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Homilite

A valid IMA mineral species - grandfathered
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About HomiliteHide

Formula:
Ca2(Fe2+,Mg)B2Si2O10
Colour:
Greenish black to brownish black
Lustre:
Vitreous, Resinous
Hardness:
5 - 5½
Specific Gravity:
3.34
Crystal System:
Monoclinic
Name:
Named by Sigurd Reinhold Paijkull (1849-1884) from the Greek ὁμιλέω, "to occur together," in allusion to its association with meliphanite and "erdmannite".
A borosilicate mineral belonging to the datolite subgroup of the gadolinite group of the gadolinite supergroup. Crystals of homilite was first noticed from Stokkøya, Langesundsfjorden, Norway by A. E. Nordenskiöld in 1860, but it was first published and described by S.R.Paijkull (1876). Brøgger (1890) published extensive crystallographic data. The structure was solved by Miyawaki et al. (1985) on the material from type locality.

In the Langesundsfjorden area, Norway it occurs in syenite pegmatites, exclusively within the "meliphanite zone", a zone strecthing across the central parts of the Stokkøya and Arøya Island. Homilite was also discovered in a volcanic ejectum at Tre Croci, Vico volcanic complex, Viterbo Province, Latium, Italy in 2004 (Pierini 2004).


Unique IdentifiersHide

Mindat ID:
1926
Long-form identifier:
mindat:1:1:1926:8

Similar NamesHide

Hamelitea hydrated (H2O) Silicate of Al, Fe and Mg
HemloiteA valid IMA mineral species(Ti,V3+,Fe3+,Al)12(As3+,Sb3+)2O23(OH)
HuemuliteA valid IMA mineral speciesNa4Mg(V10O28) · 24H2O
OhmiliteA valid IMA mineral speciesSr3(Ti,Fe3+)(Si4O12)(O,OH) · 2-3H2O

IMA Classification of HomiliteHide

Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
Ca2Fe2+B2(SiO4)2O2
First published:
1876

Classification of HomiliteHide

9.AJ.20

9 : SILICATES (Germanates)
A : Nesosilicates
J : Nesosilicates with BO3 triangles and/or B[4], Be[4] tetrahedra, cornersharing with SiO4
54.2.1b.5

54 : NESOSILICATES Borosilicates and Some Beryllosilicates
2 : Borosilicates and Some Beryllosilicates with B in [4] coordination
17.5.48

17 : Silicates Containing other Anions
5 : Borosilicates

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
HomIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of HomiliteHide

Vitreous, Resinous
Transparency:
Opaque
Colour:
Greenish black to brownish black
Comment:
Translucent in very thin splinters
Streak:
Grey
Hardness:
5 - 5½ on Mohs scale
Tenacity:
Brittle
Cleavage:
None Observed
Fracture:
Sub-Conchoidal
Density:
3.34 g/cm3 (Measured)    

Optical Data of HomiliteHide

Type:
Biaxial (+)
RI values:
nα = 1.715 nβ = 1.725 nγ = 1.738
2V:
Measured: 80° , Calculated: 84°
Max. Birefringence:
δ = 0.023
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Very High (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
none
Optical Extinction:
Z = b; Y ∧ c = -1°.
Comments:
Absorption: Y > X > Z.

Chemistry of HomiliteHide

Mindat Formula:
Ca2(Fe2+,Mg)B2Si2O10
Element Weights:
Element% weight
O42.803 %
Ca21.444 %
Si15.028 %
Fe14.940 %
B5.785 %

Calculated from ideal end-member formula.
O
Ca
Si
Fe
B
Common Impurities:
Al,Mn,Na

