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Clinophosinaite

A valid IMA mineral species
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About ClinophosinaiteHide

Formula:
Na12(Ca,Sr)4(Si4O12)(PO4)4
Colour:
Light violet
Lustre:
Vitreous
Hardness:
4
Specific Gravity:
2.85 - 2.88
Crystal System:
Monoclinic
Name:
A monoclinic polymorph of phosinaite.
This page provides mineralogical data about Clinophosinaite.


Unique IdentifiersHide

Mindat ID:
1081
Long-form identifier:
mindat:1:1:1081:4

IMA Classification of ClinophosinaiteHide

Classification of ClinophosinaiteHide

9.CF.15

9 : SILICATES (Germanates)
C : Cyclosilicates
F : [Si4O12]8- 4-membered single rings, with insular complex anions
17.6.5

17 : Silicates Containing other Anions
6 : Silicates with phosphate

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference for Standard
CpsiIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of ClinophosinaiteHide

Vitreous
Transparency:
Transparent
Colour:
Light violet
Hardness:
Fracture:
Conchoidal
Density:
2.85 - 2.88 g/cm3 (Measured)    2.84 g/cm3 (Calculated)

Optical Data of ClinophosinaiteHide

Type:
Biaxial (+)
RI values:
nα = 1.556 - 1.557 nβ = 1.559 - 1.561 nγ = 1.563 - 1.567
2V:
Measured: 75° to 80°, Calculated: 80°
Max. Birefringence:
δ = 0.007 - 0.010
Based on recorded range of RI values above.

Interference Colours:
The colours simulate birefringence patterns seen in thin section under crossed polars. They do not take into account mineral colouration or opacity.

Michel-Levy Bar The default colours simulate the birefringence range for a 30 µm thin-section thickness. Adjust the slider to simulate a different thickness.

Grain Simulation You can rotate the grain simulation to show how this range might look as you rotated a sample under crossed polars. Each grain retains its interference colour (retardation) while its brightness falls to black at extinction and reaches a maximum between extinction positions.

Surface Relief:
Low (positive)
Relative to Canada balsam mounting medium (n ≈ 1.537).

This shows the grain boundary and Becke line effect under plane-polarised light, based on the contrast between this mineral's average refractive index and the mounting medium. It does not take into account mineral colouration.
In focus
Interference Figure:
This shows the idealized biaxial acute bisectrix (Bxa) interference figure - the conoscopic view for a grain cut perpendicular to the acute bisectrix, using this mineral's 2V. The two small white dots mark the melatopes - the points where the two optic axes emerge - and are shown only when they fall within the field of view. The coloured bands are isochromatics, and the dark bands are isogyres.

Rotate the stage: at 0°/90° the isogyres form a cross through the melatopes; at 45° they pull apart into curved hyperbolas. That splitting on rotation - absent in a uniaxial figure - is the standard diagnostic test for telling biaxial minerals from uniaxial ones. If 2V is large, the melatopes may fall outside the field of view, as they often do at the microscope too.
Dispersion:
r > v strong

Chemistry of ClinophosinaiteHide

Mindat Formula:
Na12(Ca,Sr)4(Si4O12)(PO4)4
Element Weights:
Element% weight
O39.984 %
Na24.623 %
Ca14.308 %
P11.058 %
Si10.027 %

Calculated from ideal end-member formula.
O
Na
Ca
P
Si
Common Impurities:
Ce,Mn,Sr,K

Crystallography of ClinophosinaiteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P2/b
Setting:
P2/c
Cell Parameters:
a = 7.303(2) Å, b = 12.201(5) Å, c = 14.715(4) Å
β = 91.96°
Ratio:
a:b:c = 0.599 : 1 : 1.206
Unit Cell V:
1,310.40 ų (Calculated from Unit Cell)
Z:
8

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0015582ClinophosinaiteKrutik V M, Pushcharovsky D Y, Khomyakov A P, Pobedimskaya E A, Belov N V (1980) Anion radical of mixed type (four [S4O12] rings and P orthotetrahedra) in the structure of monoclinic fosinaite Soviet Physics Crystallography 25 138-1421980Khibiny pegmatites, Kola Peninsula, Russia0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
2.724 Å(100)
2.639 Å(57)
2.550 Å(50)
2.031 Å(50)
1.823 Å(47)
Comments:
Khibiny massif, Kola, Russia. Data from the type description.

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4b: Highly evolved igneous rocks>3.0
35 : Ultra-alkali and agpaitic igneous rocks
Stage 7: Great Oxidation Event<2.4
47c : [Carbonates, phosphates, borates, nitrates]

Type Occurrence of ClinophosinaiteHide

General Appearance of Type Material:
Irregular grains from 1-2 mm in zirsinalite.
Place of Conservation of Type Material:
A.E. Fersman Mineralogical Museum, Academy of Sciences, Moscow, Russia, 8159
Geological Setting of Type Material:
Alkalic pegmatite. Possible breakdown product (with zirsinalite) of eudialyte.
Associated Minerals at Type Locality:

Synonyms of ClinophosinaiteHide

Other Language Names for ClinophosinaiteHide

Related Minerals - Strunz-mindat GroupingHide

9.CF.BobmeyeritePb4(Al3Cu)(Si4O12)(S0.5Si0.5O4)(OH)7Cl(H2O)3Orth. mmm(2/m2/m2/m) : Pnnm
9.CF.05AshburtonitePb4Cu4(Si4O12)(HCO3)4(OH)3Cl · H2OTet.
9.CF.10Kainosite-(Y)Ca2Y2(SiO3)4(CO3) · H2OOrth. mmm(2/m2/m2/m)
9.CF.15Phosinaite-(Ce)Na13Ca2(Ce,La,Th,Nd,Pr)(Si4O12)(PO4)4Orth. 222 : P21212
9.CF.20StrakhoviteNaBa3Mn2+2Mn3+2Si6O19(OH)3Orth. mmm(2/m2/m2/m)
9.CF.25Cerchiaraite-(Al)Ba4Al4O3(OH)3(Si4O12)[Si2O3(OH)4]Cl Tet. 4/mmm(4/m2/m2/m) : I4/mmm
9.CF.25Cerchiaraite-(Fe)Ba4Fe3+4O3(OH)3(Si4O12)[Si2O3(OH)4]Cl Tet. 4/mmm(4/m2/m2/m) : I4/mmm
9.CF.25Cerchiaraite-(Mn)Ba4Mn3+4(Si4O12)O2(OH)4Cl2[Si2O3(OH)4]Tet. 4/mmm(4/m2/m2/m) : I4/mmm

Other InformationHide

Notes:
Easily decomposed at low temperature by 10% HCl.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for ClinophosinaiteHide

References for ClinophosinaiteHide

Localities for ClinophosinaiteHide

Showing 4 localities.

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Russia (TL)
 
  • Murmansk Oblast
    • Koashva Mt
[World of Stones 95:5-6 +2 other references
Roberto Bosi collection.
      • Rasvumchorr Mine
Tony Nikischer and Luis Menezes +1 other reference
    • Yukspor Mountain
Khomyakov et al. (1983) +1 other reference
 
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