m3m(4/m32/m) : Pn3m
SchoenfliesiteMg[Sn(OH)6]Iso. m3(2/m3) : Pn3
VismirnoviteZn[Sn(OH)6]Iso. m3m(4/m32/m) : Pn3m
WickmaniteMn2+[Sn(OH)6]Iso. m3(2/m3) : Pn3

Common AssociatesHide

Associations Based on Photo Data:
7 photos of Jeanbandyite associated with DzhalinditeIn(OH)3