Chemical AnalysisHide

Crystallography of HomiliteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/b
Setting:
P21/a
Cell Parameters:
a = 9.78 Å, b = 7.61 Å, c = 4.78 Å
β = 90.56°
Ratio:
a:b:c = 1.285 : 1 : 0.628
Unit Cell V:
355.74 ų (Calculated from Unit Cell)
Morphology:
Observed forms (after Brögger 1890): {001}, {011}, {021}, {010}, {100}, {720}, {310}, {210}, {110}, {890}, {120}, {201}, {111}, {211}, {111}, {421}, {221}, {10·5·2}.
Twinning:
Frequently occurs as twins: with (100) as the twin plane, with (001) as the twin plane, with (430) as the twin pane or with (120) as the twin plane.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0010002HomiliteMiyawaki R, Nakai I, Nagashima K (1985) Structure of homilite, Ca2.00(Fe0.90Mn0.03)B2.00Si2.00O9.86(OH)0.14 Acta Crystallographica C41 13-151985Stoko, Brevig, Langesundfjord, Norway0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.10 Å(100)
2.52 Å(100)
2.83 Å(90)
2.97 Å(70)
2.18 Å(70)
2.23 Å(60)
1.86 Å(50)
Comments:
Store-Arø Island, Langesundsfjord, Norway. ICDD 17-211.

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4b: Highly evolved igneous rocks>3.0
35 : Ultra-alkali and agpaitic igneous rocks
Geological Setting:
syenite pegmatite

Type Occurrence of HomiliteHide

General Appearance of Type Material:
Black to black-brownish crystal
Place of Conservation of Type Material:
Muséum National d’Histoire Naturelle, Galerie Nationale de Minéralogie et de Géologie, Paris, France (catalogue #78142), Naturhistoriske Riksmuseet, Sektionen för Mineralogi, Stockholm, Sweden (catalogue # 531010)
Geological Setting of Type Material:
Nepheline syenite pegmatite
Associated Minerals at Type Locality:

Other Language Names for HomiliteHide

Dutch:Homiliet
German:Homilit
Spanish:Homilita

Relationship of Homilite to other SpeciesHide

Other Members of Datolite Subgroup:
DatoliteCaB(SiO4)(OH)Mon. 2/m : P21/b

Common AssociatesHide

Associations Based on Photo Data:
4 photos of Homilite associated with Meliphanite(Ca,Na)2(Be,Al)[Si2O6(OH,F)]
2 photos of Homilite associated with TitaniteCaTiO(SiO4)
2 photos of Homilite associated with MicroclineK(AlSi3O8)
1 photo of Homilite associated with ZirconZr(SiO4)

