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Eskebornite

A valid IMA mineral species - grandfathered
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About EskeborniteHide

Formula:
CuFeSe2
Colour:
Brass yellow
Lustre:
Metallic
Hardness:
3 - 3½
Specific Gravity:
5.35
Crystal System:
Tetragonal
Name:
Named for the Eskeborn adit, Tilkerode, Germany, the type locality.

Unique IdentifiersHide

Mindat ID:
1409
Long-form identifier:
mindat:1:1:1409:6

IMA Classification of EskeborniteHide

Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
Cu1+Fe3+Se2-2
First published:
1950

Classification of EskeborniteHide

2.CB.10a

2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
C : Metal Sulfides, M: S = 1: 1 (and similar)
B : With Zn, Fe, Cu, Ag, etc.
2.9.1.2

2 : SULFIDES
9 : AmBnXp, with (m+n):p = 1:1
3.1.33

3 : Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)
1 : Sulphides etc. of Cu

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
EbnIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of EskeborniteHide

Metallic
Transparency:
Opaque
Colour:
Brass yellow
Comment:
Tarnishes dark brown to black
Streak:
Black
Hardness:
3 - 3½ on Mohs scale
Hardness:
VHN15=155 - 252 kg/mm2 - Vickers
Cleavage:
Perfect
on {001}
Density:
5.35 g/cm3 (Measured)    5.44 g/cm3 (Calculated)

Optical Data of EskeborniteHide

Anisotropism:
Marked - yellowish to tan
Reflectivity:
WavelengthR1 (%)R2 (%)
400nm22.0%24.5%
440nm26.5%30.1%
480nm28.7%33.1%
520nm30.4%35.0%
560nm31.6%36.0%
600nm32.6%36.4%
640nm33.3%37.0%
680nm33.8%38.1%
700nm34.0%38.7%


Graph shows reflectance levels at different wavelengths (in nm). Peak reflectance is 38.7%.
R1 shown in black, R2 shown in red
Colour in reflected light:
brown-yellow or cream-yellow sometimes with orange tint
Pleochroism:
Weak
Comments:
Creamy yellow to yellowish brown

Chemistry of EskeborniteHide

Mindat Formula:
CuFeSe2
Element Weights:
Element% weight
Se56.947 %
Cu22.915 %
Fe20.138 %

Calculated from ideal end-member formula.
Se
Cu
Fe

Chemical AnalysisHide

wt%
 12
Cu23.0 %23.62 %
Fe19.7 %19.75 %
Se57.5 %55.96 %
Total:100.2 %99.33 %
Empirical formulas:
Sample IDEmpirical Formula
1Cu0.99Fe0.97Se2.00
2Cu1.06Fe1.01Se2.00

Crystallography of EskeborniteHide

Crystal System:
Tetragonal
Class (H-M):
42m - Scalenohedral
Space Group:
P42c
Cell Parameters:
a = 5.518(4) Å, c = 11.048(6) Å
Ratio:
a:c = 1 : 2.002
Unit Cell V:
336.39 ų (Calculated from Unit Cell)
Z:
8
Morphology:
Thick tabular crystals to 1mm

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0014365EskeborniteDelgado J M, Diaz de Delgado G, Quintero M, Woolley J C (1992) The crystal structure of copper iron selenide, CuFeSe2 Materials Research Bulletin 27 367-3731992synthetic0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.186 Å(100)
1.951 Å(90)
1.664 Å(80)
5.52 Å(70)
1.127 Å(70)
1.380 Å(60)
2.470 Å(50)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
High-? alteration and/or metamorphism
33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12])
Geological Setting:
Low temperature hydrothermal deposits

Type Occurrence of EskeborniteHide

Place of Conservation of Type Material:
The Natural History Museum, London, England, 1948,325; Harvard University, Cambridge, Massachusetts, USA, 98902.
Geological Setting of Type Material:
low-temperature hydrothermal vein deposits
Associated Minerals at Type Locality:

Other Language Names for EskeborniteHide

German:Eskebornit
Simplified Chinese:硒黄铜矿
Spanish:Eskebornita
Traditional Chinese:硒黃銅礦

Relationship of Eskebornite to other SpeciesHide

Other Members of Chalcopyrite Group:
ChalcopyriteCuFeS2Tet. 42m : I42d
GalliteCuGaS2Tet. 42m : I42d
LaforêtiteAgInS2Tet. 42m : I42d
LenaiteAgFeS2Tet. 42m : I42d
RoquesiteCuInS2Tet. 42m : I42d
ShenzhuangiteNiFeS2Tet. 42m : I42d
'Unnamed (Cu-Mn-Sn Sulphide)'Cu2MnSnS4
Forms a series with:

Common AssociatesHide

Associations Based on Photo Data:
48 photos of Eskebornite associated with ClausthalitePbSe
41 photos of Eskebornite associated with KlockmanniteCuSe
18 photos of Eskebornite associated with UmangiteCu3Se2
9 photos of Eskebornite associated with ChalcopyriteCuFeS2
9 photos of Eskebornite associated with CalciteCaCO3
8 photos of Eskebornite associated with EucairiteAgCuSe
8 photos of Eskebornite associated with