Related Minerals - Strunz-mindat GroupingHide

9.AJ.Hingganite-(Nd)Nd2◻Be2Si2O8(OH)2Mon. 2/m : P21/b
9.AJ.Arrheniusite-(Ce)CaMg[(Ce7Y3)Ca5](SiO4)4(Si2B3AsO18)(BO3)F11Trig. 3m : R3m
9.AJ.05Ominelite(Fe2+,Mg)(Al,Fe3+)3(SiO4)(BO3)O2Orth. mmm(2/m2/m2/m)
9.AJ.05Grandidierite(Mg,Fe2+)(Al,Fe3+)3(SiO4)(BO3)O2Orth. mmm(2/m2/m2/m)
9.AJ.10DumortieriteAl(Al2O)(Al2O)2(SiO4)3(BO3)Orth. mmm(2/m2/m2/m)
9.AJ.10Nioboholtite(Nb0.6◻0.4)Al6BSi3O18Orth. mmm(2/m2/m2/m) : Pbcm
9.AJ.10Titanoholtite(Ti0.75◻0.25)Al6BSi3O18Orth. mmm(2/m2/m2/m) : Pbcm
9.AJ.10Holtite(Ta0.6◻0.4)Al6BSi3O18(O,OH)2.25Orth. mmm(2/m2/m2/m) : Pnma
9.AJ.10MagnesiodumortieriteMg(Al2OH)(Al2O)2(SiO4)3(BO3)Orth. mmm(2/m2/m2/m)
9.AJ.15GarrelsiteBa3NaSi2B7O16(OH)4Mon. 2/m : B2/b
9.AJ.20'Muromontite'near Be2FeY2Si3O12
9.AJ.20Gadolinite-(Nd)Nd2Fe2+Be2O2(SiO4)2Mon. 2/m : P21/b
9.AJ.20DatoliteCaB(SiO4)(OH)Mon. 2/m : P21/b
9.AJ.20Melanocerite-(Ce)(Ce,Ca)5(SiO4,BO4)3(OH,O)Hex.
9.AJ.20Gadolinite-(Ce)(Ce,La,Nd,Y)2Fe2+Be2Si2O10Mon. 2/m
9.AJ.20Gadolinite-(Y)Y2Fe2+Be2Si2O10Mon. 2/m : P21/b
9.AJ.20'Unnamed (OH-analogue of Gadolinite-(Y))'(Y,Ca)2(Fe,◻)Be2Si2O8(OH,O)2Mon. 2/m
9.AJ.20Hingganite-(Ce)(Ce,REE)2(◻,Fe2+)Be2[SiO4]2(OH)2Mon. 2/m : P21/b
9.AJ.20Hingganite-(Y)(Y,REE,Ca)2(◻,Fe2+)Be2[SiO4]2(OH)2Mon. 2/m : P21/b
9.AJ.20Hingganite-(Yb)(Yb,Y,REE)2◻Be2[SiO4]2(OH)2Mon. 2/m : P21/b
9.AJ.20'Minasgeraisite-(Y)'(Ca2Y2)◻2(Be2B2)[SiO4]4(OH)4Tric. 1 : P1
9.AJ.20Calcybeborosilite-(Y)(Y,Ca)2(◻,Fe2+)(B,Be)2[SiO4]2(OH,O)2Mon.
9.AJ.25Stillwellite-(La)LaBSiO5Trig. 32 : P3221
9.AJ.25Stillwellite-(Ce)(Ce,La,Ca)BSiO5Trig. 3 : P31
9.AJ.30Cappelenite-(Y)Ba(Y,Ce)6Si3B6O24F2Trig. 3 : P3
9.AJ.35Laptevite-(Ce)Ca6(Fe2+,Mn2+)Y3REE7(SiO4)3(PO4)(B3Si3O18)(BO3)F11Trig. 3m : R3m
9.AJ.35Proshchenkoite-(Y)Ca(Y,REE,Ca,Na,Mn)15Fe2+(P,Si)Si6B3O34F14Trig. 3m : R3m
9.AJ.35Okanoganite-(Y)(Na,Ca)3(Y,Ce)12Si6B2O27F14Trig. 3m : R3m
9.AJ.35Hundholmenite-(Y)(Y,REE,Ca,Na)15(Al,Fe3+)(CaxAs3+1-x)(Si,As5+)Si6B3(O,F)48Trig. 3m : R3m
9.AJ.35Vicanite-(Ce)(Ca,Ce,La,Th)15As5+(As3+0.5,Na0.5)Fe3+Si6B4O40F7Trig. 3m : R3m
9.AJ.40JadariteLiNaSiB3O7(OH)Mon. 2/m

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for HomiliteHide

References for HomiliteHide

Reference List:

Localities for HomiliteHide

Showing 13 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Italy
 
  • Lazio
    • Viterbo Province
      • Vetralla
Pierini (2004) +1 other reference
Norway
 
  • Vestfold
    • Larvik Commune
Larsen et al. (2010)
Brøgger (1890)
Paijkull (1876) +1 other reference
      • Stokksund
Naturhistorska Riskmuseets Stockholm ... +1 other reference
      • Store Arøya (Arøy)
Brøgger (1890)
Åsheim et al. (1980)
      • Tvedalen
Nordrum (2001)
    • Sandefjord
      • Vesterøya
Hansen (1981)
Romania
 
  • Suceava County
    • Iacobeni
minerals-of-the-carpathians.eu (2008)
      • Tolovanu
Hîrtopanu (1997) +1 other reference
Sweden
 
  • Värmland County
    • Filipstad
      • Nordmark Odal Field
Probed 2004 - M.E. Ciriotti
 
and/or  
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